ES457263A1 - Procedimiento para la obtencion de copolimerizados de esti- reno antichoque. - Google Patents
Procedimiento para la obtencion de copolimerizados de esti- reno antichoque.Info
- Publication number
- ES457263A1 ES457263A1 ES457263A ES457263A ES457263A1 ES 457263 A1 ES457263 A1 ES 457263A1 ES 457263 A ES457263 A ES 457263A ES 457263 A ES457263 A ES 457263A ES 457263 A1 ES457263 A1 ES 457263A1
- Authority
- ES
- Spain
- Prior art keywords
- high impact
- manufacture
- translucent
- styrene
- styrene polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Procedimiento para la obtención de copolimerizados de estireno antichoque, modificados con caucho, caracterizados porque se polimeriza el estireno en presencia del caucho en, como mínimo dos etapas, prepolimerizándose en la primera etapa el estireno que contiene el caucho disuelto a una temperatura de entre 50 y 150ºC, en caso dado en presencia de diluyentes indiferentes y/o inciadores que forman radicales libres, bajo separación de la fase dispersa de componente blando que se forma durante la polimerización mediante cizallamiento de la mezcla de polimerización y continuándose la polimerización en una o varias etapas bajo cizallamiento redicudo o sin cizallamiento, en solución, suspensión acuosa o en ausencia de disolventes hasta alcanzar la conversación deseada, en el cual durante la prepolimerización.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2613352A DE2613352B2 (de) | 1976-03-29 | 1976-03-29 | Verfahren zur Herstellung von schlagfest modifizierten Styrolpolymerisaten |
Publications (1)
Publication Number | Publication Date |
---|---|
ES457263A1 true ES457263A1 (es) | 1978-02-01 |
Family
ID=5973755
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES457263A Expired ES457263A1 (es) | 1976-03-29 | 1977-03-28 | Procedimiento para la obtencion de copolimerizados de esti- reno antichoque. |
Country Status (11)
Country | Link |
---|---|
US (1) | US4282334A (es) |
JP (1) | JPS6057443B2 (es) |
BE (1) | BE852793A (es) |
CA (1) | CA1114984A (es) |
DE (1) | DE2613352B2 (es) |
ES (1) | ES457263A1 (es) |
FR (1) | FR2346381A1 (es) |
GB (1) | GB1576772A (es) |
GR (1) | GR65690B (es) |
IT (1) | IT1081354B (es) |
NL (1) | NL7703199A (es) |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES8103120A1 (es) * | 1979-03-07 | 1981-02-16 | Monsanto Co | Un procedimiento mejorado para la polimerizacion continua enmasa de una solucion que comprende un monomero alquenilaro- matico que tiene un caucho dienico disuelto. |
JPS5919576B2 (ja) * | 1979-11-01 | 1984-05-07 | 三井東圧化学株式会社 | ゴム変性スチレン系樹脂の製造方法 |
DE3018643C2 (de) * | 1980-05-16 | 1982-07-08 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von schlagfest modifizierten Styrolpolymerisaten |
DE3023721A1 (de) * | 1980-06-25 | 1982-01-21 | Basf Ag, 6700 Ludwigshafen | Verfahren zur kontinuierlichen herstellung von mit kautschuk modifizierten polymerisaten von vinylaromaten |
DE3032260A1 (de) * | 1980-08-27 | 1982-04-08 | Basf Ag, 6700 Ludwigshafen | Verfahren zur kontinuierlichen herstellung von mit kautschuk modifizierten polymerisaten von vinylaromaten, verwendung derselben zum spritzgiessen sowie formteile aus diesen polymerisaten |
JPS5796006A (en) * | 1980-12-05 | 1982-06-15 | Mitsui Toatsu Chem Inc | Production of rubber-modified styrene resin |
DE3047293A1 (de) * | 1980-12-16 | 1982-07-29 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von abs-polymerisaten, verwendung derselben, sowie formteile aus diesen |
DE3409656A1 (de) * | 1984-03-16 | 1985-09-19 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von mit kautschuk schlagfest modifiziertem, transluzentem polystyrol |
US4594391A (en) * | 1984-05-21 | 1986-06-10 | The Dow Chemical Company | Impact-modified monovinylidene aromatic polymer injection molding resins |
CA1244986A (en) * | 1984-05-21 | 1988-11-15 | Mary A. Jones | Impact-modified monovinylidene aromatic polymer injection molding resins |
DE3611705A1 (de) * | 1986-04-08 | 1987-10-22 | Basf Ag | Verfahren zur herstellung von schlagfestem poly(alkyl)styrol |
DE3611704A1 (de) * | 1986-04-08 | 1987-10-22 | Basf Ag | Verfahren zur herstellung von schlagfestem poly(alkyl)styrol |
US4839418A (en) * | 1988-01-05 | 1989-06-13 | Basf Aktiengesellschaft | Thermoplastic molding materials and their preparation |
JPH0714990B2 (ja) * | 1990-03-02 | 1995-02-22 | 新日鐵化学株式会社 | ゴム変性スチレン系樹脂の製造法 |
DE4030352A1 (de) * | 1990-09-26 | 1992-04-02 | Basf Ag | Verfahren zur herstellung von abs-formmassen |
