ES322236A1 - The manufacture of aerylonitrile copolymers - Google Patents
The manufacture of aerylonitrile copolymersInfo
- Publication number
- ES322236A1 ES322236A1 ES0322236A ES322236A ES322236A1 ES 322236 A1 ES322236 A1 ES 322236A1 ES 0322236 A ES0322236 A ES 0322236A ES 322236 A ES322236 A ES 322236A ES 322236 A1 ES322236 A1 ES 322236A1
- Authority
- ES
- Spain
- Prior art keywords
- monomers
- weight
- acrylonitrile
- styrene
- copolymerized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B17/00—Surgical instruments, devices or methods, e.g. tourniquets
- A61B17/08—Wound clamps or clips, i.e. not or only partly penetrating the tissue ; Devices for bringing together the edges of a wound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/42—Nitriles
- C08F220/44—Acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Surgery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Molecular Biology (AREA)
- Medical Informatics (AREA)
- Heart & Thoracic Surgery (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
In a process for copolymerizing acrylonitrile in emulsion the polymerization is effected in the presence of (a) an emulsifier, (b) 0À2-5%, based on the weight of monomers, of an organic polyhalide of formula C n X 2n+2 , where n is 1, 2 or 3 and X represents Cl and/or Br, (c) a copper compound capable of supplying 150- 1000 mg. of ionic copper per 100 litres of emulsion, (d) 0À1-5%, based on the weight of monomers, of a water-soluble reducing agent capable of at least partially reducing the copper compound to the metallic state, (e) 0À01-0À1%, based on the weight of monomers, of a Redox adjuvant, and (f) less than 1%, based on the weight of monomers of free ammonia. Specified components are (a) oleic acid (apparently in ammonium salt form) and its sodium salt, (b) carbon tetrachloride, (c) copper sulphate, (d) hydrazine hydrate, and (e) polyphenols, aminophenols, hydroquinone, oxyhydroquinone, chlorhydroquinone, gallic acid, pyrogallol and iconogen (1 -amino-2-oxynaphthyl-6- sulphonic acid). The acrylonitrile may be copolymerized with one or more compounds selected from styrene, butadiene, isoprene, chloroprene and vinyl chloride. In one Example, acrylonitrile is copolymerized with styrene in the presence of a polybutadiene latex. An ABS resin may also be produced by copolymerizing acrylonitrile in the presence of the elastomer latex described in Example 5 of French Specification 1,324,321, i.e. a butadiene-styrene copolymer latex.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR3396A FR1435002A (en) | 1965-01-25 | 1965-01-25 | Process for the manufacture of acrylonitrile copolymers and products obtained by this process |
Publications (1)
Publication Number | Publication Date |
---|---|
ES322236A1 true ES322236A1 (en) | 1966-08-01 |
Family
ID=8569316
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES0322236A Expired ES322236A1 (en) | 1965-01-25 | 1966-01-25 | The manufacture of aerylonitrile copolymers |
Country Status (7)
Country | Link |
---|---|
BE (1) | BE675241A (en) |
DE (1) | DE1620964A1 (en) |
ES (1) | ES322236A1 (en) |
FR (1) | FR1435002A (en) |
GB (1) | GB1132265A (en) |
LU (1) | LU50309A1 (en) |
NL (2) | NL6600693A (en) |
-
0
- NL NL127445D patent/NL127445C/xx active
-
1965
- 1965-01-25 FR FR3396A patent/FR1435002A/en not_active Expired
-
1966
- 1966-01-18 BE BE675241D patent/BE675241A/xx unknown
- 1966-01-19 NL NL6600693A patent/NL6600693A/xx unknown
- 1966-01-22 DE DE19661620964 patent/DE1620964A1/en active Pending
- 1966-01-24 GB GB311666A patent/GB1132265A/en not_active Expired
- 1966-01-24 LU LU50309A patent/LU50309A1/xx unknown
- 1966-01-25 ES ES0322236A patent/ES322236A1/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR1435002A (en) | 1966-04-15 |
DE1620964A1 (en) | 1970-05-21 |
LU50309A1 (en) | 1966-07-25 |
GB1132265A (en) | 1968-10-30 |
BE675241A (en) | 1966-05-16 |
NL6600693A (en) | 1966-07-26 |
NL127445C (en) |
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