ES440183A1 - Un procedimiento de preparacion de una emulsion estable en agua,en aceite de polimeros y copolimeros de monomeros eli- lenicamente insaturados. - Google Patents
Un procedimiento de preparacion de una emulsion estable en agua,en aceite de polimeros y copolimeros de monomeros eli- lenicamente insaturados.Info
- Publication number
- ES440183A1 ES440183A1 ES440183A ES440183A ES440183A1 ES 440183 A1 ES440183 A1 ES 440183A1 ES 440183 A ES440183 A ES 440183A ES 440183 A ES440183 A ES 440183A ES 440183 A1 ES440183 A1 ES 440183A1
- Authority
- ES
- Spain
- Prior art keywords
- latex polymers
- high hlb
- selecting
- emulsions
- properties
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/32—Polymerisation in water-in-oil emulsions
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Colloid Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
1.Un procedimiento de preparación de una emulsión estable agua en aceite de polímeros y copolímeros de monómeros etilénicamente insaturados, solubles en agua, cuyo procedimiento consiste en disolver un monómero etilénicamente insaturado soluble en agua, con una solubilidad en agua del 5% en peso como mínimo para preparar soluciones acuosas del mismo, agregar un medio de dispersión líquido orgánico, inerte e hidrófobo, que contiene entre 0,1 y 10% en peso de un agente emulsionante de agua en aceite, para formar una emulsión agua en aceite donde la proporción de fase acuosa oscila entre el 70 y el 95% de la emulsión, polimerizar el monómero en una fase dispersa en dicho medio de dispersión calentando la emulsión bajo condiciones de formación de radicales libres y recuperar el látex polimerizado producido; siendo el medio de dispersión orgánico líquido, inerte e hidrófobo, un hidrocarburo alifático líquido y uno o más agentes emulsionantes de agua en aceite, con lo que se forma una emulsión con una relación de energía cohesiva comprendida entre 1, 0 y 3, 0.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/542,982 US3997492A (en) | 1975-01-22 | 1975-01-22 | High HLB latex polymers |
Publications (1)
Publication Number | Publication Date |
---|---|
ES440183A1 true ES440183A1 (es) | 1980-07-16 |
Family
ID=24166114
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES440183A Expired ES440183A1 (es) | 1975-01-22 | 1975-08-11 | Un procedimiento de preparacion de una emulsion estable en agua,en aceite de polimeros y copolimeros de monomeros eli- lenicamente insaturados. |
Country Status (13)
Country | Link |
---|---|
US (1) | US3997492A (es) |
JP (1) | JPS5187552A (es) |
BE (1) | BE832701A (es) |
BR (1) | BR7505399A (es) |
CA (1) | CA1050679A (es) |
DE (1) | DE2537586B2 (es) |
ES (1) | ES440183A1 (es) |
FR (1) | FR2298555A1 (es) |
GB (1) | GB1511908A (es) |
IT (1) | IT1041298B (es) |
NL (1) | NL7510025A (es) |
SE (1) | SE426492B (es) |
ZA (1) | ZA754840B (es) |
Families Citing this family (61)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4090992A (en) * | 1975-09-15 | 1978-05-23 | Drew Chemical Corp. | Dispersions of water soluble polymers in oil |
US4162966A (en) * | 1976-06-16 | 1979-07-31 | Nalco Chemical Company | Flotation of deep mined coal with water-in-oil emulsions of sodium polyacrylate |
IT7847966A0 (it) * | 1977-06-22 | 1978-02-08 | Nalco Chemical Company Soc Del | Processo per trattare fanghi rossi |
US4222861A (en) * | 1978-06-08 | 1980-09-16 | Nalco Chemical Company | Treatment and recovery of larger particles of fine oxidized coal |
US4222862A (en) * | 1978-10-06 | 1980-09-16 | Nalco Chemical Company | Flotation of oxidized coal with a latex emulsion of sodium polyacrylate used as a promoter |
US4212784A (en) * | 1979-05-04 | 1980-07-15 | Nalco Chemical Co. | Polymerization of water soluble polymers in water-in-oil latex form to produce emulsions containing high polymer solids levels and low oil levels |
