ES2794828T3 - Un procedimiento para la obtención de un polímero catiónico con una distribución por lo menos bimodal de peso molecular - Google Patents
Un procedimiento para la obtención de un polímero catiónico con una distribución por lo menos bimodal de peso molecular Download PDFInfo
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- ES2794828T3 ES2794828T3 ES17700447T ES17700447T ES2794828T3 ES 2794828 T3 ES2794828 T3 ES 2794828T3 ES 17700447 T ES17700447 T ES 17700447T ES 17700447 T ES17700447 T ES 17700447T ES 2794828 T3 ES2794828 T3 ES 2794828T3
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- cationic polymer
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- 229920006317 cationic polymer Polymers 0.000 title claims abstract description 129
- 238000000034 method Methods 0.000 title claims abstract description 75
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- 229920000642 polymer Polymers 0.000 claims abstract description 80
- 125000002091 cationic group Chemical group 0.000 claims abstract description 41
- 238000004062 sedimentation Methods 0.000 claims abstract description 38
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 31
- 150000001875 compounds Chemical class 0.000 claims abstract description 27
- 239000012986 chain transfer agent Substances 0.000 claims abstract description 18
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 17
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims abstract description 8
- 125000000923 (C1-C30) alkyl group Chemical group 0.000 claims abstract description 6
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 5
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims abstract description 5
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- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 12
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 7
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- KNSXNCFKSZZHEA-UHFFFAOYSA-N [3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C KNSXNCFKSZZHEA-UHFFFAOYSA-N 0.000 claims description 7
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- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims description 5
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- FYRWKWGEFZTOQI-UHFFFAOYSA-N 3-prop-2-enoxy-2,2-bis(prop-2-enoxymethyl)propan-1-ol Chemical compound C=CCOCC(CO)(COCC=C)COCC=C FYRWKWGEFZTOQI-UHFFFAOYSA-N 0.000 claims description 4
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- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
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- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims description 4
- FZGFBJMPSHGTRQ-UHFFFAOYSA-M trimethyl(2-prop-2-enoyloxyethyl)azanium;chloride Chemical group [Cl-].C[N+](C)(C)CCOC(=O)C=C FZGFBJMPSHGTRQ-UHFFFAOYSA-M 0.000 claims description 4
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 claims description 4
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- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 claims description 2
- LVKKFNORSNCNPP-UHFFFAOYSA-N 2,2-bis(prop-2-enoylamino)acetic acid Chemical compound C=CC(=O)NC(C(=O)O)NC(=O)C=C LVKKFNORSNCNPP-UHFFFAOYSA-N 0.000 claims description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical group S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 2
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- 235000014655 lactic acid Nutrition 0.000 claims description 2
- 239000004310 lactic acid Substances 0.000 claims description 2
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical class O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 abstract description 8
- 239000002904 solvent Substances 0.000 description 62
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 51
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- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 15
- AVTLBBWTUPQRAY-UHFFFAOYSA-N 2-(2-cyanobutan-2-yldiazenyl)-2-methylbutanenitrile Chemical compound CCC(C)(C#N)N=NC(C)(CC)C#N AVTLBBWTUPQRAY-UHFFFAOYSA-N 0.000 description 14
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- 150000004665 fatty acids Chemical class 0.000 description 14
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- OPJWPPVYCOPDCM-UHFFFAOYSA-N 2-ethylhexyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC OPJWPPVYCOPDCM-UHFFFAOYSA-N 0.000 description 13
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- LQPLDXQVILYOOL-UHFFFAOYSA-I pentasodium;2-[bis[2-[bis(carboxylatomethyl)amino]ethyl]amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC(=O)[O-])CCN(CC([O-])=O)CC([O-])=O LQPLDXQVILYOOL-UHFFFAOYSA-I 0.000 description 12
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- WQHCGPGATAYRLN-UHFFFAOYSA-N chloromethane;2-(dimethylamino)ethyl prop-2-enoate Chemical group ClC.CN(C)CCOC(=O)C=C WQHCGPGATAYRLN-UHFFFAOYSA-N 0.000 description 10
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
-
- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F226/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a single or double bond to nitrogen
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F226/10—N-Vinyl-pyrrolidone
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/05—Bimodal or multimodal molecular weight distribution
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
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| EP16152590 | 2016-01-25 | ||
| PCT/EP2017/050829 WO2017129434A1 (en) | 2016-01-25 | 2017-01-16 | A process for obtaining a cationic polymer with an at least bimodal molecular weight distribution |
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| FR3079833B1 (fr) | 2018-04-10 | 2020-10-09 | Rhodia Operations | Composition aqueuse gelifiee pour l'extraction petroliere |
