ES469145A1 - Oxydehydrogenation process for alkylaromatics - Google Patents

Oxydehydrogenation process for alkylaromatics

Info

Publication number
ES469145A1
ES469145A1 ES469145A ES469145A ES469145A1 ES 469145 A1 ES469145 A1 ES 469145A1 ES 469145 A ES469145 A ES 469145A ES 469145 A ES469145 A ES 469145A ES 469145 A1 ES469145 A1 ES 469145A1
Authority
ES
Spain
Prior art keywords
aromatic
aromatic compound
elements
group
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES469145A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of ES469145A1 publication Critical patent/ES469145A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyridine Compounds (AREA)

Abstract

A process of dehydrogenation of an alkyl aromatic compound to the corresponding alkenyl aromatic compound, wherein said alkyl aromatic compound contains at least one alkyl group of from 2 to 6 carbon atoms which is attached to a single aromatic ring, and that the aromatic group is selected from the group consisting of mononuclear aromatic, condensed ring dinuclear compounds and the corresponding nitrogen-containing heterocyclic aromatic compounds, which process comprises passing a gaseous mixture of the aromatic-aromatic compound, molecular oxygen and optionally a gas diluent, on a catalyst, at a temperature of from about 300 to 650º c, said catalyst having the composition represented by the following empirical formula Aa mb m1c m11d be py ox Where a is an alkali metal and/or thallium; m is one or more of the elements nickel, cobalt, copper, manganese, magnesium, zinc, calcium, niobium, tantalum, strontium or barium; is one or more of the elements iron, chromium, uranium, thorium, vanadium, titanium, lanthanum or other rare earths; m11 is one or more of the elements tin, boron, lead, germanium, aluminum, tungsten or molybdenum; b is bismuth, tellurium, arsenic, antimony, cadmium or combinations thereof: p is phosphorus, and where a a and have the following values: a = 0 to 20; b = 0 to 20; c = 0 to 20; d = 0 to 4; e = 0.1 to 20; y = 8 to 16; x = number of oxygens required to satisfy the valence requirements of the other elements present; and where the sum of b c e is greater than 1. (Machine-translation by Google Translate, not legally binding)
ES469145A 1977-05-02 1978-04-26 Oxydehydrogenation process for alkylaromatics Expired ES469145A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US79263777A 1977-05-02 1977-05-02

Publications (1)

Publication Number Publication Date
ES469145A1 true ES469145A1 (en) 1978-11-16

Family

ID=25157563

Family Applications (2)

Application Number Title Priority Date Filing Date
ES469145A Expired ES469145A1 (en) 1977-05-02 1978-04-26 Oxydehydrogenation process for alkylaromatics
ES470908A Expired ES470908A1 (en) 1977-05-02 1978-06-19 Oxydehydrogenation process for alkylaromatics

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES470908A Expired ES470908A1 (en) 1977-05-02 1978-06-19 Oxydehydrogenation process for alkylaromatics

Country Status (16)

Country Link
JP (1) JPS53135940A (en)
BE (1) BE866403A (en)
BR (1) BR7802706A (en)
CA (1) CA1117120A (en)
CS (1) CS199528B2 (en)
DD (1) DD135897A5 (en)
DE (1) DE2816946A1 (en)
EG (1) EG13250A (en)
ES (2) ES469145A1 (en)
FR (1) FR2389590A1 (en)
GB (2) GB1598509A (en)
IN (1) IN148087B (en)
IT (1) IT1094807B (en)
NL (1) NL7804618A (en)
NO (1) NO781508L (en)
PT (1) PT67944B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2849637A1 (en) * 1978-11-16 1980-05-29 Hoechst Ag CARRIER CATALYST AND METHOD FOR THE PRODUCTION THEREOF
DE2849715A1 (en) * 1978-11-16 1980-05-29 Hoechst Ag CARRIER CATALYST AND METHOD FOR THE PRODUCTION THEREOF
ATE7861T1 (en) * 1980-07-18 1984-06-15 Mitsubishi Chemical Industries Limited CATALYTIC COMPOSITION, PROCESS FOR ITS PREPARATION AND ITS USE.
US4777313A (en) * 1983-08-12 1988-10-11 Atlantic Richfield Company Boron-promoted reducible metal oxides and methods of their use
JPH0764763B2 (en) * 1987-03-05 1995-07-12 東ソー株式会社 Method for producing methylstyrene
DE19530454A1 (en) * 1995-08-18 1997-02-20 Manfred Prof Dr Baerns Economical continuous oxidative dehydrogenation of propane to propene in high yield

