KR960014074A - 이소파라핀에 의한 아필렌의 알킬화 중 합성 이소펜탄 생성 억제 방법 - Google Patents
이소파라핀에 의한 아필렌의 알킬화 중 합성 이소펜탄 생성 억제 방법 Download PDFInfo
- Publication number
- KR960014074A KR960014074A KR1019940016669A KR19940016669A KR960014074A KR 960014074 A KR960014074 A KR 960014074A KR 1019940016669 A KR1019940016669 A KR 1019940016669A KR 19940016669 A KR19940016669 A KR 19940016669A KR 960014074 A KR960014074 A KR 960014074A
- Authority
- KR
- South Korea
- Prior art keywords
- isopentane
- mixture
- weight
- amylene
- synthetic
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
- C07C2/62—Catalytic processes with acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/08—Halides
- C07C2527/12—Fluorides
- C07C2527/1206—Hydrogen fluoride
Abstract
알킬화 반응기 공급 물질 내에 이소펜탄 농도를 제공함으로써 아밀렌과 이소파리핀의촉매화된 알킬화 반응중 합성 이소펜탄의 생성을 최소화하거나 조절하는 방법.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (6)
- 아밀렌 및 이소부탄으로 구성도고 함성 이소펜탄의 생성을 원하는 양으로 억제하기에 효과적인 양이 이소펜탄을 또한 포함하는 물질과 일칼화 촉매를 반응 영역내에서 접촉시키고; 실질적으로 이소펜탄 농도가 없는 상기 혼합물을상기 알킬화 촉매와 접촉시킬 때 결과되는 농도 미만의 감소된 합성 이소펜탄 농도를 갖는 알킬레이트 생성물로 구성되는 바응 생성물을 상기 반응 영역내에서 생성하는 것으로 구성되는, 이소파라핀에 의한 아밀렌의 알킬화 방법.
- 제1항에 있어서, 합성 이소펜탄의 생성을 억제하기에 효과적인 상기 혼합물 내 상기 이소펜탄량이 상기 혼합물 내 이소펩탄의 중량 대 상기 혼합물 내 아밀렌 중량의 비율로써 결정되는 바 2 : 1을 초과하는 방법
- 제2항에 있어서, 상기 혼합물 내 상기 이소펜탄량은 상기 혼합물 내 이소펜탄의 중량 대 상기 혼합물 내 아밀렌의 중량의 비율로써 결정되는 바 약 2 : 1-약 10 : 1인 방법
- 제1-3항 중 어느 한 항에 있어서, 합성 이소펜탄 생성의 상기 바람직한 양은 합성 이소펜탄 생성 중량 대 상기 혼합물 내 암리렌 중량의 비율로써 측정되는 바 약 0.8 : 1미만인 방법
- 제1-3항 중 어느 한 항에 있어서, 상기 알킬화 촉매는 불화수소를 포함하는 방법.
- 제1-3항 중 어느 한 항에 있어서, 상기 혼합물 내 이소부탄 대 아밀렌의 중량비는 2 : 1을 초과하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/088.942 | 1993-07-12 | ||
US08/088,942 | 1993-07-12 | ||
US08/088,942 US5382744A (en) | 1993-07-12 | 1993-07-12 | Control of synthetic isopentane production during alkylation of amylenes |
Publications (2)
Publication Number | Publication Date |
---|---|
KR960014074A true KR960014074A (ko) | 1996-05-22 |
KR100278082B1 KR100278082B1 (ko) | 2001-01-15 |
Family
ID=22214422
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019940016669A KR100278082B1 (ko) | 1993-07-12 | 1994-07-11 | 이소부탄에 의한 아밀렌의 알킬화 방법 |
Country Status (12)
Country | Link |
---|---|
US (1) | US5382744A (ko) |
EP (1) | EP0634382B1 (ko) |
JP (1) | JP2886090B2 (ko) |
KR (1) | KR100278082B1 (ko) |
AT (1) | ATE172705T1 (ko) |
AU (1) | AU659778B2 (ko) |
CA (1) | CA2122377C (ko) |
DE (1) | DE69414193T2 (ko) |
DK (1) | DK0634382T3 (ko) |
ES (1) | ES2122100T3 (ko) |
FI (1) | FI113166B (ko) |
SG (1) | SG50562A1 (ko) |
Families Citing this family (32)
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---|---|---|---|---|
US5583275A (en) * | 1994-08-19 | 1996-12-10 | Stratco, Inc. | Alkylation of olefins utilizing mixtures of isoparaffins |
US5489727A (en) * | 1994-10-28 | 1996-02-06 | Phillips Petroleum Company | Isopentane disproportionation |
US5684220A (en) * | 1995-03-23 | 1997-11-04 | Phillips Petroleum Company | Process for reducing the vapor pressure of gasoline by removing amylenes therefrom and enhancing the octane thereof |
US5629466A (en) * | 1995-03-23 | 1997-05-13 | Phillips Petroleum Company | Method for removing amylenes from gasoline and alkylating such amylene and other olefins while minimizing synthetic isopentane production |
US6429349B1 (en) * | 1996-08-12 | 2002-08-06 | Bp Corporation North America Inc. | Co-alkylation for gasoline RVP reduction |
US6395945B1 (en) * | 2000-03-31 | 2002-05-28 | Phillips Petroleum Company | Integrated hydroisomerization alkylation process |
US7838708B2 (en) * | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
US20050038310A1 (en) * | 2003-07-15 | 2005-02-17 | Lorkovic Ivan M. | Hydrocarbon synthesis |
US20050171393A1 (en) * | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
