ES401838A1 - Procedimiento para la preparacion de esteres de acido me- tantionofosfonico. - Google Patents
Procedimiento para la preparacion de esteres de acido me- tantionofosfonico.Info
- Publication number
- ES401838A1 ES401838A1 ES401838A ES401838A ES401838A1 ES 401838 A1 ES401838 A1 ES 401838A1 ES 401838 A ES401838 A ES 401838A ES 401838 A ES401838 A ES 401838A ES 401838 A1 ES401838 A1 ES 401838A1
- Authority
- ES
- Spain
- Prior art keywords
- formula
- group
- alcohol
- preparation
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 2
- WXJXBKBJAKPJRN-UHFFFAOYSA-N Methanephosphonothioic acid Chemical class CP(O)(O)=S WXJXBKBJAKPJRN-UHFFFAOYSA-N 0.000 title 1
- 125000003158 alcohol group Chemical group 0.000 abstract 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 239000011630 iodine Substances 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 125000002560 nitrile group Chemical group 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/42—Halides thereof
- C07F9/425—Acid or estermonohalides thereof, e.g. RP(=X)(YR)(Hal) (X, Y = O, S; R = H, or hydrocarbon group)
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing aromatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4084—Esters with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/42—Halides thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
Abstract
Procedimiento para la preparación de ésteres de ácido metentionofosfónico de la fórmula **fórmula** en la que X, Y y Z , que pueden ser iguales o diferentes significan hidrógeno, cloro, bromo, yodo o alcohilo y en la que Z puede representar también el grupo nitrilo, un grupo alcohiltio, alcohilsulfinilo, alcohilsulfonilo o carboalcoxi o un grupo carbamilo o sulfamilo, que puede estar sustituido una o dos veces en el átomo de nitrógeno, sobre todo por grupos alcohilo, y en la que R designa un grupo alcohilo o el radical. **fórmula** en que X, Y y Z, tienen los significados arriba indicados, caracterizado porque se reduce en caliente un compuesto de la fórmula **fórmula** con zinc y un ácido orgánico, eventualmente con adición de un disolvente orgánico inerte.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19712118861 DE2118861A1 (en) | 1971-04-19 | 1971-04-19 | Methanethionophosphonic acid esters - insecticides and acaricides |
| DE19722204777 DE2204777A1 (de) | 1972-02-02 | 1972-02-02 | Verfahren zur herstellung von 0-alkyl0-phenyl-methylthionophosphonsaeureestern |
| DE19722205564 DE2205564A1 (de) | 1972-02-07 | 1972-02-07 | Methanthionophosphonsaeurediphenylester |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES401838A1 true ES401838A1 (es) | 1975-10-16 |
Family
ID=27183366
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES401838A Expired ES401838A1 (es) | 1971-04-19 | 1972-04-17 | Procedimiento para la preparacion de esteres de acido me- tantionofosfonico. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US3794700A (es) |
| BE (1) | BE782334A (es) |
| CA (1) | CA997364A (es) |
| CH (1) | CH574969A5 (es) |
| CS (1) | CS173594B2 (es) |
| DD (1) | DD99381A5 (es) |
| DK (1) | DK130985B (es) |
| ES (1) | ES401838A1 (es) |
| FR (1) | FR2133916B1 (es) |
| GB (1) | GB1390556A (es) |
| HU (1) | HU164576B (es) |
| IL (1) | IL39249A (es) |
| IT (1) | IT957638B (es) |
| NL (1) | NL7205127A (es) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3881002A (en) * | 1972-06-02 | 1975-04-29 | Monsanto Co | Insecticidal O-phenyl S-aryl alkylphosphonodithioates |
-
1972
- 1972-01-18 DK DK188172AA patent/DK130985B/da unknown
- 1972-04-13 CS CS2488A patent/CS173594B2/cs unknown
- 1972-04-14 CH CH554872A patent/CH574969A5/xx not_active IP Right Cessation
- 1972-04-16 IL IL39249A patent/IL39249A/xx unknown
- 1972-04-17 NL NL7205127A patent/NL7205127A/xx unknown
- 1972-04-17 HU HUBO1364A patent/HU164576B/hu unknown
- 1972-04-17 ES ES401838A patent/ES401838A1/es not_active Expired
- 1972-04-18 GB GB1795472A patent/GB1390556A/en not_active Expired
- 1972-04-18 DD DD162372A patent/DD99381A5/xx unknown
- 1972-04-18 IT IT49713/72A patent/IT957638B/it active
- 1972-04-18 US US00245179A patent/US3794700A/en not_active Expired - Lifetime
- 1972-04-18 CA CA139,899A patent/CA997364A/en not_active Expired
- 1972-04-19 FR FR7213867A patent/FR2133916B1/fr not_active Expired
- 1972-04-19 BE BE782334A patent/BE782334A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| HU164576B (es) | 1974-03-28 |
| BE782334A (fr) | 1972-10-19 |
| IT957638B (it) | 1973-10-20 |
| CS173594B2 (es) | 1977-02-28 |
| CH574969A5 (es) | 1976-04-30 |
| DK130985C (es) | 1975-10-13 |
| DK130985B (da) | 1975-05-12 |
| IL39249A0 (en) | 1972-06-28 |
| GB1390556A (en) | 1975-04-16 |
| FR2133916A1 (es) | 1972-12-01 |
| US3794700A (en) | 1974-02-26 |
| CA997364A (en) | 1976-09-21 |
| DD99381A5 (es) | 1973-08-05 |
| IL39249A (en) | 1975-06-25 |
| NL7205127A (es) | 1972-10-23 |
| FR2133916B1 (es) | 1977-12-30 |
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