ES538269A0 - Procedimiento para preparar acidos a-acilaminocarboxilicos opticamente activos - Google Patents
Procedimiento para preparar acidos a-acilaminocarboxilicos opticamente activosInfo
- Publication number
- ES538269A0 ES538269A0 ES538269A ES538269A ES538269A0 ES 538269 A0 ES538269 A0 ES 538269A0 ES 538269 A ES538269 A ES 538269A ES 538269 A ES538269 A ES 538269A ES 538269 A0 ES538269 A0 ES 538269A0
- Authority
- ES
- Spain
- Prior art keywords
- optically active
- formula
- acids
- acilaminocarboxylic
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002253 acid Substances 0.000 title 1
- 150000007513 acids Chemical class 0.000 title 1
- 150000003283 rhodium Chemical class 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- -1 tetrafluoroborate Chemical compound 0.000 abstract 2
- YMRKZKDKJJCIHH-UHFFFAOYSA-N (4-diphenylphosphanylpyrrolidin-3-yl)-diphenylphosphane Chemical class C1NCC(P(C=2C=CC=CC=2)C=2C=CC=CC=2)C1P(C=1C=CC=CC=1)C1=CC=CC=C1 YMRKZKDKJJCIHH-UHFFFAOYSA-N 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 238000009876 asymmetric hydrogenation reaction Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 150000005673 monoalkenes Chemical class 0.000 abstract 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/36—Oxygen or sulfur atoms
- C07D207/40—2,5-Pyrrolidine-diones
- C07D207/416—2,5-Pyrrolidine-diones with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to other ring carbon atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2291—Olefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
- B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/04—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D207/10—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/12—Oxygen or sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/04—Indoles; Hydrogenated indoles
- C07D209/10—Indoles; Hydrogenated indoles with substituted hydrocarbon radicals attached to carbon atoms of the hetero ring
- C07D209/18—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D209/20—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals substituted additionally by nitrogen atoms, e.g. tryptophane
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/44—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D317/46—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
- C07D317/48—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
- C07D317/50—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to atoms of the carbocyclic ring
- C07D317/58—Radicals substituted by nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/572—Five-membered rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Pyrrole Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19843403194 DE3403194A1 (de) | 1984-01-31 | 1984-01-31 | Optisch aktive 3,4-bis-(diphenylphosphino)-pyrrolidine, diese als chirale liganden enthaltende rhodiumkomplexe und deren verwendung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES8603906A1 ES8603906A1 (es) | 1986-01-01 |
| ES538269A0 true ES538269A0 (es) | 1986-01-01 |
Family
ID=6226312
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES538269A Granted ES538269A0 (es) | 1984-01-31 | 1984-12-05 | Procedimiento para preparar acidos a-acilaminocarboxilicos opticamente activos |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4634775A (enExample) |
| EP (1) | EP0151282B1 (enExample) |
| JP (1) | JPS60185793A (enExample) |
| AT (1) | ATE37031T1 (enExample) |
| BR (1) | BR8500437A (enExample) |
| CA (1) | CA1238913A (enExample) |
| DD (1) | DD235190A5 (enExample) |