US4252706A (en) * | 1979-10-31 | 1981-02-24 | Nalco Chemical Company | Method for precisely controlling the dissolution rate of high molecular weight water-soluble vinyl polymers |
US4328149A (en) * | 1980-01-30 | 1982-05-04 | Calgon Corporation | Polymerization method utilizing a three-phase emulsion system |
JPS6025045B2 (ja) * | 1980-03-19 | 1985-06-15 | 製鉄化学工業株式会社 | 塩水吸収能のすぐれたアクリル酸重合体の製造方法 |
US4340467A (en) * | 1980-03-20 | 1982-07-20 | American Cyanamid Company | Flotation of coal with latex emulsions of hydrocarbon animal or vegetable based oil |
JPS56147630A (en) * | 1980-04-15 | 1981-11-16 | Seitetsu Kagaku Co Ltd | Water absorptivity imparting method |
US4521620A (en) * | 1980-12-05 | 1985-06-04 | Nalco Chemical Company | Acrylamide synthesis from an oil-in-water emulsion containing acrylonitrile |
US4413143A (en) * | 1980-12-05 | 1983-11-01 | Nalco Chemical Company | Method of producing acrylamide from water-in-oil emulsion of acrylonitrile |
US4362838A (en) * | 1981-06-11 | 1982-12-07 | Seymour Of Sycamore, Inc. | Solvent resin emulsion gloss coating composition |
US4365028A (en) * | 1981-06-11 | 1982-12-21 | Seymour Of Sycamore, Inc. | Coating composition |
US4363887A (en) * | 1981-06-11 | 1982-12-14 | Seymour Of Sycamore, Inc. | Solvent resin emulsion enamel composition |
FR2507606B1 (fr) * | 1981-06-12 | 1985-11-15 | Hoechst France | Nouvelles dispersions stables, eau dans huile de polymeres cationiques hydrosolubles a base d'acrylate de dimethylaminoethyle salifie ou quaternise, leur procede de fabrication et leur application comme floculants |
US4375529A (en) * | 1981-08-03 | 1983-03-01 | Nalco Chemical Company | Hydrogenation of residual monomers in partially polymerized acrylamide copolymers in latex form |
US4427821A (en) | 1981-08-03 | 1984-01-24 | Nalco Chemical Company | Hydrogenation of residual monomers in partially polymerized acrylamide copolymers in latex form |
CA1205935A (en) | 1981-09-14 | 1986-06-10 | Union Carbide Corporation | Process for producing a polymer water-in-oil emulsion |
US4529782A (en) * | 1981-09-14 | 1985-07-16 | Union Carbide Corporation | High molecular weight water soluble polymers |
US4485209A (en) * | 1981-09-14 | 1984-11-27 | Union Carbide Corporation | Process for producing a polymer water-in-oil emulsion |
US4555346A (en) * | 1981-09-14 | 1985-11-26 | Union Carbide Corporation | Process for flocculating phophatic slimes |
US4443576A (en) * | 1982-03-29 | 1984-04-17 | Nalco Chemical Company | Terpolymer composition |
US4618647A (en) * | 1983-03-11 | 1986-10-21 | Union Carbide Corp. | Process for producing a polymer water-in-oil emulsion |
US4619967A (en) * | 1983-05-26 | 1986-10-28 | The Dow Chemical Company | Multi-modal emulsions of water-soluble polymers |
US4529637A (en) * | 1983-08-24 | 1985-07-16 | Hankel Keith M | Acoustical material |
GB8323241D0 (en) * | 1983-08-30 | 1983-09-28 | Ici Plc | Coating compositions |
US4727110A (en) * | 1984-04-19 | 1988-02-23 | Union Carbide Corporation | Process for the polymerization of shear-stable water-in-oil emulsions |
NO165879C (no) * | 1984-06-07 | 1991-04-24 | Inst Francais Du Petrole | Fremgangsmaate for fremstilling av en invers, stabil mikrolateks. |
FR2565623B1 (fr) * | 1984-06-07 | 1987-12-11 | Inst Francais Du Petrole | Utilisation de microlatex inverses a teneur elevee en copolymeres hydrosolubles pour l'amelioration de la production d'hydrocarbures |
US4539368A (en) * | 1984-07-26 | 1985-09-03 | Azs Corporation | Technology for the production of inverse emulsion polymers |
GB8522052D0 (en) * | 1985-09-05 | 1985-10-09 | Ici Plc | Polymerisation process |
US4764574A (en) * | 1986-12-09 | 1988-08-16 | Phillips Petroleum Company | Inverse emulsion polymerization with sorbitan fatty acid esters and ethoxylated alcohol |
US5290479A (en) * | 1986-12-09 | 1994-03-01 | Phillips Petroleum Company | Surfactant system of polyethoxylated compounds and glyceride compounds |
