ES404840A1 - Indonaniline leuco derivatives - Google Patents
Indonaniline leuco derivativesInfo
- Publication number
- ES404840A1 ES404840A1 ES404840A ES404840A ES404840A1 ES 404840 A1 ES404840 A1 ES 404840A1 ES 404840 A ES404840 A ES 404840A ES 404840 A ES404840 A ES 404840A ES 404840 A1 ES404840 A1 ES 404840A1
- Authority
- ES
- Spain
- Prior art keywords
- formula
- see formula
- diphenylamine
- given above
- meaning given
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/411—Aromatic amines, i.e. where the amino group is directly linked to the aromatic nucleus
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/413—Indoanilines; Indophenol; Indoamines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B53/00—Quinone imides
- C09B53/02—Indamines; Indophenols
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A method of preparing a hair dye composition, characterized by: a) subject to reduction, carried out in an alkaline aqueous medium or by catalytic hydrogenation in an appropriate organic solvent, an indoaniline of the formula **(See formula)** where the radicals R1 and R2, the same or different, each represent a hydrogen or halogen atom or a lower alkyl radical containing from 1 to 4 carbon atoms, at least one of which is different from a hydrogen atom; R3, R4, R5, R6 and R7, the same or different, each represent a hydrogen atom or a lower alkyl moiety of 1 to 4c optionally substituted with one or more hydroxyl, carbamoyl, piperidinyl or acylamino groups; on the other hand, R3 and R6 or R4 and R7 can form, together with the carbon and nitrogen atoms to which they are attached, a dihydrooxazinic or pyrrolinic heterocycle and Z represents an amino, acylamino or hydroxyl group, to obtain a diphenylamine of formula: **(See formula)** where a and Z have the meaning given above; or else condense a dinitrated derivative of formula: **(See formula)** where R3, R4 and R5 have the meaning given above and X represents a halogen atom, with a para-aminophenol of formula: **(See formula)** where R1 and R2 have the meaning indicated above, in order to obtain a dinitrodiphenylamine which is then reduced with sodium hydrosulfite in alkaline medium or by catalytic hydrogenation, to obtain a diphenylamine of formula: **(See formula)** where R1 to R5 have the meaning given above; b) separating the diphenylamines obtained in a) from the reaction mixture, by filtration after neutralization and/or cooling of the reaction medium or also by concentration followed by filtration after removing the catalyst: c) optionally recrystallizing the separated diphenylamines in b); d) dissolving at least one diphenylamine obtained in b) or in c) in an amount of 0.002 to 2% by weight, in an aqueous or hydroalcoholic solution that may contain other cosmetic ingredients and e) adjusting the pH in a range between 4 and 11 by means of a compatible acidifying or alkalizing agent, used in cosmetics. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
LU63527 | 1971-07-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES404840A1 true ES404840A1 (en) | 1975-06-01 |
Family
ID=19726766
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES404840A Expired ES404840A1 (en) | 1971-07-14 | 1972-07-13 | Indonaniline leuco derivatives |
Country Status (13)
Country | Link |
---|---|
AT (1) | AT337906B (en) |
AU (1) | AU459976B2 (en) |
BE (1) | BE786218A (en) |
CA (1) | CA997346A (en) |
CH (1) | CH547635A (en) |
DE (1) | DE2234476A1 (en) |
ES (1) | ES404840A1 (en) |
FR (2) | FR2174473A5 (en) |
GB (1) | GB1346535A (en) |
IT (1) | IT988349B (en) |
LU (1) | LU63527A1 (en) |
NL (1) | NL7209718A (en) |
SE (1) | SE374123B (en) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
LU69459A1 (en) * | 1974-02-22 | 1975-12-09 | ||
