ES439592A1 - Oxidation catalysts - Google Patents

Oxidation catalysts

Info

Publication number
ES439592A1
ES439592A1 ES439592A ES439592A ES439592A1 ES 439592 A1 ES439592 A1 ES 439592A1 ES 439592 A ES439592 A ES 439592A ES 439592 A ES439592 A ES 439592A ES 439592 A1 ES439592 A1 ES 439592A1
Authority
ES
Spain
Prior art keywords
mixture
tungsten
oxidation
sulphur
numbers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES439592A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of ES439592A1 publication Critical patent/ES439592A1/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0576—Tellurium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J27/192—Molybdenum with bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The oxidation catalyst has the general formula XaAbDcEdFefBigMo12Ox, wherein: X is yttrium, zirconium, silver, sulphur, cerium, thorium, praseodymium, ruthenium, gallium, niobium, germanium, chromium, tin, manganese, indium, copper, tungsten, tantalum, tellurium, lanthanum, or a mixture thereof, A is an alkali metal, thallium or a mixture thereof, D is nickel, cobalt, magnesium, strontium, calcium, zinc, cadmium or a mixture thereof, E is phosphorus, arsenic, boron, tungsten, antimony or a mixture thereof, it also being possible for E to be sulphur if X is tungsten, a is a number greater than 0 and smaller than 5, b and d are numbers from 0 to 4, c is a number from 0.1 to 20, f and g are numbers from 0.1 to 10 and x is the number of oxygen atoms required for saturating the valency of the other elements present. The catalyst can be used for a very wide range of oxidation reactions, such as the oxidative dehydrogenation of olefins and oxidation and ammoxidation of methyl-substituted aromatic compounds.
ES439592A 1974-07-22 1975-07-21 Oxidation catalysts Expired ES439592A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US49053274A 1974-07-22 1974-07-22

Publications (1)

Publication Number Publication Date
ES439592A1 true ES439592A1 (en) 1977-06-01

Family

ID=23948462

Family Applications (1)

Application Number Title Priority Date Filing Date
ES439592A Expired ES439592A1 (en) 1974-07-22 1975-07-21 Oxidation catalysts

Country Status (19)

Country Link
JP (2) JPS6036812B2 (en)
AT (1) AT354408B (en)
BE (1) BE831530A (en)
BR (1) BR7504680A (en)
CA (1) CA1075672A (en)
CH (1) CH616861A5 (en)
CS (1) CS195708B2 (en)
DD (1) DD122065A5 (en)
DE (1) DE2530959C2 (en)
EG (1) EG12556A (en)
ES (1) ES439592A1 (en)
FR (1) FR2279465A1 (en)
GB (1) GB1523772A (en)
IN (1) IN144016B (en)
IT (1) IT1039883B (en)
NL (1) NL188016B (en)
NO (1) NO145184C (en)
RO (1) RO70128A (en)
YU (1) YU37273B (en)

