ES447875A1 - Process for the production of 2-aryl-2h-benzotriazoles - Google Patents

Process for the production of 2-aryl-2h-benzotriazoles

Info

Publication number
ES447875A1
ES447875A1 ES447875A ES447875A ES447875A1 ES 447875 A1 ES447875 A1 ES 447875A1 ES 447875 A ES447875 A ES 447875A ES 447875 A ES447875 A ES 447875A ES 447875 A1 ES447875 A1 ES 447875A1
Authority
ES
Spain
Prior art keywords
benzotriazoles
aryl
production
nitroazobenzene
cyclising
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES447875A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of ES447875A1 publication Critical patent/ES447875A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/16—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms condensed with carbocyclic rings or ring systems
    • C07D249/18—Benzotriazoles
    • C07D249/20—Benzotriazoles with aryl radicals directly attached in position 2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Springs (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

2-Aryl-2H-benzotriazoles of the formula I are prepared by reducing a suitable o-nitroazobenzene with hydrogen in an alkaline medium of pH greater than 10 in the presence of a nickel hydrogenation catalyst at 20 to 100 DEG C and a pressure of 1 to 66 atmospheres, and cyclising the product. The meanings of the symbols are given in Claim 1. The compounds can be used as UV stabilisers. The process is environmentally friendly and gives high yields.
ES447875A 1975-05-14 1976-05-13 Process for the production of 2-aryl-2h-benzotriazoles Expired ES447875A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US57738675A 1975-05-14 1975-05-14

Publications (1)

Publication Number Publication Date
ES447875A1 true ES447875A1 (en) 1977-07-16

Family

ID=24308487

Family Applications (2)

Application Number Title Priority Date Filing Date
ES447876A Expired ES447876A1 (en) 1975-05-14 1976-05-13 Process for the production of 2-aryl-2h-benzotriazoles
ES447875A Expired ES447875A1 (en) 1975-05-14 1976-05-13 Process for the production of 2-aryl-2h-benzotriazoles

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES447876A Expired ES447876A1 (en) 1975-05-14 1976-05-13 Process for the production of 2-aryl-2h-benzotriazoles

Country Status (9)

Country Link
JP (1) JPS6036432B2 (en)
BE (1) BE841771A (en)
BR (1) BR7603023A (en)
CH (1) CH615167A5 (en)
DE (1) DE2620896A1 (en)
ES (2) ES447876A1 (en)
FR (1) FR2311013A1 (en)
GB (1) GB1494826A (en)
NL (1) NL7605204A (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4668235A (en) * 1982-12-07 1987-05-26 The Commonwealth Of Australia Commonwealth Scientific & Industrial Research Organization Use of substituted 2-(2-hydroxyaryl)-2H-benzotriazolesulfonates as photostabilizing agents for natural synthetic fibres
JPS6471862A (en) * 1987-09-11 1989-03-16 Chemipro Kasei Kaisha Ltd Production of 2-phenylbenzotriazole
JPH02202880A (en) * 1989-01-31 1990-08-10 Kemipuro Kasei Kk Production of 2-phenylbenzotriazoles
JPH02202879A (en) * 1989-01-31 1990-08-10 Kemipuro Kasei Kk Production of 2-phenylbenzotriazoles
US5675015A (en) * 1996-03-07 1997-10-07 Eastman Kodak Company Process for the preparation of benzotriazole derivatives
JP6131400B2 (en) * 2013-01-29 2017-05-24 シプロ化成株式会社 Benzotriazole derivative compounds

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH529815A (en) * 1970-06-19 1972-10-31 Ciba Geigy Ag Use of 2- (2'-hydroxyphenyl) -benzotriazole compounds as light stabilizers
US3978074A (en) * 1973-11-21 1976-08-31 Uniroyal Inc. Method of making hydroxyarylbenzotriazoles and their N-oxides

Also Published As

Publication number Publication date
NL7605204A (en) 1976-11-16
JPS6036432B2 (en) 1985-08-20
GB1494826A (en) 1977-12-14
JPS51138679A (en) 1976-11-30
DE2620896A1 (en) 1976-12-02
CH615167A5 (en) 1980-01-15
FR2311013B1 (en) 1978-05-19
BR7603023A (en) 1977-05-31
ES447876A1 (en) 1977-07-16
BE841771A (en) 1976-11-16
FR2311013A1 (en) 1976-12-10

Similar Documents

Publication Publication Date Title
ES8106933A1 (en) Process for the production of D-Glucosone and D-Fructose.
ES447873A1 (en) Process for the production of 2-aryl-2h-benzotriazoles
ES447875A1 (en) Process for the production of 2-aryl-2h-benzotriazoles
ES447874A1 (en) Process for the production of 2-aryl-2h-benzotriazoles
GB1494823A (en) Process for the production of 2-aryl-2h-benzotriazoles
ES424851A1 (en) A procedure for preparing piperazine derivatives. (Machine-translation by Google Translate, not legally binding)
GB1377192A (en) Hydrogenation process for the preparation of aliphatic diamines
ES422433A1 (en) Antibiotic a-287 and process for production thereof
ES424607A1 (en) Process for preparing hydroxydiphenyl
GB1387512A (en) Method for the preparation of hydrogen peroxide
GB1165060A (en) New N,N-Diglycidyl-Bis-Hydantoinyl Methane Derivatives, Process for their Production, and Use
ES422625A1 (en) A procedure for the production of bicilomycin. (Machine-translation by Google Translate, not legally binding)
GB1314278A (en) Manufacture of trimethyl hydroquinone
ES412047A1 (en) Preparation of dihydrocoumarin and of alkyl derivatives thereof
ES423365A1 (en) Process for the simultaneous production of methanol-utilising and non-methanol-utilising micro-organisms
ES425412A1 (en) Procedure for obtaining epsilon-aminocaprnamide. (Machine-translation by Google Translate, not legally binding)
GB1462309A (en) Production of a tanning formulation
ES331087A1 (en) A procedure to produce l-lysine. (Machine-translation by Google Translate, not legally binding)
ES240761A1 (en) A method of producing tetracyclines (Machine-translation by Google Translate, not legally binding)
JPS5277048A (en) Purification of anthraquinones having substituents
ES449163A1 (en) Antibiotic complex
ES260211A1 (en) Production of tetracycline antibiotics
ES303758A1 (en) A procedure to produce an organic compound. (Machine-translation by Google Translate, not legally binding)
JPS5294481A (en) Production of microbial cells
JPS51115986A (en) Process for producing yeast cells