ES395527A1 - Catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxides - Google Patents

Catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxides

Info

Publication number
ES395527A1
ES395527A1 ES395527A ES395527A ES395527A1 ES 395527 A1 ES395527 A1 ES 395527A1 ES 395527 A ES395527 A ES 395527A ES 395527 A ES395527 A ES 395527A ES 395527 A1 ES395527 A1 ES 395527A1
Authority
ES
Spain
Prior art keywords
catalyst
hydroperoxides
oxirane compounds
epoxidizing olefins
producing oxirane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES395527A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of ES395527A1 publication Critical patent/ES395527A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0254—Nitrogen containing compounds on mineral substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0275—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B01J35/613—
    • B01J35/615—
    • B01J35/617—
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

A process for the preparation of oxirane compounds by reacting an olefinic compound with a hydroperoxide in the presence of a catalyst comprising an inorganic silicon oxygenate in chemical combination with at least 0.1% by weight of a titanium oxide or hydroxide, molybdenum, vanadium, zirconium or boron, characterized in that an improved catalyst is used which has been obtained by contacting said catalyst with a silylating agent at elevated temperatures, in particular up to 450ºC. (Machine-translation by Google Translate, not legally binding)
ES395527A 1970-10-01 1971-09-29 Catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxides Expired ES395527A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US7738570A 1970-10-01 1970-10-01

Publications (1)

Publication Number Publication Date
ES395527A1 true ES395527A1 (en) 1973-12-16

Family

ID=22137754

Family Applications (1)

Application Number Title Priority Date Filing Date
ES395527A Expired ES395527A1 (en) 1970-10-01 1971-09-29 Catalyst for producing oxirane compounds by epoxidizing olefins with hydroperoxides

Country Status (16)

Country Link
JP (1) JPS5440526B1 (en)
AT (1) AT315135B (en)
BE (1) BE773363A (en)
CA (1) CA1002056A (en)
CH (1) CH568792A5 (en)
DE (1) DE2148637C3 (en)
DK (1) DK150592C (en)
ES (1) ES395527A1 (en)
FR (1) FR2109867A5 (en)
GB (1) GB1339309A (en)
IE (1) IE35681B1 (en)
IT (1) IT938878B (en)
NL (1) NL153872C (en)
NO (2) NO129888B (en)
SE (1) SE377525B (en)
ZA (1) ZA716592B (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK151016C (en) * 1972-03-13 1988-06-27 Shell Int Research PROCEDURE FOR THE PREPARATION OF OXIRAN COMPOUNDS BY CONVERSING AN OLEFINIC UNLAMATED COMPOUND WITH AN ORGANIC HYDROPEROXIDE IN THE PRESENT OF A CATALYST
DE3734138A1 (en) * 1987-10-09 1989-04-20 Scharmer Klaus Dr Ing ACID CATALYST AND METHOD FOR PRODUCING THE CATALYST
CA2002341A1 (en) * 1988-11-09 1990-05-09 Takehisa Nakanishi Method for preparing epichlorohydrins
US5081267A (en) * 1989-10-05 1992-01-14 Arco Chemical Technology, Inc. Epoxidation process
US5319114A (en) * 1993-09-23 1994-06-07 Arco Chemical Technology, L. P. Olefin epoxidation using a carbon molecular sieve impregnated with a transition metal
EP0920909A1 (en) * 1994-03-31 1999-06-09 Exxon Chemical Patents Inc. Supported lewis acid catalysts for hydrocarbon conversion reactions
DE19545042A1 (en) * 1995-12-02 1997-06-05 Studiengesellschaft Kohle Mbh Amorphous microporous mixed oxide catalysts with controlled surface polarity for selective heterogeneous catalysis adsorption and material separation
DE19743165A1 (en) * 1997-09-30 1999-04-01 Studiengesellschaft Kohle Mbh Selective alkylation of aromatics with surface-modified microporous mixed oxides
KR20010020209A (en) * 1998-02-24 2001-03-15 고교기주츠인초가다이효스루니혼고쿠 Catalyst for partially oxidizing unsaturated hydrocarbon
SG73663A1 (en) * 1998-08-04 2000-06-20 Sumitomo Chemical Co A process for producing propylene oxide
SG82626A1 (en) * 1998-08-04 2001-08-21 Sumitomo Chemical Co Titanium-containing silicon oxide catalyst
JP2000279809A (en) * 1999-03-30 2000-10-10 Nippon Shokubai Co Ltd Catalyst for manufacture of epoxide and manufacture of epoxide
DE19925926A1 (en) * 1999-06-08 2000-12-14 Bayer Ag Catalysts based on titanium-containing, organic-inorganic hybrid materials for the selective oxidation of hydrocarbons
JP4694712B2 (en) * 2001-01-15 2011-06-08 丸善石油化学株式会社 Titanium-containing solid catalyst and method for producing epoxy compound using the same
CA3106070C (en) * 2018-07-30 2023-04-04 Kao Corporation Method for producing epoxyalkane and solid oxidation catalyst
KR102518067B1 (en) * 2020-01-14 2023-04-05 완후아 케미컬 그룹 코., 엘티디 Preparation method of propylene epoxidation catalyst and use thereof
CN113181961B (en) * 2020-01-14 2022-09-20 万华化学集团股份有限公司 Preparation method and application of propylene epoxidation catalyst

Also Published As

Publication number Publication date
AT315135B (en) 1974-05-10
NO138883C (en) 1978-11-29
DE2148637C3 (en) 1982-04-22
DK150592C (en) 1987-10-05
NO129888B (en) 1974-06-10
IE35681B1 (en) 1976-04-28
AU3399671A (en) 1973-04-19
IT938878B (en) 1973-02-10
DK150592B (en) 1987-04-06
ZA716592B (en) 1972-06-28
BE773363A (en) 1972-03-30
FR2109867A5 (en) 1972-05-26
IE35681L (en) 1972-04-01
JPS5440526B1 (en) 1979-12-04
NL7113338A (en) 1972-04-05
DE2148637A1 (en) 1972-04-06
NO138883B (en) 1978-08-21
CH568792A5 (en) 1975-11-14
SE377525B (en) 1975-07-14
NL153872C (en) 1981-07-16
CA1002056A (en) 1976-12-21
DE2148637B2 (en) 1981-02-26
GB1339309A (en) 1973-12-05
NL153872B (en) 1977-07-15

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