ES8405352A1 - Procedimiento continuo para preparar alcoxidos de metales alcalinos. - Google Patents
Procedimiento continuo para preparar alcoxidos de metales alcalinos.Info
- Publication number
- ES8405352A1 ES8405352A1 ES521310A ES521310A ES8405352A1 ES 8405352 A1 ES8405352 A1 ES 8405352A1 ES 521310 A ES521310 A ES 521310A ES 521310 A ES521310 A ES 521310A ES 8405352 A1 ES8405352 A1 ES 8405352A1
- Authority
- ES
- Spain
- Prior art keywords
- reactor
- alkali metal
- alcohol
- metal hydroxide
- phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 5
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- 150000004703 alkoxides Chemical class 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- -1 alkali metal alkoxides Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 230000008016 vaporization Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/11—Esters of phosphoric acids with hydroxyalkyl compounds without further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/34—Separation; Purification; Stabilisation; Use of additives
- C07C41/40—Separation; Purification; Stabilisation; Use of additives by change of physical state, e.g. by crystallisation
- C07C41/42—Separation; Purification; Stabilisation; Use of additives by change of physical state, e.g. by crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/091—Esters of phosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Saccharide Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
PROCEDIMIENTO CONTINUO PARA PREPARAR ALCOXIDOS DE METALES ALCALINOS.COMPRENDE LAS ETAPAS DE: A) INTRODUCIR CONTINUAMENTE UNA SOLUCION ACUOSA DE UN HIDROXIDO DE METAL ALCALINO EN LA SECCION SUPERIOR DE UN REACTOR DE COLUMNA; B) VAPORIZAR UN ALCOHOL ALIFATICO, DE FORMULA R1-R2COH-R3, DONDE R1, R2 Y R3 SON HIDROGENO Y RADICALES ALQUILO O ALCOXIALQUILO CON C 1 A 18, Y ALIMENTAR EL ALCOHOL VAPORIZADO A LA SECCION INFERIOR DEL REACTOR DE COLUMNA EN PROPORCION DE 2 A 4 MOLES DE ALCOHOL POR MOL DE HIDROXIDO DE METAL ALCALINO INTRODUCIDO EN EL REACTOR DE LA COLUMNA;C) REACCIONAR EL ALCOHOL ALIFATICO CON EL HIDROXIDO DE METAL ALCALINO EN EL REACTOR DE COLUMNA; D) SEPARAR A LA VEZ EL AGUA DE LA SOLUCION DE HIDROXIDO DE METAL ALCALINO Y DE LA FORMACION DE ALCOXIDO DE LA SECCION SUPERIOR DEL REACTOR DE COLUMNA EN FORMA DE UN AZEOTROPO; E) CONDENSAR Y SEPARAR CONTINUAMENTE EL AZEOTROPO EN UNA FASE ALCOHOLICA Y UNA FASE ACUOSA; Y F) RECUPERAR EL PRODUCTO DE REACCION ANHIDRO QUE COMPRENDE EL PRODUCTO ALCOXIDO Y ALCOHOL ALIFATICO DE UNA SECCION INFERIOR DEL REACTOR.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US36626282A | 1982-04-07 | 1982-04-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
ES521310A0 ES521310A0 (es) | 1984-06-01 |
ES8405352A1 true ES8405352A1 (es) | 1984-06-01 |
Family
ID=23442314
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES521310A Expired ES8405352A1 (es) | 1982-04-07 | 1983-04-07 | Procedimiento continuo para preparar alcoxidos de metales alcalinos. |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0091425B1 (es) |
JP (1) | JPS6039658B2 (es) |
AT (1) | ATE26831T1 (es) |
CA (1) | CA1199035A (es) |
DE (1) | DE3371197D1 (es) |
ES (1) | ES8405352A1 (es) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3413212C1 (de) * | 1984-04-07 | 1985-09-12 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Herstellung von wasserfreiem Kalium-tert.-butoxid |
DE3701268C1 (de) * | 1987-01-17 | 1988-04-14 | Dynamit Nobel Ag | Verfahren zur kontinuierlichen Herstellung von Kalium-tert.-butoxid |
DE19849353A1 (de) * | 1998-10-27 | 2000-05-04 | Degussa | Magnesiumethoxid mit hohem Grobkornanteil, Verfahren zu seiner Herstellung und seine Verwendung |
DE19956558C2 (de) * | 1999-11-24 | 2003-10-02 | Chemetall Gmbh | Konzentrierte, stabile Alkalialkoholatlösungen |
DE102007025904A1 (de) * | 2007-06-01 | 2008-12-04 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Alkalimetallalkoholaten |
US20090134369A1 (en) * | 2007-11-26 | 2009-05-28 | Applied Nanoworks, Inc. | Metal alkoxides, apparatus for manufacturing metal alkoxides, related methods and uses thereof |
CN102584546A (zh) * | 2011-09-26 | 2012-07-18 | 盘锦兴福化工有限公司 | 2,3—二氟苯乙醚的合成方法 |
US11945767B2 (en) | 2019-12-18 | 2024-04-02 | Basf Se | Method for producing metal alcoholates |
EP4255875B1 (en) | 2020-12-04 | 2024-10-02 | Basf Se | Process for preparing metal alkoxides by transalcoholisation |
CN114591143B (zh) * | 2022-03-16 | 2024-06-21 | 齐翔华利新材料有限公司 | 一种甲基烯丙醇钠的制备方法 |
WO2024120883A1 (en) | 2022-12-07 | 2024-06-13 | Evonik Operations Gmbh | Improved process for preparing metal alkoxide compounds |
WO2024125775A1 (de) | 2022-12-14 | 2024-06-20 | Evonik Operations Gmbh | Verbessertes verfahren zur herstellung von metallalkoholatverbindungen |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1712830A (en) * | 1923-10-20 | 1929-05-14 | Nat Aniline & Chem Co Inc | Alkali-metal alcoholates |
US2877274A (en) * | 1958-01-21 | 1959-03-10 | Du Pont | Production of sodium methoxide |
-
1983
- 1983-03-24 EP EP83890044A patent/EP0091425B1/en not_active Expired
- 1983-03-24 DE DE8383890044T patent/DE3371197D1/de not_active Expired
- 1983-03-24 AT AT83890044T patent/ATE26831T1/de not_active IP Right Cessation
- 1983-03-24 CA CA000424436A patent/CA1199035A/en not_active Expired
- 1983-04-06 JP JP58059415A patent/JPS6039658B2/ja not_active Expired
- 1983-04-07 ES ES521310A patent/ES8405352A1/es not_active Expired
Also Published As
Publication number | Publication date |
---|---|
EP0091425A2 (en) | 1983-10-12 |
DE3371197D1 (en) | 1987-06-04 |
JPS6039658B2 (ja) | 1985-09-06 |
EP0091425B1 (en) | 1987-04-29 |
ES521310A0 (es) | 1984-06-01 |
ATE26831T1 (de) | 1987-05-15 |
CA1199035A (en) | 1986-01-07 |
EP0091425A3 (en) | 1984-05-23 |
JPS58185531A (ja) | 1983-10-29 |
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