ES8402254A1 - Procedimiento para la esterificacion continua de acido metacrilico. - Google Patents
Procedimiento para la esterificacion continua de acido metacrilico.Info
- Publication number
- ES8402254A1 ES8402254A1 ES517511A ES517511A ES8402254A1 ES 8402254 A1 ES8402254 A1 ES 8402254A1 ES 517511 A ES517511 A ES 517511A ES 517511 A ES517511 A ES 517511A ES 8402254 A1 ES8402254 A1 ES 8402254A1
- Authority
- ES
- Spain
- Prior art keywords
- methacrylic acid
- water
- azeotrope
- esterification
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PROCEDIMIENTO PARA LA ESTERIFICACION CONTINUA DE ACIDO METACRILICO PARA OBTENER ESTERES INFERIORES DEL ACIDO METACRILICO, ESPECIALMENTE MTILESTER DE ACIDO METACRILICO. COMPRENDE LAS SIGUIENTES OPERACIONES: PRIMERA, SE INTRODUCE ACIDO METACRILICO Y UNA CANTIDAD POR LO MENOS EQUIVALENTE DE ALCANOL, EN UNA MEZCLA DE ESTERIFICACION QUE SE MANTIENE, MEDIANTE UN DISPOSITIVO DE CALEFACCION, A UNA TEMPERATURA COMPRENDIDA ENTRE 70 Y 170 GRADOS; SEGUNDA, SE INTRODUCE EN DICHA MEZCLA DE ESTERIFICACION UN ACIDO SULFONICO ORGANICO COMO CATALIZADOR DE ESTERIFICACION; Y POR ULTIMO, SE SEPARA DE FORMA CONTINUA EL AGUA FORMADA DURANTE LA ESTERIFICACION EN FORMA DE UN ACEOTROPO DE ESTER DE ACIDO METACRILICO-AGUA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19813146191 DE3146191A1 (de) | 1981-11-21 | 1981-11-21 | Verfahren zum kontinuierlichen verestern von methacrylsaeure |
Publications (2)
Publication Number | Publication Date |
---|---|
ES8402254A1 true ES8402254A1 (es) | 1984-01-16 |
ES517511A0 ES517511A0 (es) | 1984-01-16 |
Family
ID=6146896
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES517511A Granted ES517511A0 (es) | 1981-11-21 | 1982-11-19 | Procedimiento para la esterificacion continua de acido metacrilico. |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0080023B1 (es) |
JP (1) | JPS5892638A (es) |
CA (1) | CA1193282A (es) |
DE (2) | DE3146191A1 (es) |
ES (1) | ES517511A0 (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6081149A (ja) * | 1983-09-14 | 1985-05-09 | イー・アイ・デユポン・デ・ニモアス・アンド・カンパニー | n‐ブチルメタクリレートの製造方法 |
US4999452A (en) * | 1989-05-15 | 1991-03-12 | Union Carbide Chemicals And Plastics Company Inc. | Process for producing acrylic ester |
US5231222A (en) * | 1991-07-02 | 1993-07-27 | Union Carbide Chemicals & Plastics Technology Corporation | Esterification process |
DE19536178A1 (de) * | 1995-09-28 | 1997-04-03 | Basf Ag | Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Alkylestern der (Meth)acrylsäure |
DE19727234C1 (de) * | 1997-06-26 | 1999-07-15 | Basf Ag | Verfahren zur Herstellung eines Alkyl(meth)acrylats |
CA2252748A1 (en) * | 1997-11-17 | 1999-05-17 | Rohm And Haas Company | Process for preparing alkyl (meth) acrylates |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1211946A (fr) * | 1957-12-31 | 1960-03-18 | Standard Oil Co | Procédé de production d'alkyl esters d'acides aliphatiques non saturés |
DE1288596B (de) * | 1962-01-30 | 1969-02-06 | Knapsack Ag | Verfahren zur Herstellung von Acrylsaeure-n-butylester aus waessriger Acrylsaeure und n-Butanol |
DE2913218A1 (de) * | 1979-04-03 | 1980-10-23 | Bayer Ag | Verfahren zur herstellung von (meth)acrylsaeureestern |
-
1981
- 1981-11-21 DE DE19813146191 patent/DE3146191A1/de not_active Withdrawn
-
1982
- 1982-08-05 EP EP82107078A patent/EP0080023B1/de not_active Expired
- 1982-08-05 DE DE8282107078T patent/DE3261766D1/de not_active Expired
- 1982-11-18 CA CA000415870A patent/CA1193282A/en not_active Expired
- 1982-11-18 JP JP57201229A patent/JPS5892638A/ja active Pending
- 1982-11-19 ES ES517511A patent/ES517511A0/es active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS5892638A (ja) | 1983-06-02 |
EP0080023B1 (de) | 1985-01-02 |
CA1193282A (en) | 1985-09-10 |
DE3261766D1 (en) | 1985-02-14 |
DE3146191A1 (de) | 1983-05-26 |
ES517511A0 (es) | 1984-01-16 |
EP0080023A1 (de) | 1983-06-01 |
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