ES395616A1 - Method for the epoxidation of ethylene - Google Patents

Method for the epoxidation of ethylene

Info

Publication number
ES395616A1
ES395616A1 ES395616A ES395616A ES395616A1 ES 395616 A1 ES395616 A1 ES 395616A1 ES 395616 A ES395616 A ES 395616A ES 395616 A ES395616 A ES 395616A ES 395616 A1 ES395616 A1 ES 395616A1
Authority
ES
Spain
Prior art keywords
ethylene
solvent
epoxidation
hydroperoxide
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES395616A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Atlantic Richfield Co
Original Assignee
Atlantic Richfield Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atlantic Richfield Co filed Critical Atlantic Richfield Co
Publication of ES395616A1 publication Critical patent/ES395616A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A method for the epoxidation of ethylene by reaction of ethylene with tert-butyl hydroperoxide, in the presence of a molybdenum catalyst and a solvent, characterized in that the solvent is benzene, an alkylated benzene of 1 to 6 carbon atoms in the portion alkyl or a saturated alkane containing 7 to 14 carbon atoms and because the reaction is carried out between 80º and 115ºC, with an ethylene to hydroperoxide molar ratio of between 5: 1 and 20: 1 and a solvent to hydroperoxide molar ratio between 12: 1 and 25: 1. (Machine-translation by Google Translate, not legally binding)
ES395616A 1970-12-04 1971-09-30 Method for the epoxidation of ethylene Expired ES395616A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US9538070A 1970-12-04 1970-12-04

Publications (1)

Publication Number Publication Date
ES395616A1 true ES395616A1 (en) 1973-11-16

Family

ID=22251689

Family Applications (1)

Application Number Title Priority Date Filing Date
ES395616A Expired ES395616A1 (en) 1970-12-04 1971-09-30 Method for the epoxidation of ethylene

Country Status (8)

Country Link
BE (1) BE773865A (en)
CA (1) CA967582A (en)
DE (1) DE2148432A1 (en)
ES (1) ES395616A1 (en)
FR (1) FR2111317A5 (en)
GB (1) GB1337296A (en)
IT (1) IT939572B (en)
NL (1) NL7114023A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290527A (en) * 1992-11-05 1994-03-01 Texaco Chemical Company Molybdenum recovery
US5274138A (en) * 1993-01-21 1993-12-28 Texaco Chemical Company Epoxidation process for manufacture of olefin oxide and alcohol
US5539131A (en) * 1995-07-13 1996-07-23 Arco Chemical Technology, L.P. Olefin epoxidation process

Also Published As

Publication number Publication date
BE773865A (en) 1972-04-13
DE2148432A1 (en) 1972-06-08
FR2111317A5 (en) 1972-06-02
NL7114023A (en) 1972-06-06
CA967582A (en) 1975-05-13
IT939572B (en) 1973-02-10
GB1337296A (en) 1973-11-14

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