US4906701A (en) * | 1986-12-09 | 1990-03-06 | Phillips Petroleum Company | Inverse emulsion polymerization |
US4742114A (en) * | 1987-02-13 | 1988-05-03 | Nalco Chemical Company | Water-in-oil emulsions of amidase |
US4786679A (en) * | 1987-02-13 | 1988-11-22 | Nalco Chemical Company | Water-in-oil emulsions of amidase |
US4687807A (en) * | 1987-02-13 | 1987-08-18 | Nalco Chemical Company | Use of amidase for reducing the acrylamide content of water-in-oil emulsions containing acrylamide polymers |
US4954547A (en) * | 1987-04-23 | 1990-09-04 | Nalco Chemical Company | Use of fatty acids for improvement in shear stability of water-in-oil emulsions |
US4751259A (en) * | 1987-08-05 | 1988-06-14 | Nalco Chemical Company | Compositions for iron ore agglomeration |
US4795789A (en) * | 1987-10-26 | 1989-01-03 | Nalco Chemical Company | Process for making acrylamido methane sulfonic acid polymers |
US4952642A (en) * | 1987-10-26 | 1990-08-28 | Nalco Chemical Company | Process for making acrylamido methane sulfonic acid polymers |
US4800071A (en) * | 1988-05-03 | 1989-01-24 | Nalco Chemical Company | Filtration aids for removal of calcium solids from aqueous phosphoric acid |
US4915859A (en) * | 1988-09-16 | 1990-04-10 | Nalco Chemical Company | Micro-emulsion drawing fluids for steel and aluminum |
US5100951A (en) * | 1988-09-23 | 1992-03-31 | Betz Laboratories, Inc. | Stable blends of cationic water-in-oil emulsion polymers and cationic aqueous solution polymers |
US4921903A (en) * | 1988-10-11 | 1990-05-01 | Nalco Chemical Company | Process for preparing high molecular weight hydrophobic acrylamide polymers |
US5006596A (en) * | 1990-02-09 | 1991-04-09 | Betz Laboratories, Inc. | Self-inverting, water-in-oil emulsions |
DE4111334A1 (de) * | 1990-11-14 | 1992-05-21 | Henkel Kgaa | Neue wasser-in-oel-emulsionen |
ES2100337T3 (es) * | 1991-02-14 | 1997-06-16 | Johnson & Son Inc S C | Composiciones polimericas mezcladas. |
US5178871A (en) * | 1991-06-26 | 1993-01-12 | S. C. Johnson & Son, Inc. | Stable double emulsions containing finely-divided particles |
US5925714A (en) * | 1994-03-04 | 1999-07-20 | Snf S.A. | Surfactant for self-inverting polyacrylmides |
FR2721511B1 (fr) * | 1994-06-22 | 1996-07-19 | Seppic Sa | Composition topique comprenant une phase aqueuse et un agent épaississant. |
US6210585B1 (en) | 1995-07-26 | 2001-04-03 | Nalco Chemical Company | Fatty acid free latex polymer flocculants |
US5837215A (en) * | 1995-07-26 | 1998-11-17 | Nalco Chemical Company | Method of removing insoluble materials from bayer process with fatty acid and fatty acid free polymer flocculants |
US6372204B1 (en) | 1996-02-15 | 2002-04-16 | Societe D'exploitation De Produits Pour Les Industries Chimiques, S.E.P.P.I.C. | Topical composition of unsaturated monoacid/monoacrylamide/polyfunctional monomer copolymer |
NO310581B1 (no) * | 1999-09-24 | 2001-07-23 | Procom As | Emulgert geleringsmiddel |
US6476168B1 (en) | 2001-09-14 | 2002-11-05 | Rhodia, Inc. | Emulsions having activating agents of alkoxylates of 6, 6-dimethylbicyclo [3.1.1] hept-2-ene-2-ethanol |
MX2017014523A (es) | 2015-05-13 | 2018-04-10 | Ecolab Usa Inc | Latex de agua en aceite invertibles y sus metodos de uso. |
US11384281B2 (en) | 2018-11-26 | 2022-07-12 | Halliburton Energy Services, Inc. | Methods for preparing invert emulsions using dibasic ester solvents |
CA3111764A1 (en) | 2018-11-26 | 2020-06-04 | Halliburton Energy Services, Inc. | Compositions and methods using subterranean treatment fluids comprising water-soluble polymers |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2982749A (en) * | 1957-07-15 | 1961-05-02 | Dow Chemical Co | Inverse suspension polymerization of water soluble unsaturated monomers |
US3284393A (en) * | 1959-11-04 | 1966-11-08 | Dow Chemical Co | Water-in-oil emulsion polymerization process for polymerizing watersoluble monomers |
US3734873A (en) * | 1970-12-15 | 1973-05-22 | Nalco Chemical Co | Rapid dissolving water-soluble polymers |