| DE (2) | DE3403194A1 (enExample) |
| ES (1) | ES538269A0 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3446303A1 (de) * | 1984-12-19 | 1986-06-19 | Degussa Ag, 6000 Frankfurt | Verfahren zur herstellung von optisch aktivem 1-benzyl-3,4-bis-(diphenylphosphino)-pyrrolidin |
| US4793949A (en) * | 1985-10-15 | 1988-12-27 | University Of Southern Mississippi | New vinyl monomers capable of forming side-chain liquid crystalline polymers and the resulting polymers |
| US4879398A (en) * | 1987-12-31 | 1989-11-07 | Monsanto Company | Process for producing 2,6-disubstituted tyrosine |
| DE3818435A1 (de) * | 1988-02-19 | 1989-08-31 | Hoechst Ag | Optisch aktive rhodiumkomplexe von 3,4-bis(diarylphosphino)-pyrrolidinen und ihre verwendung zur herstellung von phosphinothricin durch asymmetrische hydrierung |
| DE4001019A1 (de) * | 1990-01-16 | 1991-07-18 | Degussa | Verfahren zur asymmetrischen hydrierung von (alpha)-ketocarbonylverbindungen zu optisch aktiven (alpha)-hydroxycarbonylverbindungen |
| WO1992016536A1 (de) * | 1991-03-15 | 1992-10-01 | F. Hoffmann-La Roche Ag | Chirale phosphine |
| EP0512416B1 (de) * | 1991-05-03 | 1997-01-08 | Hoechst Aktiengesellschaft | Neue homochirale Diphosphine |
| DE4200415A1 (de) * | 1992-01-10 | 1993-07-15 | Bayer Ag | Enantiomerenreine 2-oxa-5,8-diazabicyclo(4.3.0)nonane sowie verfahren zu ihrer herstellung |
| US6004956A (en) * | 1992-01-10 | 1999-12-21 | Bayer Aktiengesellschaft | Enantiomerically pure 2-oxa-5,8-dizaabicyclo[4.3.0] nonanes and process for their preparation |
| CA2121308C (en) * | 1993-04-19 | 2001-07-24 | Toshihiro Omatsu | Rhodium-containing catalyst |
| IT1270082B (it) | 1994-07-12 | 1997-04-28 | Univ Degli Studi Milano | Difosfine eteroaromatiche come leganti chirali, complessi tra dette difosfine e metalli di transizione ed impiego di detti complessi come catalizzatori chirali |
| DE4425071C2 (de) | 1994-07-15 | 1996-08-29 | Degussa | Verfahren zur Herstellung optisch aktiver Pyrrolidine mit hoher Enantiomerenreinheit |
| DE19516968A1 (de) * | 1995-05-12 | 1996-11-14 | Basf Ag | Optisch aktive Phosphine, deren Herstellung, deren Metallkomplexe und Anwendung in der asymmetrischen Synthese |
| DE19622271A1 (de) * | 1996-06-03 | 1997-12-04 | Basf Ag | Chirale Verbindungen |
| DE19725643A1 (de) * | 1997-06-18 | 1998-12-24 | Basf Ag | Optisch aktive Diphosphinliganden |
| DE19725796A1 (de) * | 1997-06-18 | 1998-12-24 | Basf Ag | Herstellung optisch aktiver Phospholane, deren Metallkomplexe und Anwendung in der asymmetrischen Synthese |
| DE10002973A1 (de) * | 2000-01-24 | 2001-07-26 | Degussa | Polymere Diphosphinliganden für homogen lösliche Hydrierkatalysatoren, Verfahren zu deren Herstellung und Verwendung |
| DE10002976A1 (de) | 2000-01-24 | 2001-07-26 | Degussa | Molekulargewichtsvergrößerte Liganden für asymmetrische homogen lösliche Hydrierkatalysatoren, Verfahren zu deren Herstellung und Verwendung |
| KR100476584B1 (ko) * | 2002-07-05 | 2005-03-17 | 한국과학기술연구원 | 비대칭 알릴 치환반응에 유용한 키랄피롤리디닐(비스포스피노다이아미드) 유도체 |
| US20050101813A1 (en) * | 2003-09-08 | 2005-05-12 | Degussa Ag, | Molecular weight-enlarged ligands for asymmetric, homogeneously soluble hydrogenation catalysts, process for the production thereof and use |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4343741A (en) * | 1981-04-22 | 1982-08-10 | Hoffmann-La Roche Inc. | Chiral phosphines |
-
1984
- 1984-01-31 DE DE19843403194 patent/DE3403194A1/de not_active Withdrawn
- 1984-12-05 ES ES538269A patent/ES538269A0/es active Granted
- 1984-12-14 EP EP84115470A patent/EP0151282B1/de not_active Expired
