ES8607272A1 - Procedimiento para la metilacion de un homologo no alfa del tocoferol - Google Patents

Procedimiento para la metilacion de un homologo no alfa del tocoferol

Info

Publication number
ES8607272A1
ES8607272A1 ES545838A ES545838A ES8607272A1 ES 8607272 A1 ES8607272 A1 ES 8607272A1 ES 545838 A ES545838 A ES 545838A ES 545838 A ES545838 A ES 545838A ES 8607272 A1 ES8607272 A1 ES 8607272A1
Authority
ES
Spain
Prior art keywords
tocopherol
alpha
vapor
liquid phase
methylation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES545838A
Other languages
English (en)
Other versions
ES545838A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel Corp
Original Assignee
Henkel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Corp filed Critical Henkel Corp
Publication of ES8607272A1 publication Critical patent/ES8607272A1/es
Publication of ES545838A0 publication Critical patent/ES545838A0/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
    • C07D311/58—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4
    • C07D311/70—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4 with two hydrocarbon radicals attached in position 2 and elements other than carbon and hydrogen in position 6
    • C07D311/72—3,4-Dihydro derivatives having in position 2 at least one methyl radical and in position 6 one oxygen atom, e.g. tocopherols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pyrane Compounds (AREA)

Abstract

PROCEDIMIENTO PARA LA METILACION DE UN HOMOLOGO NO ALFA DEL TOCOFEROL. SE OBTIENE PONIENDO EN CONTACTO EL HOMOLOGO NO ALFA DEL TOCOFEROL CON UN AGENTE DE ALQUILACION TAL COMO METANOL, FORMALDEHIDO O ETER DIMETILICO DURANTE UN PERIODO DE TIEMPO SUFICIENTE A UNA TEMPERATURA EN EL INTERVALO DE APROXIMADAMENTE 300JC A APROXIMADAMENTE 550JC EN PRESENCIA DE UN CATALIZADOR DE ALQUILACION. LA METILACION OCURRIRA EN UNA CANTIDAD SUSTANCIAL, PRODUCIENDO ALFATOCOFEROL.
ES545838A 1984-09-18 1985-08-02 Procedimiento para la metilacion de un homologo no alfa del tocoferol Expired ES8607272A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US65172684A 1984-09-18 1984-09-18

Publications (2)

Publication Number Publication Date
ES8607272A1 true ES8607272A1 (es) 1986-06-01
ES545838A0 ES545838A0 (es) 1986-06-01

Family

ID=24613975

Family Applications (1)

Application Number Title Priority Date Filing Date
ES545838A Expired ES8607272A1 (es) 1984-09-18 1985-08-02 Procedimiento para la metilacion de un homologo no alfa del tocoferol

Country Status (4)

Country Link
EP (1) EP0176690A1 (es)
JP (1) JPS6172776A (es)
AU (1) AU4567185A (es)
ES (1) ES8607272A1 (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5932748A (en) * 1997-06-06 1999-08-03 Roche Vitamins Inc. Process for permethylating non-α-tocopherols to produce α-tocopherol

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2519863A (en) * 1949-05-14 1950-08-22 Eastman Kodak Co Conversion of beta-, gamma-, and delta-tocopherol to alpha-tocopherol by aminoalkylation and reduction
GB1031495A (en) * 1964-01-24 1966-06-02 Eisai Co Ltd Process for producing ª‡-tocopherol having a high vitamin e activity
US4239691A (en) * 1979-06-04 1980-12-16 Eastman Kodak Company Conversion of non-alpha-tocopherols to alpha-tocopherols

Also Published As

Publication number Publication date
EP0176690A1 (en) 1986-04-09
AU4567185A (en) 1986-03-27
ES545838A0 (es) 1986-06-01
JPS6172776A (ja) 1986-04-14

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