KR960014074A - 이소파라핀에 의한 아필렌의 알킬화 중 합성 이소펜탄 생성 억제 방법 - Google Patents

이소파라핀에 의한 아필렌의 알킬화 중 합성 이소펜탄 생성 억제 방법 Download PDF

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Publication number
KR960014074A
KR960014074A KR1019940016669A KR19940016669A KR960014074A KR 960014074 A KR960014074 A KR 960014074A KR 1019940016669 A KR1019940016669 A KR 1019940016669A KR 19940016669 A KR19940016669 A KR 19940016669A KR 960014074 A KR960014074 A KR 960014074A
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South Korea
Prior art keywords
isopentane
mixture
weight
amylene
synthetic
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KR1019940016669A
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KR100278082B1 (ko
Inventor
지이 애벗트 로널드
비이 랜돌프 브루스
엘 앤더어슨 리차아드
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제이 이이 휘립프스
휘립프스 피트로오리암 캄파니
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56Addition to acyclic hydrocarbons
    • C07C2/58Catalytic processes
    • C07C2/62Catalytic processes with acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06Halogens; Compounds thereof
    • C07C2527/08Halides
    • C07C2527/12Fluorides
    • C07C2527/1206Hydrogen fluoride

Abstract

알킬화 반응기 공급 물질 내에 이소펜탄 농도를 제공함으로써 아밀렌과 이소파리핀의촉매화된 알킬화 반응중 합성 이소펜탄의 생성을 최소화하거나 조절하는 방법.

Description

이소파라핀에 의한 아필렌의 알킬화 중 합성 이소펜탄 생성 억제 방법.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 아밀렌 및 이소부탄으로 구성도고 함성 이소펜탄의 생성을 원하는 양으로 억제하기에 효과적인 양이 이소펜탄을 또한 포함하는 물질과 일칼화 촉매를 반응 영역내에서 접촉시키고; 실질적으로 이소펜탄 농도가 없는 상기 혼합물을상기 알킬화 촉매와 접촉시킬 때 결과되는 농도 미만의 감소된 합성 이소펜탄 농도를 갖는 알킬레이트 생성물로 구성되는 바응 생성물을 상기 반응 영역내에서 생성하는 것으로 구성되는, 이소파라핀에 의한 아밀렌의 알킬화 방법.
  2. 제1항에 있어서, 합성 이소펜탄의 생성을 억제하기에 효과적인 상기 혼합물 내 상기 이소펜탄량이 상기 혼합물 내 이소펩탄의 중량 대 상기 혼합물 내 아밀렌 중량의 비율로써 결정되는 바 2 : 1을 초과하는 방법
  3. 제2항에 있어서, 상기 혼합물 내 상기 이소펜탄량은 상기 혼합물 내 이소펜탄의 중량 대 상기 혼합물 내 아밀렌의 중량의 비율로써 결정되는 바 약 2 : 1-약 10 : 1인 방법
  4. 제1-3항 중 어느 한 항에 있어서, 합성 이소펜탄 생성의 상기 바람직한 양은 합성 이소펜탄 생성 중량 대 상기 혼합물 내 암리렌 중량의 비율로써 측정되는 바 약 0.8 : 1미만인 방법
  5. 제1-3항 중 어느 한 항에 있어서, 상기 알킬화 촉매는 불화수소를 포함하는 방법.
  6. 제1-3항 중 어느 한 항에 있어서, 상기 혼합물 내 이소부탄 대 아밀렌의 중량비는 2 : 1을 초과하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940016669A 1993-07-12 1994-07-11 이소부탄에 의한 아밀렌의 알킬화 방법 KR100278082B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/088.942 1993-07-12
US08/088,942 1993-07-12
US08/088,942 US5382744A (en) 1993-07-12 1993-07-12 Control of synthetic isopentane production during alkylation of amylenes

Publications (2)

Publication Number Publication Date
KR960014074A true KR960014074A (ko) 1996-05-22
KR100278082B1 KR100278082B1 (ko) 2001-01-15

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019940016669A KR100278082B1 (ko) 1993-07-12 1994-07-11 이소부탄에 의한 아밀렌의 알킬화 방법

Country Status (12)

Country Link
US (1) US5382744A (ko)
EP (1) EP0634382B1 (ko)
JP (1) JP2886090B2 (ko)
KR (1) KR100278082B1 (ko)
AT (1) ATE172705T1 (ko)
AU (1) AU659778B2 (ko)
CA (1) CA2122377C (ko)
DE (1) DE69414193T2 (ko)
DK (1) DK0634382T3 (ko)
ES (1) ES2122100T3 (ko)
FI (1) FI113166B (ko)
SG (1) SG50562A1 (ko)

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US7838708B2 (en) * 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
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US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US7674941B2 (en) * 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7371918B2 (en) * 2004-12-15 2008-05-13 Uop Llc Alkylation process with settler effluent recycle
EP1993951B1 (en) * 2006-02-03 2014-07-30 GRT, Inc. Separation of light gases from bromine
AP2012006510A0 (en) 2006-02-03 2012-10-31 Grt Inc Continuous process for converting natural gas to liquid hydrocarbons
CN101687725A (zh) * 2007-05-14 2010-03-31 Grt公司 使烃类原料转化同时电解回收卤素的方法
MX2009012581A (es) 2007-05-24 2010-03-15 Grt Inc Reactor de zonas que incorpora captura y liberacion de haluro de hidrogeno reversible.
US7920027B2 (en) * 2008-04-07 2011-04-05 Qualcomm Incorporated Amplifier design with biasing and power control aspects
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
US8415517B2 (en) * 2008-07-18 2013-04-09 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
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Also Published As

Publication number Publication date
FI943297A0 (fi) 1994-07-11
SG50562A1 (en) 1998-07-20
JPH07145085A (ja) 1995-06-06
AU659778B2 (en) 1995-05-25
DE69414193T2 (de) 1999-04-01
EP0634382B1 (en) 1998-10-28
CA2122377C (en) 1998-10-13
ATE172705T1 (de) 1998-11-15
US5382744A (en) 1995-01-17
DK0634382T3 (da) 1999-07-05
JP2886090B2 (ja) 1999-04-26
KR100278082B1 (ko) 2001-01-15
EP0634382A1 (en) 1995-01-18
FI113166B (fi) 2004-03-15
DE69414193D1 (de) 1998-12-03
AU6614394A (en) 1995-01-19
CA2122377A1 (en) 1995-01-13
FI943297A (fi) 1995-01-13
ES2122100T3 (es) 1998-12-16

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