JP3345921B2 (ja) * | 1992-09-30 | 2002-11-18 | 日本ゼオン株式会社 | 耐衝撃性ポリスチレン系樹脂及びその製造方法 |
DE4416861A1 (de) * | 1994-05-13 | 1995-11-16 | Basf Ag | Expandierbare Styrolpolymerisate |
US5661191A (en) * | 1995-01-13 | 1997-08-26 | Mitsubishi Chemical Basf Company Limited | Expandable rubber-modified styrene resin beads, expanded beads thereof, and expanded molded articles obtained therefrom |
US5637646A (en) * | 1995-12-14 | 1997-06-10 | Minnesota Mining And Manufacturing Company | Bulk radical polymerization using a batch reactor |
DE19614293A1 (de) * | 1996-04-11 | 1997-10-16 | Basf Ag | Kontinuierliches Verfahren zur Herstellung thermoplastischer Formmassen |
US5985997A (en) * | 1997-05-23 | 1999-11-16 | Chevron Chemical Company | In situ process for making a bimodal HIPS having both high gloss and high impact strength |
US6221987B1 (en) * | 1998-04-17 | 2001-04-24 | Asahi Glass Company Ltd. | Method for producing a fluorine-containing polymer |
SG79291A1 (en) | 1998-11-20 | 2001-03-20 | Daicel Chem | Rubber-containing styrenic resin and process for producing the same |
JP2001240637A (ja) | 2000-02-25 | 2001-09-04 | Nippon Zeon Co Ltd | ブロック共重合ゴム、樹脂改質剤および樹脂組成物並びに樹脂組成物の製造方法 |
JP4017994B2 (ja) * | 2003-02-04 | 2007-12-05 | テクノポリマー株式会社 | レーザー溶着用成形材料及び成形品 |
ATE526358T1 (de) † | 2003-03-25 | 2011-10-15 | Sekisui Plastics | Expandierbare harzteilchen aus styrolmodifiziertem linearen polyethylen niederer dichte |
US8258083B2 (en) * | 2004-12-30 | 2012-09-04 | Sun Drilling Products Corporation | Method for the fracture stimulation of a subterranean formation having a wellbore by using impact-modified thermoset polymer nanocomposite particles as proppants |
US20070299209A1 (en) * | 2006-06-21 | 2007-12-27 | Sosa Jose M | Methods for production of high impact polystyrene |
AR096841A1 (es) * | 2014-07-07 | 2016-02-03 | Sotro Financial Inc | Nanocompuestos sintéticos en forma de micropartículas, proceso para su producción, agentes de sostén y fluidos de fractura para procesos de extracción de gas y petróleo |
IT201600079947A1 (it) | 2016-07-29 | 2018-01-29 | Versalis Spa | Composizione polimerica espandibile contentente copolimeri etilen-vinilacetato |
US20230392052A1 (en) | 2020-08-31 | 2023-12-07 | Ineos Styrolution Group Gmbh | Sealable multilayer film of styrene polymers with improved organoleptic properties |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3243481A (en) * | 1962-01-08 | 1966-03-29 | Dow Chemical Co | Process for making graft copolymers of vinyl aromatic compounds and stereospecific rubbers |
GB1005681A (en) * | 1962-04-04 | 1965-09-29 | Monsanto Co | Process for polymerizing a rubber-monomer solution |
DE1595203A1 (de) * | 1963-08-14 | 1970-04-16 | Rexall Drug Chemical | Pfropfpolymerisationsverfahren |
GB1180085A (en) * | 1966-02-08 | 1970-02-04 | Toyo Rayon Co Ltd | Transparent Thermoplastic Composition of High Impact Resistance and manufacture thereof |
US3660535A (en) * | 1970-09-23 | 1972-05-02 | Dow Chemical Co | Process for the production of alkenyl aromatic polymers containing a reinforcing polymer therein |
JPS5229353B2 (es) * | 1972-05-04 | 1977-08-01 | ||
FR2197042B1 (es) * | 1972-08-23 | 1980-03-14 | Gen Electric | |
US3903202A (en) * | 1973-09-19 | 1975-09-02 | Monsanto Co | Continuous mass polymerization process for polyblends |
-
1976
- 1976-03-29 DE DE2613352A patent/DE2613352B2/de not_active Ceased
-
1977
- 1977-02-14 GR GR52777A patent/GR65690B/el unknown
- 1977-03-07 IT IT21012/77A patent/IT1081354B/it active
- 1977-03-14 CA CA273,939A patent/CA1114984A/en not_active Expired
- 1977-03-22 FR FR7708471A patent/FR2346381A1/fr active Granted
- 1977-03-23 BE BE176045A patent/BE852793A/xx not_active IP Right Cessation
- 1977-03-24 NL NL7703199A patent/NL7703199A/xx not_active Application Discontinuation
- 1977-03-28 ES ES457263A patent/ES457263A1/es not_active Expired
- 1977-03-28 GB GB12880/77A patent/GB1576772A/en not_active Expired
- 1977-03-29 JP JP52034074A patent/JPS6057443B2/ja not_active Expired
-
1979
- 1979-11-27 US US06/097,815 patent/US4282334A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
GR65690B (en) | 1980-10-20 |
JPS6057443B2 (ja) | 1985-12-14 |
CA1114984A (en) | 1981-12-22 |
FR2346381B1 (es) | 1983-06-03 |
NL7703199A (nl) | 1977-10-03 |
JPS52117990A (en) | 1977-10-03 |
DE2613352A1 (de) | 1977-10-06 |
GB1576772A (en) | 1980-10-15 |
US4282334A (en) | 1981-08-04 |
DE2613352B2 (de) | 1980-08-07 |
FR2346381A1 (fr) | 1977-10-28 |
BE852793A (fr) | 1977-09-23 |
IT1081354B (it) | 1985-05-21 |
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