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3641180A (en) * 1969-12-29 1972-02-08 Dow Chemical Co Method of dehydrogenating compounds
US3925499A (en) * 1971-11-01 1975-12-09 Phillips Petroleum Co Oxidative dehydrogenation using group IA or IIA metal Sn/P/O catalyst
JPS5146299B2 (en) * 1972-08-15 1976-12-08
US3935126A (en) * 1974-05-28 1976-01-27 The Dow Chemical Company Catalyst and method of oxydehydrogenation of alkyl aromatic compounds
US3957897A (en) * 1974-05-28 1976-05-18 The Dow Chemical Company Method of oxydehydrogenation of alkyl aromatic compounds

Also Published As

Publication number Publication date
ES470908A1 (en) 1979-02-01
GB1598509A (en) 1981-09-23
DD135897A5 (en) 1979-06-06
IT1094807B (en) 1985-08-10
IN148087B (en) 1980-10-18
BR7802706A (en) 1979-01-23
CA1117120A (en) 1982-01-26
EG13250A (en) 1981-03-31
BE866403A (en) 1978-08-14
CS199528B2 (en) 1980-07-31
JPS53135940A (en) 1978-11-28
NL7804618A (en) 1978-11-06
PT67944B (en) 1979-11-14
NO781508L (en) 1978-11-03
JPH0154095B2 (en) 1989-11-16
DE2816946A1 (en) 1978-11-09
IT7822880A0 (en) 1978-04-28
FR2389590A1 (en) 1978-12-01
GB1598510A (en) 1981-09-23
PT67944A (en) 1978-05-01

Similar Documents

Publication Publication Date Title
ES439592A1 (en) Oxidation catalysts
Yamamoto et al. Zirconium enolate as a new erythro-selective aldol condensation reagent
KR860000233A (en) Oxydehydrogenation with Ethanol Ethylene
MY116795A (en) Lower alkane oxidative dehydrogenation catalysts and a process for producing olefins
ES439572A1 (en) Process for the oxidation of olefins using catalysts containing various promoter elements
GB1415468A (en) Preparation of aromatic nitriles
ES429854A1 (en) Process for preparing ethylene oxide
KR830003931A (en) Process for preparing improved Sb-containing catalyst
ES469145A1 (en) Oxydehydrogenation process for alkylaromatics
Kaftory et al. Reactions in the solid state. 2. The crystal structures of the inclusion complexes of 1, 1, 6, 6-tetraphenylhexa-2, 4-diyne-1, 6-diol with benzylideneacetophenone and 2, 5-diphenylhydroquinone with dibenzylideneacetone
KR830003932A (en) Tin-antimony oxide catalyst
Kobayashi et al. Synthesis and physiological activities of both enantiomers of coriolic acid and their geometric isomers
Tamaru et al. Palladium catalyzed polyhetero-Claisen rearrangement
Gerber et al. Synthesis of the torsionally strained monocyclic polythiaether 1, 4, 7-trithiacyclononane
Kulka Octahalogenodibenzo-p-dioxins
Lai et al. Rearrangement of 2, 2, 6, 6-tetramethyl-4-piperidone in phase-transfer catalyzed reactions
Smith et al. Ring-chain tautomerism as a factor in the reaction between Grignard reagents and substituted phthalides
ES465738A1 (en) Process for directed chlorination of alkylbenzenes
Saegusa et al. Synthetic reactions by complex catalysts. XII. Copper-catalyzed reaction of isocyanide with alcohol
Mazières et al. Structural Characterization of Bismuth (III) and Antimony (III) Chlorotriflates: Key Intermediates in Catalytic Friedel− Crafts Transformations
Ishizu et al. Observation of periselectivity for the cyclocoupling reactions of 2-oxyallyl cation with tricarbonyliron complexes of seven-membered-ring unsaturated compounds
Okuma et al. A novel reaction of selenobenzophenones with tetracyanoethylene. Formation of a 2, 3-dihydroselenophene
Wang et al. Structure of [Au (PPh3) 2][C (CN) 3]
Attanasi et al. Reduction of N-acyl, N′-tosylhydrazines with diborane: A simple, convenient procedure for the conversion of the carboxylic to the methyl group
GB1136744A (en) Production of acrylonitrile and methacrylonitrile