| FR3096985B1 (fr) * | 2019-06-05 | 2021-05-14 | S N F Sa | Procede de preparation de polymeres structures sous forme de poudre par voie gel |
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| DE10059824A1 (de) * | 2000-12-01 | 2002-06-13 | Clariant Gmbh | Elektrolythaltige kosmetische, pharmazeutische und dermatologische Mittel |
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| WO2003102043A1 (en) | 2002-06-04 | 2003-12-11 | Ciba Specialty Chemicals Holdings Inc. | Aqueous polymer formulations |
| MXPA05001801A (es) * | 2002-08-15 | 2005-04-19 | Ciba Spec Chem Water Treat Ltd | Polimeros cationicos de alto peso molecular obtenidos por reaccion de reticulacion posterior a la polimerizacion. |
| ATE334182T1 (de) | 2002-11-29 | 2006-08-15 | Ciba Sc Holding Ag | Wässrige zusammensetzungen mit homo- und/oder copolymeren |
| FR2879607B1 (fr) | 2004-12-16 | 2007-03-30 | Seppic Sa | Nouveaux latex inverse concentre, procede pour sa preparation, et utilisation dans l'industrie |
| ZA200704946B (en) * | 2004-12-28 | 2008-09-25 | Akzo Nobel Nv | Polymer dispersion and process for preparing a polymer dispersion |
| MX295407B (es) * | 2005-01-27 | 2012-02-01 | Ciba Sc Holding Ag | Uso de polimeros cationicos solubles en agua, reticulados, de alto peso molecular en formulaciones de cuidado de cabello. |
| US7639737B2 (en) | 2006-04-27 | 2009-12-29 | Rambus Inc. | Adaptive equalization using correlation of edge samples with data patterns |
| US20110301312A1 (en) | 2009-01-06 | 2011-12-08 | S.P.C.M. Sa | Cationic polymer thickeners |
| MX2011007285A (es) | 2009-01-06 | 2011-08-08 | Unilever Nv | Mejoras que se refieren a acondicionadores de generos. |
| PL2419462T3 (pl) * | 2009-04-17 | 2015-12-31 | Solenis Tech Cayman Lp | Bimolekularna odwrócona emulsja polimerowa |
| JP2012254430A (ja) * | 2011-06-10 | 2012-12-27 | Hymo Corp | 凝集処理剤およびそれを用いた汚泥脱水方法 |
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| WO2013174622A1 (en) | 2012-05-21 | 2013-11-28 | Basf Se | Inverse dispersion comprising a cationic polymer and a stabilizing agent |
| JP2014233647A (ja) * | 2013-05-31 | 2014-12-15 | ハイモ株式会社 | 凝集処理剤及び汚泥の脱水方法 |
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| WO2016127387A1 (en) | 2015-02-13 | 2016-08-18 | The Procter & Gamble Company | Cleaning compositions containing alkyl sulfate surfactants and cationic polymer for holistic improvement of sudsing profile |
| EP3122856A1 (en) | 2014-03-26 | 2017-02-01 | The Procter & Gamble Company | Cleaning compositions containing cationic polymers, and methods of making and using same |
| WO2015143645A1 (en) | 2014-03-26 | 2015-10-01 | The Procter & Gamble Company | Cleaning compositions containing cationic polymers, and methods of making and using same |
| WO2015143644A1 (en) | 2014-03-26 | 2015-10-01 | The Procter & Gamble Company | Cleaning compositions containing cationic polymers, and methods of making and using same |
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| EP3172307A1 (en) | 2014-07-23 | 2017-05-31 | The Procter and Gamble Company | Treatment compositions |
| US10519402B2 (en) | 2014-07-23 | 2019-12-31 | The Procter & Gamble Company | Treatment compositions |
| CA2951936A1 (en) | 2014-07-23 | 2016-01-28 | The Procter & Gamble Company | Fabric and/or home care compositions |
| EP3172301B1 (en) | 2014-07-23 | 2019-01-02 | The Procter and Gamble Company | Fabric and home care treatment compositions |
| WO2016014743A1 (en) | 2014-07-23 | 2016-01-28 | The Procter & Gamble Company | Fabric and home care treatment compositions |
| EP3172302B1 (en) | 2014-07-23 | 2019-01-16 | The Procter & Gamble Company | Fabric and home care treatment compositions |
| US20160024427A1 (en) | 2014-07-23 | 2016-01-28 | The Procter & Gamble Company | Treatment compositions |
| KR20170039200A (ko) | 2014-07-23 | 2017-04-10 | 바스프 에스이 | 양이온성 중합체, 안정화제 및 ３관능성 및／또는 다관능성 가교제를 포함하는 역 분산액 |
| JP6728132B2 (ja) | 2014-08-27 | 2020-07-22 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | カチオン性ポリマーを含む洗剤組成物 |
| JP6672266B2 (ja) | 2014-08-27 | 2020-03-25 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | カチオン性ポリマーを含む洗剤組成物 |
| WO2016032995A1 (en) | 2014-08-27 | 2016-03-03 | The Procter & Gamble Company | Method of treating a fabric |
| EP3186344B1 (en) | 2014-08-27 | 2020-02-26 | The Procter and Gamble Company | Method of preparing a detergent composition |
| RU2560177C1 (ru) * | 2014-10-16 | 2015-08-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Волгоградский государственный технический университет" (ВолгГТУ) | Способ получения водорастворимых полимеров на основе четвертичных солей диметиламиноэтилметакрилата |
| ES2814152T3 (es) | 2014-11-18 | 2021-03-26 | Basf Se | Modificador de reología |
| US10689600B2 (en) | 2016-01-25 | 2020-06-23 | The Procter & Gamble Company | Treatment compositions |
| CN108495868B (zh) | 2016-01-25 | 2021-03-19 | 巴斯夫欧洲公司 | 具有至少双峰分子量分布的阳离子聚合物 |
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| PL3408301T3 (pl) | 2020-08-24 |
| EP3408301A1 (en) | 2018-12-05 |
| CA3009585A1 (en) | 2017-08-03 |
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| US10920001B2 (en) | 2021-02-16 |
| WO2017129434A1 (en) | 2017-08-03 |
| KR20180104298A (ko) | 2018-09-20 |
| CN108602902A (zh) | 2018-09-28 |
| US20190062478A1 (en) | 2019-02-28 |
| EP3408301B1 (en) | 2020-03-11 |
| RU2018130687A (ru) | 2020-02-27 |
| BR112018014989A2 (en) | 2018-12-11 |
| JP2019505657A (ja) | 2019-02-28 |
| BR112018014989B1 (pt) | 2022-06-28 |
| RU2018130687A3 (enExample) | 2020-03-25 |
| JP7068190B2 (ja) | 2022-05-16 |
| CN108602902B (zh) | 2021-06-04 |
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