US7244867B2 (en) | 2004-04-16 | 2007-07-17 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US20080275284A1 (en) * | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
US7674941B2 (en) * | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US7371918B2 (en) * | 2004-12-15 | 2008-05-13 | Uop Llc | Alkylation process with settler effluent recycle |
EP1993951B1 (en) * | 2006-02-03 | 2014-07-30 | GRT, Inc. | Separation of light gases from bromine |
AP2012006510A0 (en) | 2006-02-03 | 2012-10-31 | Grt Inc | Continuous process for converting natural gas to liquid hydrocarbons |
CN101687725A (zh) * | 2007-05-14 | 2010-03-31 | Grt公司 | 使烃类原料转化同时电解回收卤素的方法 |
MX2009012581A (es) | 2007-05-24 | 2010-03-15 | Grt Inc | Reactor de zonas que incorpora captura y liberacion de haluro de hidrogeno reversible. |
US7920027B2 (en) * | 2008-04-07 | 2011-04-05 | Qualcomm Incorporated | Amplifier design with biasing and power control aspects |
US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
US8415517B2 (en) * | 2008-07-18 | 2013-04-09 | Grt, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
WO2010124041A1 (en) * | 2009-04-22 | 2010-10-28 | Grt, Inc. | Process for converting hydrocarbon feedstocks with electrolytic and photoelectrocatalytic recovery of halogens |
US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
US10059639B2 (en) | 2016-09-02 | 2018-08-28 | Chevron U.S.A. Inc. | Alkylation of refinery pentenes with isobutane |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2403649A (en) * | 1942-01-13 | 1946-07-09 | Phillips Petroleum Co | Hydrocarbon reconstruction |
US2662103A (en) * | 1945-12-18 | 1953-12-08 | Phillips Petroleum Co | Production of paraffins |
US3679771A (en) * | 1970-05-12 | 1972-07-25 | Phillips Petroleum Co | Conversion of hydrocarbons |
CA1108653A (en) * | 1978-04-24 | 1981-09-08 | Don B. Carson | Hf alkylation process |
US4262155A (en) * | 1979-07-03 | 1981-04-14 | Phillips Petroleum Company | Maximization of isoparaffin utilization in alkylation of hydrocarbons |
US4429173A (en) * | 1982-03-09 | 1984-01-31 | Phillips Petroleum Company | Production of high-octane, unleaded motor fuel by alkylation of isobutane with isoamylenes obtained by dehydrogenation of isopentane |
-
1993
- 1993-07-12 US US08/088,942 patent/US5382744A/en not_active Expired - Lifetime
-
1994
- 1994-04-28 CA CA002122377A patent/CA2122377C/en not_active Expired - Fee Related
- 1994-07-05 AU AU66143/94A patent/AU659778B2/en not_active Ceased
- 1994-07-11 KR KR1019940016669A patent/KR100278082B1/ko not_active IP Right Cessation
- 1994-07-11 JP JP6158916A patent/JP2886090B2/ja not_active Expired - Fee Related
- 1994-07-11 FI FI943297A patent/FI113166B/fi not_active IP Right Cessation
- 1994-07-12 AT AT94110813T patent/ATE172705T1/de not_active IP Right Cessation
- 1994-07-12 EP EP94110813A patent/EP0634382B1/en not_active Expired - Lifetime
- 1994-07-12 DE DE69414193T patent/DE69414193T2/de not_active Expired - Fee Related
- 1994-07-12 SG SG1996005011A patent/SG50562A1/en unknown
- 1994-07-12 ES ES94110813T patent/ES2122100T3/es not_active Expired - Lifetime
- 1994-07-12 DK DK94110813T patent/DK0634382T3/da active
Also Published As
Publication number | Publication date |
---|---|
FI943297A0 (fi) | 1994-07-11 |
SG50562A1 (en) | 1998-07-20 |
JPH07145085A (ja) | 1995-06-06 |
AU659778B2 (en) | 1995-05-25 |
DE69414193T2 (de) | 1999-04-01 |
EP0634382B1 (en) | 1998-10-28 |
CA2122377C (en) | 1998-10-13 |
ATE172705T1 (de) | 1998-11-15 |
US5382744A (en) | 1995-01-17 |
DK0634382T3 (da) | 1999-07-05 |
JP2886090B2 (ja) | 1999-04-26 |
KR100278082B1 (ko) | 2001-01-15 |
EP0634382A1 (en) | 1995-01-18 |
FI113166B (fi) | 2004-03-15 |
DE69414193D1 (de) | 1998-12-03 |
AU6614394A (en) | 1995-01-19 |
CA2122377A1 (en) | 1995-01-13 |
FI943297A (fi) | 1995-01-13 |
ES2122100T3 (es) | 1998-12-16 |
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