- 1984-12-14 AT AT84115470T patent/ATE37031T1/de not_active IP Right Cessation
- 1984-12-14 DE DE8484115470T patent/DE3473879D1/de not_active Expired
-
1985
- 1985-01-02 US US06/688,360 patent/US4634775A/en not_active Expired - Fee Related
- 1985-01-29 DD DD85272830A patent/DD235190A5/de unknown
- 1985-01-30 CA CA000473217A patent/CA1238913A/en not_active Expired
- 1985-01-31 BR BR8500437A patent/BR8500437A/pt unknown
- 1985-01-31 JP JP60015665A patent/JPS60185793A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60185793A (ja) | 1985-09-21 |
| JPH0314318B2 (enExample) | 1991-02-26 |
| ES8603906A1 (es) | 1986-01-01 |
| ATE37031T1 (de) | 1988-09-15 |
| DD235190A5 (de) | 1986-04-30 |
| DE3403194A1 (de) | 1985-08-01 |
| EP0151282A1 (de) | 1985-08-14 |
| BR8500437A (pt) | 1985-09-10 |
| US4634775A (en) | 1987-01-06 |
| CA1238913A (en) | 1988-07-05 |
| DE3473879D1 (en) | 1988-10-13 |
| EP0151282B1 (de) | 1988-09-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BR8500437A (pt) | Processo para a obtencao de acidos alfa-aminocarboxilicos oticamente ativos | |
| SU597322A3 (ru) | Каталитический элемент дл окислени аммиака | |
| KR880002802A (ko) | 광학활성 2급 아릴아민의 제조방법 | |
| ES427527A1 (es) | Procedimiento de preparacion de una composicion tintorea para fibras queratinicas. | |
| HUP0100419A2 (hu) | Átmenetifémekkel katalizált eljárás, a katalizátorokhoz alkalmazható királis ligandumok, és előállításuk | |
| KR840006492A (ko) | 플라티늄-디아민 착화물의 제조 방법 | |
| JPS5561937A (en) | Catalyst for asymmetric hydrogenation | |
| IE40048B1 (en) | Improved process for producing -6-deoxytetracyclines | |
| ATE340192T1 (de) | Lagerstabile zusammensetzung enthaltend quadratsäure-aktivierten träger, der für die immobilisierung von amingruppen enthaltenden substanzen benutzt werden kann | |
| ES550091A0 (es) | Procedimiento para preparar 1-bencil-3,4-bis-(difenilfosfino)-pirrolidina opticamente activa | |
| ES2061747T3 (es) | Complejos de rodio opticamente activos de 3,4-bis (diarilfosfino) pirrolidinas y su utilizacion para la preparacion de fosfinotricina mediante hidrogenacion asimetrica. | |
| BE814869A (fr) | Nouveaux derives d'acides 11-alcoxy prostanoiques utiles notamment comme hypotenseurs | |
| ATE605T1 (de) | Aminosaeuren und mineralsalze enthaltende infusionsloesung. | |
| ES423853A1 (es) | Un procedimiento para la preparacion de fluorogenos deriva-dos de furanona. | |
| IT1016736B (it) | Catalizzatore per scambio idrogeno amina d | |
| FI52408C (fi) | Kantoaineeseen sidotun entsymaattisen kasvualustan koostumus käytettäv äksi entsymaattisissa reaktioissa. | |
| KR860001812A (ko) | 신규 벤조디아제핀의 제조방법 | |
| JPS55121837A (en) | Asymmetric hydrogenation catalyst | |
| BR8601244A (pt) | Processo para a preparacao de um composto azo hidrossoluvel,bem como processo para tingir(colorir)material contendo grupos hidroxi e/ou carbonamida | |
| GB1501559A (en) | Asymmetric hydrogenation of n-(alkyl-styryl)-amides | |
| ES449505A1 (es) | Procedimiento para preparar colorantes que contienen un gru-po dihalogeno-5-cianopirimidinilo. | |
| SE7607930L (sv) | Kugghjulspump eller- motor for hogtrycksmedium | |
| FR2277810A1 (fr) | Acides 1,4-bis-formyl-cyclohexane-polycarboxyliques utilisables comme agents antitartre | |
| ES442022A1 (es) | Procedimiento para la preparacion de derivados de propanol. | |
| JPS5317640A (en) | Process for producing low salttcontent thick solution of coblttand chromee1 22 complex compound dyes nonncontaining sulfonic acid groups |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19970303 |