ES471561A1 - Un procedimiento para efectuar una isomerizacion catalitica de compuestos hidrocarbonados monociclicos sustituidos con metilo - Google Patents
Un procedimiento para efectuar una isomerizacion catalitica de compuestos hidrocarbonados monociclicos sustituidos con metiloInfo
- Publication number
- ES471561A1 ES471561A1 ES471561A ES471561A ES471561A1 ES 471561 A1 ES471561 A1 ES 471561A1 ES 471561 A ES471561 A ES 471561A ES 471561 A ES471561 A ES 471561A ES 471561 A1 ES471561 A1 ES 471561A1
- Authority
- ES
- Spain
- Prior art keywords
- aromatic hydrocarbon
- zeolite
- hydrocarbon compounds
- hydrogen
- catalytic isomerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000004945 aromatic hydrocarbons Chemical class 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 238000006317 isomerization reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 125000002950 monocyclic group Chemical group 0.000 title 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 239000010457 zeolite Substances 0.000 abstract 3
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 229910017464 nitrogen compound Inorganic materials 0.000 abstract 1
- 150000002830 nitrogen compounds Chemical class 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
- C07C5/2732—Catalytic processes
- C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Un procedimiento para efectuar una isomerización catalítica de compuestos hidrocarbonados aromáticos mocíclicos sustituidos con metilo, de 8 a 10 átomos de carbono, contenidos en un material de alimentación que contiene también etilbenceno, que comprende poner en contacto dicho material de alimentación en fase de vapor con un catalizador que comprende una zeolita de aluminosolicato cristalina que tiene un índice de restricción en el intervalo de 1 a 12, conteniendo dicha zeolita hidrógena, precursor de hidrógeno y/o cationes metálicos del grupo VIII, a una temperatura de 316ºC a 482ºC, una presión de 0 kg/cm2 manométricos a 35 kg/cm2 monométricos, una relación molar hidrógeno/hidrocarburos de 0 a 10 y una velocidad espacial horaria en peso entre 0,1 a 200, habiéndose puesto en contacto dicho catalizador con uno o más compuestos de nitrógeno básicos o sus precursores, siendo la relación resultante de átomos de nitrógeno/átomos de aluminio en la zeolita de 0,01 a 1,0.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US81391177A | 1977-07-08 | 1977-07-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES471561A1 true ES471561A1 (es) | 1979-01-16 |
Family
ID=25213739
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES471561A Expired ES471561A1 (es) | 1977-07-08 | 1978-07-07 | Un procedimiento para efectuar una isomerizacion catalitica de compuestos hidrocarbonados monociclicos sustituidos con metilo |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4158676A (es) |
| EP (1) | EP0000432B1 (es) |
| JP (1) | JPS6024771B2 (es) |
| AR (1) | AR223821A1 (es) |
| CA (1) | CA1098918A (es) |
| DE (1) | DE2862267D1 (es) |
| ES (1) | ES471561A1 (es) |
| IN (1) | IN149346B (es) |
| IT (1) | IT1109966B (es) |
| MX (1) | MX4173E (es) |
| ZA (1) | ZA783919B (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1121967B (it) * | 1979-06-29 | 1986-04-23 | Montedison Spa | Zeolite mb 28 particolarmente adatta per la catalisi dell'isomerizzazione degli xileni |
| US4300011A (en) * | 1980-04-28 | 1981-11-10 | Mobil Oil Corporation | Selective production of aromatics |
| US4302323A (en) * | 1980-05-12 | 1981-11-24 | Mobil Oil Corporation | Catalytic hydroconversion of residual stocks |
| US4533298A (en) * | 1982-12-02 | 1985-08-06 | Westinghouse Electric Corp. | Turbine blade with integral shroud |
| US5100535A (en) * | 1987-12-03 | 1992-03-31 | Mobil Oil Corporation | Method for controlling hydrocracking operations |
| US5419830A (en) * | 1985-07-26 | 1995-05-30 | Mobil Oil Corporation | Method for controlling hydrocracking and isomerization dewaxing |
| US5043512A (en) * | 1988-10-06 | 1991-08-27 | Mobil Oil Corp. | Alkylaromatic isomerization process |
| US5030787A (en) * | 1990-01-24 | 1991-07-09 | Mobil Oil Corp. | Catalytic disproportionation/transalkylation utilizing a C9+ aromatics feed |
| US5905181A (en) * | 1997-12-29 | 1999-05-18 | Uop Llc | Process for the isomerization of paraffins |
| US6333289B1 (en) | 1998-04-10 | 2001-12-25 | Institut Francais Du Petrole | Process for activating catalysts for isomerizing aromatic compounds containing eight carbon atoms |
| US6313363B1 (en) | 1998-04-10 | 2001-11-06 | Institut Francais Du Petrole | Process for isomerizing aromatic compounds containing eight carbon atoms |