US3624019A (en) * | 1970-12-15 | 1971-11-30 | Nalco Chemical Co | Process for rapidly dissolving water-soluble polymers |
US3826771A (en) * | 1973-01-11 | 1974-07-30 | Nalco Chemical Co | Stable high solids water-in-oil emulsions of water soluble polymers |
-
1975
- 1975-01-22 US US05/542,982 patent/US3997492A/en not_active Expired - Lifetime
- 1975-06-02 CA CA228,238A patent/CA1050679A/en not_active Expired
- 1975-07-25 GB GB31245/75A patent/GB1511908A/en not_active Expired
- 1975-07-28 ZA ZA00754840A patent/ZA754840B/xx unknown
- 1975-08-11 ES ES440183A patent/ES440183A1/es not_active Expired
- 1975-08-18 SE SE7509193A patent/SE426492B/xx not_active IP Right Cessation
- 1975-08-21 DE DE2537586A patent/DE2537586B2/de not_active Ceased
- 1975-08-22 BR BR7505399*A patent/BR7505399A/pt unknown
- 1975-08-22 IT IT51029/75A patent/IT1041298B/it active
- 1975-08-25 FR FR7526186A patent/FR2298555A1/fr active Granted
- 1975-08-25 JP JP50102851A patent/JPS5187552A/ja active Pending
- 1975-08-25 BE BE1006841A patent/BE832701A/xx not_active IP Right Cessation
- 1975-08-25 NL NL7510025A patent/NL7510025A/xx not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
ZA754840B (en) | 1976-06-30 |
BE832701A (fr) | 1976-02-25 |
NL7510025A (nl) | 1976-07-26 |
AU8416875A (en) | 1977-02-24 |
US3997492A (en) | 1976-12-14 |
JPS5187552A (en) | 1976-07-31 |
SE426492B (sv) | 1983-01-24 |
CA1050679A (en) | 1979-03-13 |
SE7509193L (sv) | 1976-07-23 |
BR7505399A (pt) | 1976-09-08 |
FR2298555B1 (es) | 1978-04-28 |
FR2298555A1 (fr) | 1976-08-20 |
GB1511908A (en) | 1978-05-24 |
DE2537586B2 (de) | 1980-02-21 |
DE2537586A1 (de) | 1976-07-29 |
IT1041298B (it) | 1980-01-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ES440183A1 (es) | Un procedimiento de preparacion de una emulsion estable en agua,en aceite de polimeros y copolimeros de monomeros eli- lenicamente insaturados. | |
AU509069B2 (en) | Water-in-oil emulsions | |
AU506940B2 (en) | Freeze-thaw stable, self-inverting water-in-oil emulsion | |
NL7606534A (nl) | Diepe laminaire golfgenerator. | |
NL177015C (nl) | Verbeterde werkwijze voor de bereiding van een aromatisch koolwaterstofmengsel. | |
JPS52107083A (en) | Preparation of vinyl polymer emulsions | |
ES436656A1 (es) | Procedimiento para la obtencion de un latex polimerico con- teniendo grupos carboxilo. | |
NL185619C (nl) | Werkwijze voor het winnen van butadieen-1,3 uit mengsels van koolwaterstoffen, die vier koolstofatomen bevatten door middel van extractieve destillatie. | |
JPS51146586A (en) | Preparation of polymer emulsions | |
JPS52122278A (en) | Membrane for separation | |
NL7602997A (nl) | Polymeermengsel en werkwijze voor de bereiding ervan. | |
NL7710979A (nl) | Werkwijze voor de emulsiepolymerisatie van vinylchloride. | |
JPS51125442A (en) | A hydrous gel and a process for preparing it | |
IT1024398B (it) | Procedimento per la produzione di polimeri idrocarburici insaturi contenenti gruppi vinilici | |
CA1008108A (en) | Method for establishing core-flow in water-in-oil emulsions or dispersions | |
FR2276323A1 (fr) | Procede de polymerisation d'une olefine | |
GB1547331A (en) | Method of stabilizing an olefin polymer | |
JPS51125472A (en) | Preparation of sunthetic resin emvlsion | |
JPS5225039A (en) | Gel toilet good and a process for its preparation | |
SE410146B (sv) | Anordning for kontinuerligt genomforande av kemiska omsettningar. anvendning av densamma for polymerisation av vinylklorid | |
CA1026551A (en) | Apparatus for reclaiming strip-mined land | |
IT1062382B (it) | Procedimento per eliminare il cloruro di vinile monomerico residuo dal relativo polimero | |
JPS5297723A (en) | Paper for diazo copying | |
JPS52136286A (en) | Preparation of cationic vinyl polymer emulsions | |
SU502640A1 (ru) | Аппарат дл разделени водонефт ной эмульсии |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 20001204 |