US4200432A (en) * | 1974-02-22 | 1980-04-29 | L'oreal | Dye composition containing oxidation dye and diphenylamine |
LU69458A1 (en) * | 1974-02-22 | 1975-12-09 | ||
LU69456A1 (en) * | 1974-02-22 | 1975-12-09 | ||
LU69457A1 (en) * | 1974-02-22 | 1975-12-09 | ||
US5026730A (en) * | 1987-08-21 | 1991-06-25 | Ciba-Geigy Corporation | Anilinophenylthioureas, compositions containing them, and the use thereof in pest control |
US5053540A (en) | 1990-03-08 | 1991-10-01 | The Goodyear Tire & Rubber Company | Preparation of a para-aminodiphenylamine |
DE4234886A1 (en) * | 1992-10-16 | 1994-04-21 | Wella Ag | New N-phenylaminopyrazole derivatives and agents and processes for coloring hair |
US5849042A (en) * | 1997-11-19 | 1998-12-15 | Bristol-Myers Squibb | Hair dye compositions containing 2,3 dialkyl-4-aminophenol and a 2-alkyl-1-naphthol |
FR2983856B1 (en) | 2011-12-13 | 2014-05-16 | Oreal | TRI-AROMATIC DIRECT AZOMETHINIC DYES, TINCTORIAL COMPOSITION COMPRISING AT LEAST ONE SUCH COLOR, PROCESS FOR IMPLEMENTATION AND USE |
FR2983855B1 (en) | 2011-12-13 | 2014-01-10 | Oreal | PARTICULATE AZOMETHINIC DYES, TINCTORIAL COMPOSITION COMPRISING AT LEAST ONE SUCH COLOR, PROCESS FOR CARRYING OUT AND USE |
FR2983711B1 (en) | 2011-12-13 | 2014-01-17 | Oreal | TRI-AROMATIC DIRECT AZOMETHINIC DYES COMPRISING AT LEAST ONE RESORCINOL-DERIVED PATTERN, TINCTORIAL COMPOSITION, PROCESS AND USE |
FR2983854B1 (en) | 2011-12-13 | 2014-01-10 | Oreal | PARTICULATE DIRECT QUININE DYES, TINCTORIAL COMPOSITION COMPRISING AT LEAST ONE SUCH COLOR, PROCESS FOR CARRYING OUT AND USE |
FR3006179B1 (en) | 2013-05-29 | 2015-05-15 | Oreal | QUINONIC DIRECT DYES WITH A CONTAINING ANILINE GROUP, TINCTORIAL COMPOSITION COMPRISING AT LEAST ONE SUCH COLOR, METHOD OF IMPLEMENTATION AND USE |
FR3060308B1 (en) | 2016-12-16 | 2020-06-19 | L'oreal | NOVEL DISSYMMETRIC AZOMETHINIC DIRECT DYES, COSMETIC COMPOSITION COMPRISING AT LEAST ONE SUCH DYE, PROCESS FOR USE AND USE |
FR3060331B1 (en) | 2016-12-16 | 2020-06-19 | L'oreal | NOVEL SYMMETRICAL AZOMETHINIC DIRECT DYES, COSMETIC COMPOSITION COMPRISING AT LEAST ONE SUCH DYE, PROCESS FOR USE AND USE |
FR3060562B1 (en) | 2016-12-16 | 2019-05-24 | L'oreal | NOVEL DIRECT AZOMETHINIC DYES HAVING AT LEAST ONE CATIONIC LOAD, COSMETIC COMPOSITION COMPRISING AT LEAST ONE SUCH DYE, METHOD FOR IMPLEMENTATION AND USE |
-
0
- BE BE786218D patent/BE786218A/xx unknown
-
1971
- 1971-07-14 LU LU63527D patent/LU63527A1/xx unknown
-
1972
- 1972-07-13 FR FR7225634A patent/FR2174473A5/fr not_active Expired
- 1972-07-13 SE SE927172A patent/SE374123B/xx unknown
- 1972-07-13 GB GB3281572A patent/GB1346535A/en not_active Expired
- 1972-07-13 AU AU44519/72A patent/AU459976B2/en not_active Expired
- 1972-07-13 CA CA147,117A patent/CA997346A/en not_active Expired
- 1972-07-13 NL NL7209718A patent/NL7209718A/xx unknown
- 1972-07-13 AT AT602172A patent/AT337906B/en not_active IP Right Cessation
- 1972-07-13 CH CH1056172A patent/CH547635A/en not_active IP Right Cessation
- 1972-07-13 IT IT6926472A patent/IT988349B/en active
- 1972-07-13 ES ES404840A patent/ES404840A1/en not_active Expired
- 1972-07-13 DE DE19722234476 patent/DE2234476A1/en active Pending
- 1972-12-19 FR FR7245274A patent/FR2165965B1/fr not_active Expired
Also Published As
Publication number | Publication date |
---|---|
NL7209718A (en) | 1973-01-16 |
FR2165965B1 (en) | 1983-04-29 |
ATA602172A (en) | 1976-11-15 |
AU459976B2 (en) | 1975-04-10 |
CH547635A (en) | 1974-04-11 |
IT988349B (en) | 1975-04-10 |
AU4451972A (en) | 1974-01-17 |
DE2234476A1 (en) | 1973-01-25 |
CA997346A (en) | 1976-09-21 |
FR2165965A1 (en) | 1973-08-10 |
GB1346535A (en) | 1974-02-13 |
SE374123B (en) | 1975-02-24 |
LU63527A1 (en) | 1973-01-23 |
FR2174473A5 (en) | 1973-10-12 |
BE786218A (en) | 1973-01-15 |
AT337906B (en) | 1977-07-25 |
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