ES481656A1 - Prepn. of propylene! copolymer for foaming sealable foils - by catalytic random copolymerisation to high reduced specific viscosity and degradation by melt extrusion - Google Patents
Prepn. of propylene! copolymer for foaming sealable foils - by catalytic random copolymerisation to high reduced specific viscosity and degradation by melt extrusionInfo
- Publication number
- ES481656A1 ES481656A1 ES481656A ES481656A ES481656A1 ES 481656 A1 ES481656 A1 ES 481656A1 ES 481656 A ES481656 A ES 481656A ES 481656 A ES481656 A ES 481656A ES 481656 A1 ES481656 A1 ES 481656A1
- Authority
- ES
- Spain
- Prior art keywords
- copolymer
- melt extrusion
- specific viscosity
- reduced specific
- prepn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/50—Partial depolymerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
A C3H6 copolymer, (I), is produced in 2 steps, by (I) preparing a random copolymer having reduced specific viscosity, RSV, 4-8 dl./g., by copolymerising a mixt. contg. by wt., either (a) 94-5-99.5% C3H6 with 0.5-6.5% C2H4 or (b) 85-97.5% C3H6, 0.5-5% C2H4 and 2-10%, w.r.t. total mixt., of another l-olefin having formula CH2=CHR (where R is 2-6C alkyl) in the presence of H2 as mol. wt. regulator, a catalyst and opt. a dispersant, and (2) degrading the copolymer by melt extrusion at 200-300 degrees C. in the absence of O2 and radical-donors, to reduce mol. wt. to RSV 1.8-3.5 dl./g. The catalyst in (1) consists of a Ti-contg. solid component, an organic Al component and opt. 1 or more cpds. having electron-donor character. (I) forms foils which retain their sealability also after preliminary printing. By controlling RSV in step (1), soluble polymer quantity is no higher than that obtd. by C3H6 homoplymerisation. The suspension is easily pumped and polymer powder is easily separated.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2827764A DE2827764C2 (en) | 1978-06-24 | 1978-06-24 | Process for the production of a polypropylene suitable for sealable films |
Publications (1)
Publication Number | Publication Date |
---|---|
ES481656A1 true ES481656A1 (en) | 1980-02-16 |
Family
ID=6042643
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES481656A Expired ES481656A1 (en) | 1978-06-24 | 1979-06-18 | Prepn. of propylene! copolymer for foaming sealable foils - by catalytic random copolymerisation to high reduced specific viscosity and degradation by melt extrusion |
Country Status (5)
Country | Link |
---|---|
AU (1) | AU526083B2 (en) |
DE (1) | DE2827764C2 (en) |
ES (1) | ES481656A1 (en) |
FR (1) | FR2429231B1 (en) |
ZA (1) | ZA792833B (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4384024A (en) * | 1981-03-19 | 1983-05-17 | Imperial Chemical Industries Limited | Composite heat-sealable films |
DE4000695C2 (en) * | 1990-01-12 | 1997-07-03 | Huels Chemische Werke Ag | Largely amorphous polyalphaolefins with a narrow molecular weight distribution, process for their production and use for carpet heavy-duty coating compositions or hot melt adhesives |
BE1012068A3 (en) | 1998-07-10 | 2000-04-04 | Solvay | HOLLOW bioriented BASED terpolymers PROPYLENE AND METHOD FOR MAKING SUCH HOLLOW. |
DE602006004987D1 (en) | 2006-07-10 | 2009-03-12 | Borealis Tech Oy | Electrical insulating film |
EP2208749B1 (en) | 2006-07-10 | 2015-12-16 | Borealis Technology Oy | Biaxially oriented polypropylene films |
EP1967547A1 (en) | 2006-08-25 | 2008-09-10 | Borealis Technology OY | Extrusion coated substrate |
ATE432165T1 (en) † | 2006-12-18 | 2009-06-15 | Borealis Tech Oy | HIGH MELTING POINT TERPOLYMER |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL298986A (en) * | 1963-01-09 | 1900-01-01 | ||
GB1135542A (en) * | 1966-02-23 | 1968-12-04 | Asahi Chemical Ind | Process for producing polyolefin fibres |
US3562788A (en) * | 1967-06-08 | 1971-02-09 | Eastman Kodak Co | Thermal degradation of polyolefins |
AT290114B (en) * | 1968-08-12 | 1971-05-25 | Basf Ag | Process for the production of easily further processable granular propylene polymer |
DE2637990A1 (en) * | 1976-08-24 | 1978-03-02 | Hoechst Ag | PROPYLENE TERPOLYMER |
DE2637978B2 (en) * | 1976-08-24 | 1979-10-25 | Hoechst Ag, 6000 Frankfurt | Heat-sealable plastic film and process for its production |
DE2637991A1 (en) * | 1976-08-24 | 1978-03-02 | Hoechst Ag | PLASTIC FILM MADE OF COPOLYMERS AND METHOD FOR MANUFACTURING THE SAME |
-
1978
- 1978-06-24 DE DE2827764A patent/DE2827764C2/en not_active Expired
-
1979
- 1979-06-08 ZA ZA792833A patent/ZA792833B/en unknown
- 1979-06-18 ES ES481656A patent/ES481656A1/en not_active Expired
- 1979-06-21 AU AU48261/79A patent/AU526083B2/en not_active Ceased
- 1979-06-25 FR FR7916235A patent/FR2429231B1/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE2827764A1 (en) | 1980-01-10 |
AU4826179A (en) | 1980-01-03 |
FR2429231A1 (en) | 1980-01-18 |
ZA792833B (en) | 1980-07-30 |
DE2827764C2 (en) | 1988-01-21 |
FR2429231B1 (en) | 1986-03-14 |
AU526083B2 (en) | 1982-12-16 |
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