| FR2777207B1 (fr) * | 1998-04-10 | 2000-05-19 | Inst Francais Du Petrole | Procede d'activation des catalyseurs d'isomerisation des composes aromatiques a huit atomes de carbone |
| FR2784686B1 (fr) | 1998-09-10 | 2001-02-23 | Inst Francais Du Petrole | Procede d'isomerisation des composes aromatiques a huit atomes de carbone en deux etapes successives et utilisant un catalyseur active |
| US6051744A (en) * | 1998-12-17 | 2000-04-18 | Chevron Chemical Company Llc | Low pressure hydrodealkylation of ethylbenzene and xylene isomerization |
| FR2795343B1 (fr) * | 1999-06-22 | 2001-08-03 | Inst Francais Du Petrole | Procede de pretraitement dans des conditions severes d'un catalyseur a base de zeolithe euo |
| KR102160602B1 (ko) * | 2017-12-27 | 2020-09-28 | 한화솔루션 주식회사 | 탄화수소 함유 용액 내의 방향족 함량의 측정 방법 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3293314A (en) * | 1965-03-04 | 1966-12-20 | Chevron Res | Equilibration of lower alkyl substituted aromatic hydrocarbons |
| US3644200A (en) * | 1968-12-23 | 1972-02-22 | Union Oil Co | Ammoniated zeolite catalysts |
| US3856873A (en) * | 1973-09-13 | 1974-12-24 | Mobil Oil Corp | Xylene isomerization |
| US3856872A (en) * | 1973-09-13 | 1974-12-24 | Mobil Oil Corp | Xylene isomerization |
| US3992466A (en) * | 1975-08-13 | 1976-11-16 | Mobil Oil Corporation | Hydrocarbon conversion |
| DE2558035A1 (de) * | 1975-12-22 | 1977-06-23 | Mobil Oil Corp | Kombiniertes verfahren zur katalytischen umwandlung und hydrodealkylierung von kohlenwasserstoffen |
-
1978
- 1978-06-14 US US05/915,414 patent/US4158676A/en not_active Expired - Lifetime
- 1978-06-27 CA CA306,268A patent/CA1098918A/en not_active Expired
- 1978-06-28 IN IN713/CAL/78A patent/IN149346B/en unknown
- 1978-07-05 EP EP78300119A patent/EP0000432B1/en not_active Expired
- 1978-07-05 DE DE7878300119T patent/DE2862267D1/de not_active Expired
- 1978-07-06 MX MX787208U patent/MX4173E/es unknown
- 1978-07-07 ZA ZA783919A patent/ZA783919B/xx unknown
- 1978-07-07 IT IT25466/78A patent/IT1109966B/it active
- 1978-07-07 ES ES471561A patent/ES471561A1/es not_active Expired
- 1978-07-07 AR AR272883A patent/AR223821A1/es active
- 1978-07-07 JP JP53082135A patent/JPS6024771B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0000432A1 (en) | 1979-01-24 |
| EP0000432B1 (en) | 1983-05-25 |
| ZA783919B (en) | 1980-02-27 |
| IT1109966B (it) | 1985-12-23 |
| US4158676A (en) | 1979-06-19 |
| MX4173E (es) | 1982-01-15 |
| JPS5419921A (en) | 1979-02-15 |
| AR223821A1 (es) | 1981-09-30 |
| IN149346B (es) | 1981-10-31 |
| DE2862267D1 (en) | 1983-07-07 |
| JPS6024771B2 (ja) | 1985-06-14 |
| CA1098918A (en) | 1981-04-07 |
| IT7825466A0 (it) | 1978-07-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES471561A1 (es) | Un procedimiento para efectuar una isomerizacion catalitica de compuestos hidrocarbonados monociclicos sustituidos con metilo | |
| Gnep et al. | Conversion of light alkanes to aromatic hydrocarbons: II. Role of gallium species in propane transformation on GaZSM5 catalysts | |
| Pines | The chemistry of catalytic hydrocarbon conversions | |
| GB1402503A (en) | Vapour-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation | |
| KR910016652A (ko) | 방향족 화합물의 접촉-수첨탈알킬화 | |
| GB1525323A (en) | Alkylation in presence of thermally crystalline aluminosilicate catalyst | |
| KR860000234A (ko) | 에탄올 에틸렌으로 산화탈수소화하는 방법 | |
| KR900003336A (ko) | 중알킬레이트 부산물로부터의 화이트오일의 제조방법 | |
| KR850002451A (ko) | 방향족 탄화수소의 알킬화공정 | |
| KR910700215A (ko) | 탄화수소를 탈수 또는 탈수소 고리화하기 위한 방법 및 촉매 | |
| ES2039651T3 (es) | Procedimiento de doble funcion para la isomerizacion y la apertura de anillos de una corriente de alimentacion que contiene parafinas e hidrocarburos ciclicos. | |
| KR960703102A (ko) | 액상 에틸벤젠 합성방법(Liquid phase ethylbenzene synthesis) | |
| KR860007185A (ko) | 알킬방향족 화합물의 탈수소화방법 | |
| GB1039246A (en) | Process for the catalytic rearrangement of alkyl aromatic hydrocarbons | |
| ES467610A1 (es) | Procedimiento de conversion de hidrocarburos | |
| GB1536109A (en) | Isomerization of monocyclic alkyl aromatic hydrocarbons | |
| KR930701367A (ko) | 알킬방향족 화합물의 이성질체화 방법 | |
| US2369377A (en) | Method of preparing sulphur compounds | |
| RO81243B (ro) | Catalizator pentru dezalchilarea alchilbenzenilor prin tratare cu vapori de apa | |
| US2577788A (en) | Concurrent dealkylation of aromatic hydrocarbons and dehydrogenation of naphthenic hydrocarbons | |
| KR920701087A (ko) | C_9^+ 방향족의 접촉전환법 | |
| GB1351983A (en) | Isomerization process employing a heterogeneous catalyst | |
| US3728410A (en) | Hydrocarbon conversion | |
| KR937000388A (ko) | 나프탈렌 알킬화 방법 | |
| KR900012871A (ko) | 알킬-치환 방향족 탄화수소의 제조방법 |