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US9399606B2 (en) 2012-12-06 2016-07-26 Basf Se Catalyst and process for the oxidative dehydrogenation of N-butenes to butadiene
WO2014086768A1 (en) 2012-12-06 2014-06-12 Basf Se Method for oxidative dehydrogenation of n-butenes to butadiene
US10144681B2 (en) 2013-01-15 2018-12-04 Basf Se Process for the oxidative dehydrogenation of N-butenes to butadiene
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EA201690165A1 (en) 2013-07-10 2016-06-30 Басф Се METHOD OF OXIDATIVE DEHYDROGENATION OF N-BUTENES IN BUTADIENE
EP3063112B1 (en) 2013-10-30 2017-12-13 Basf Se Method for preparing 1,3-butadiene from n-butenes by oxidative dehydration
US20160347686A1 (en) 2014-01-13 2016-12-01 Basf Se Method of starting up a reactor for the oxidative dehydrogenation of n-butenes
DE102014203725A1 (en) 2014-02-28 2015-09-03 Basf Se Oxidation catalyst with saddle-shaped carrier shaped body
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KR20170063608A (en) 2014-09-26 2017-06-08 바스프 에스이 Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
WO2016071268A1 (en) 2014-11-03 2016-05-12 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
EA034435B1 (en) 2014-11-14 2020-02-07 Басф Се Method for producing 1,3-butadienes by dehydrogenating n-butenes, a material flow containing butanes and 2-butenes being provided
US20180072638A1 (en) 2015-03-26 2018-03-15 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
WO2016151074A1 (en) 2015-03-26 2016-09-29 Basf Se Method for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
WO2016150940A1 (en) 2015-03-26 2016-09-29 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
JP2018509450A (en) 2015-03-26 2018-04-05 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Process for producing 1,3-butadiene from n-butenes by oxidative dehydrogenation
EP3383831B1 (en) 2015-12-03 2019-10-23 Basf Se Method for preparing butadiene through the oxidative dehydration of n-butenes
EP3402769B1 (en) 2016-01-13 2020-03-25 Basf Se Method for preparing 1.3-butadiene from n-butenes by oxidative dehydration
US10647639B2 (en) 2016-02-04 2020-05-12 Basf Se Method for preparing 1,3-butadiene from N-butenes by oxidative dehydrogeneation
KR20190046848A (en) 2016-08-09 2019-05-07 바스프 에스이 Starting method of reactor for oxidative dehydrogenation of n-butene
WO2018095840A1 (en) 2016-11-22 2018-05-31 Basf Se Method for producing 1,3-butadiene from n-butenes by oxidative dehydrogenation, comprising furan removal in the processing
WO2018095776A1 (en) 2016-11-22 2018-05-31 Basf Se Method for producing 1,3-butadiene from n-butenes by oxidative dehydrogenation, comprising aqueous scrubbing of the c4 product gas flow
EP3323797A1 (en) 2016-11-22 2018-05-23 Basf Se Method for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation comprising an acidic washing of a c4 product gas flow
WO2018095856A1 (en) 2016-11-22 2018-05-31 Basf Se Method for preparing 1,3-butadiene from n-butenes through oxidative dehydrogenation comprising methacrolein removal during processing
WO2018219996A1 (en) 2017-06-02 2018-12-06 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation in recycle gas mode with co2-enriched recycle gas
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US3932551A (en) * 1973-10-12 1976-01-13 The Standard Oil Company Process for the preparation of diolefins from olefins
JPS5245692B2 (en) * 1973-10-16 1977-11-17
CA1045619A (en) * 1974-04-19 1979-01-02 Mitsubishi Chemical Industries Limited (Mitsubishi Kasei Kogyo Kabushiki Kaisha Also Trading As) Method of preparing maleic anhydride and catalysts utilized therefor
JPS5432766B2 (en) * 1974-06-04 1979-10-16
GB1523772A (en) * 1974-07-22 1978-09-06 Standard Oil Co Oxidation catalysts
US4001317A (en) * 1974-07-22 1977-01-04 Standard Oil Company Process for the oxidation of olefins using catalysts containing various promoter elements
GB1489559A (en) * 1975-03-03 1977-10-19 Mitsubishi Rayon Co Catalytic process for the preparation of acrylic acid or methacrylic acid
US4075232A (en) * 1975-03-06 1978-02-21 The Standard Oil Company Preparation of maleic anhydride from n-butene in a one-reactor, fluid-bed system using two different catalysts
GB1490683A (en) * 1975-03-12 1977-11-02 Mitsubishi Rayon Co Process and a catalyst for producing unsaturated aldehydes unsaturated carboxylic acids or conjugated diene
GB1513335A (en) * 1975-03-17 1978-06-07 Mitsubishi Rayon Co Process and a catalyst for the preparation of unsaturated carboxylic acid
IN142430B (en) * 1975-04-21 1977-07-09 Standard Oil Co
DE3315745C2 (en) * 1983-04-30 1986-11-27 Schott Glaswerke, 6500 Mainz Hob with gas-heated burners and a continuous cooking surface made of glass ceramic or comparable material

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DE2530959C2 (en) 1986-03-20
NL7508637A (en) 1976-01-26
CS195708B2 (en) 1980-02-29
DE2530959A1 (en) 1976-02-05
NO752572L (en) 1976-01-23
GB1523772A (en) 1978-09-06
NO145184B (en) 1981-10-26
CA1075672A (en) 1980-04-15
NO145184C (en) 1982-02-03
JPS6118435A (en) 1986-01-27
BR7504680A (en) 1976-07-06
YU186375A (en) 1983-04-27
IT1039883B (en) 1979-12-10
ATA544975A (en) 1979-06-15
NL188016B (en) 1991-10-16
JPS6036812B2 (en) 1985-08-22
JPS5140391A (en) 1976-04-05
FR2279465B1 (en) 1981-08-28
JPS6242654B2 (en) 1987-09-09
RO70128A (en) 1982-10-11
EG12556A (en) 1979-09-30
DD122065A5 (en) 1976-09-12
YU37273B (en) 1984-08-31
CH616861A5 (en) 1980-04-30
AT354408B (en) 1979-01-10
FR2279465A1 (en) 1976-02-20
IN144016B (en) 1978-03-11
BE831530A (en) 1975-11-17

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