ES347461A1 - Improvements in or relating to rosin reaction products - Google Patents
Improvements in or relating to rosin reaction productsInfo
- Publication number
- ES347461A1 ES347461A1 ES347461A ES347461A ES347461A1 ES 347461 A1 ES347461 A1 ES 347461A1 ES 347461 A ES347461 A ES 347461A ES 347461 A ES347461 A ES 347461A ES 347461 A1 ES347461 A1 ES 347461A1
- Authority
- ES
- Spain
- Prior art keywords
- rosin
- reacted
- acid
- blend
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 title abstract 8
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 title abstract 8
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 title abstract 8
- 239000007795 chemical reaction product Substances 0.000 title 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 abstract 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000001530 fumaric acid Substances 0.000 abstract 2
- 239000001117 sulphuric acid Substances 0.000 abstract 2
- 235000011149 sulphuric acid Nutrition 0.000 abstract 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 2
- BRDWIEOJOWJCLU-LTGWCKQJSA-N GS-441524 Chemical compound C=1C=C2C(N)=NC=NN2C=1[C@]1(C#N)O[C@H](CO)[C@@H](O)[C@H]1O BRDWIEOJOWJCLU-LTGWCKQJSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 238000007127 saponification reaction Methods 0.000 abstract 1
- 239000003784 tall oil Substances 0.000 abstract 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/62—Rosin; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F1/00—Obtaining purification, or chemical modification of natural resins, e.g. oleo-resins
- C09F1/04—Chemical modification, e.g. esterification
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
A rosin is reacted with 4À5% to 8% of its weight of formaldehyde and/or acetaldehyde in the presence of sulphuric acid or an organosulphonic acid having 1 to 10 carbon atoms at a temperature between the melting point of the rosin and 225 C., the reaction mixture is maintained at this temperature for at least 10 minutes, the catalyst is neutralized with a basic material, the mixture again maintained at the elevated temperature for at least 10 minutes, and then the product is blended with an amount of unreacted rosin such that the blend contains from 2% to 4% of the aldehyde in reacted form based on the total weight of the rosin. The blend may be further reacted with an [alpha],#-unsaturated carboxylic acid or anhydride in an amount of 0À25% to 8% by weight of the blend, by heating at 160 to 220 C. The products are saponified to form size and made into aqueous pastes for use in the manufacture of paper. In examples tall oil rosin and wood rosin are reacted with formaldehyde in the presence of p-toluene sulphonic acid and sulphuric acid, the catalysts being neutralized with sodium hydroxide and blended with unreacted rosin some of the blends are further reacted with fumaric acid size pastes are obtained by saponification of the blends (whether or not reacted with fumaric acid) with sodium hydroxide and potassium hydroxide.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US59673266A | 1966-11-23 | 1966-11-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES347461A1 true ES347461A1 (en) | 1969-05-01 |
Family
ID=24388467
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES347461A Expired ES347461A1 (en) | 1966-11-23 | 1967-11-22 | Improvements in or relating to rosin reaction products |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS4932722B1 (en) |
| BE (1) | BE706843A (en) |
| DE (1) | DE1645528B2 (en) |
| DK (1) | DK126123B (en) |
| ES (1) | ES347461A1 (en) |
| FI (1) | FI48282C (en) |
| GB (1) | GB1210675A (en) |
| NL (1) | NL159427B (en) |
| NO (1) | NO127871B (en) |
| SE (2) | SE357000C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9610955D0 (en) * | 1996-05-24 | 1996-07-31 | Hercules Inc | Sizing composition |
-
1967
- 1967-11-21 GB GB5298767A patent/GB1210675A/en not_active Expired
- 1967-11-21 BE BE706843D patent/BE706843A/xx not_active IP Right Cessation
- 1967-11-21 NL NL6715764A patent/NL159427B/en not_active IP Right Cessation
- 1967-11-22 SE SE6716069A patent/SE357000C/xx unknown
- 1967-11-22 NO NO17063567A patent/NO127871B/no unknown
- 1967-11-22 SE SE794070A patent/SE384236B/en unknown
- 1967-11-22 FI FI315167A patent/FI48282C/en active
- 1967-11-22 ES ES347461A patent/ES347461A1/en not_active Expired
- 1967-11-23 DE DE1967T0035325 patent/DE1645528B2/en not_active Withdrawn
- 1967-11-23 DK DK588067A patent/DK126123B/en not_active IP Right Cessation
-
1971
- 1971-02-23 JP JP894771A patent/JPS4932722B1/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| SE357000C (en) | 1975-01-20 |
| JPS4932722B1 (en) | 1974-09-02 |
| FI48282B (en) | 1974-04-30 |
| FI48282C (en) | 1974-08-12 |
| DK126123B (en) | 1973-06-12 |
| SE384236B (en) | 1976-04-26 |
| GB1210675A (en) | 1970-10-28 |
| DE1645528A1 (en) | 1970-12-17 |
| SE357000B (en) | 1973-06-12 |
| NL6715764A (en) | 1968-05-24 |
| NL159427B (en) | 1979-02-15 |
| DE1645528B2 (en) | 1978-09-21 |
| BE706843A (en) | 1968-05-21 |
| NO127871B (en) | 1973-08-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19850211 |