ES2748587T3 - Blend of additives for addition to a mix of coating materials and a composite coating system made from it - Google Patents

Abstract

Additive mix to add to a mix of cladding materials to form a composite cladding system for the floor, wall or façade sector, where the additive mix comprises a proportion of between 50% by weight and 95% by weight of muscovite mica and the additive mixture is in the form of powder or granules, characterized in that the proportion of muscovite mica in the additive mixture is composed of muscovite mica with at least two different particle sizes of a first part of particles with a fine particle size greater than 150 µm and less than 300 µm, and a second part with an average particle size greater than 400 µm and less than or equal to 800 µm or a first part of particles with a fine particle size greater than 150 µm and less than 300 µm, a second part of particles with an average particle size greater than 400 µm and less than 800 µm, and a third of particles with a particle size coarse with average particle diameters greater than or equal to 800 µm or one-second of a mean grain size greater than 400 µm and less than 800 µm, and one-third of a coarse-grained size of average particle diameters larger or equal to 800 μm.

Description

DESCRIPTION

Blend of additives for addition to a mix of coating materials and a composite coating system made from it

Technical field

The present invention describes a mixture of additives for addition to a mixture of coating materials to form a composite coating system for the floor, wall or facade sector, where the mixture of additives comprises a proportion of between 50% in weight and 95% by weight of muscovite mica and the mixture of additives is present in the form of powder or granules, a composite coating system for the floor, wall or facade sector, formed from a mixture of fluid coating materials or smoothing, as well as a method for manufacturing a composite cladding system for the floor, wall or façade sector, comprising a mixture of cladding materials and a mixture of additives.

State of the art

Construction material mixtures are commercially available to the construction industry, such as concrete, plaster and paint mixtures, which have an additive mixture comprising a proportion of mica, mainly in the form of Muscovite mica.

Muscovite mica has a general chemical composition of KAI2 [(OH, F) 2 | AISÍ3O-io], crystallizes in a monoclinic or trigonal crystal system, is a mineral of the mineral class of silicates and germanates, and belongs to the phyllosilicates . Muscovite mica is also called alumina mica, it is very common and is mined from natural deposits.

It is known that adding a small amount of Muscovite mica in plasters or paints can achieve a special visual impression of the plaster. Since Muscovite mica is a flaky mineral with a glazed or pearlized surface and is mostly whitish gray in color, the addition of small amounts has long been used by the skilled artisan to achieve decorative effects. Known mixtures of construction materials in plaster form include muscovite mica in particulate form having especially fine particle size in amount ratios of 0.5% by weight to a maximum of 1% by weight. Even such small amounts of muscovite mica lead to the production of the desired decorative effects.

It is also known that a form of reinforcement is achieved by adding minimal amounts of Muscovite mica in mixtures of building materials, for example, in the form of concrete. Muscovite mica particles are insoluble in water, chemically inert and have a lamellar structure, which is preserved during the production and processing of mixtures of building materials. The susceptibility to cracking in cast concrete components can be greatly reduced by adding small amounts of Muscovite mica due to the sheet structure. Due to the properties of muscovite mica, it is known that, in addition to mixtures of building materials in small quantities of at most 1% by weight, less shrinkage can be achieved when the mixture of building materials is set, so the risk of cracking is reduced.

The prior art describes a minimal addition of Muscovite mica that is less than or equal to 1% by weight of the construction material mixture. Even this small amount of muscovite mica leads to the desired mechanical properties and improved setting behavior of building material mixtures. Muscovite mica is already being used in applications in the construction industry, which is evident, inter alia, from documents EP0879805, DE69804134, AT230260 and DE102008001808. The resulting additive mixtures have different amounts of substance and different grain size distributions of muscovite mica, which do not lead to the solution of the task listed below.

Description of the Invention

The present invention has set itself the task of reducing the thermal conductivity or heat dissipation of cladding systems for the floor, wall or facade sector. Heat dissipation through objects and substrates coated with the coating systems should be reduced so that when entering the surface provided with the coating system no more cold feet are felt and therefore more heat is achieved Sliding.

By spreading a mixture of additives into a filler paste of a known coating material mixture or a mixture of the additive mixture with a dry mixture of a known coating material mixture, a composite coating system is formed in different surfaces and substrates. After drying or setting, a composite coating system is formed that greatly reduces heat dissipation through the coated object, especially in the direction of normality of the surface coated with the composite coating system. When touching or walking on the surface of the substrate with the composite coating system, a person is less likely to have cold hands or feet. This reduced heat dissipation effect through the composite cladding system is not only felt subjectively but is also objectively measured by heat dissipation measurements.

The stated object is achieved by adding or spreading an additive comprising a high proportion of Muscovite mica to the mixture of building materials, before the composite coating system sets and thus complies.

The object is preferably achieved because the additive comprises a proportion of muscovite mica of between 60% by weight and 95% by weight. An amount of at least 5% by weight of the 50% by weight Muscovite mica within the resulting composite coating system has led to desired results which have greatly influenced heat production.

Brief description of the drawings

The object of the present invention will now be described, in which the accompanying drawings are used to illustrate the measured heat conduction properties or the heat dissipation properties of different composite coating systems.

Figure 1 shows a diagram of cooling of a copper block during heat release versus time in four composite cladding systems, measured by the measurement method according to the SIA 252 standard introduced by EMPA Dübendorf.

Figure 2 shows the measured values recorded during the cooling of a copper block with heat release to a test sample with a composite coating system comprising an industrial epoxy coating with a mixture of additives spread over the 30 minute measurement period. .

Description

The following describes a mixture of mineral-based additives that forms a composite coating system with a known commercially available coating material blend.

This additive blend is marketed under the applicant's ISOPOWDER brand in various recipes. The particular recipe to be used and therefore the composition of the additive mix depends on the selected coating material mix in which the additive mix is to be mixed or spread.

The composite cladding system is applied to different object surfaces and therefore to different substrates, land or industrial spaces in the form of floors, walls, ceilings or facades. Although the pure coating material mixture has little or no thermal insulation properties, the thermal conductivity properties of the resulting composite coating system is greatly altered by the addition of the additive mixture. The resulting thickness of the composite coating system is in the range of a few millimeters.

Applicable coating mixes to form the desired lamination systems on an existing prepared surface are covered by SIA 252, a registered standard of the Swiss Association of Standards in the field of civil engineering. These mixtures of coating materials can form composite coating systems in the form of seamless industrial floor coverings after addition of the additive. Mineral coatings such as hard concrete coatings, synthetic resin and cement coatings, contact injection coatings, xylolite coatings, magnesia coatings or anhydrite deposits, which are formed from of water, sand, gravel and an anhydrite binder.

As other mixtures of coating materials, synthetic resin coatings or coatings containing plastics can be used, which are generally applied in thinner layers on the substrate. The application of the pure coating material mixture or the mixed coating material mixture with the additive mixture takes place in at least one operation.

When used in thin film systems, the additive mix amounts are 7% to 20% by weight of the mix amount of coating materials for mineral coatings and in industrial PU and epoxy resin systems, including 40% to 50% by weight of the amount of the coating material mix for a spread coat.

Dry mix

On the one hand, prior to application, a dry powder or granule mixture can be prepared, comprising the mixture of coating materials and the mixture of additives by mixing. This dry mix can be combined by mixing with mixing water and additives to form a filling paste, which can be applied with a spatula or is pourable. This filler paste is then applied to the substrate in the desired layer thickness. After drying or setting, additional coats can be applied, for example at least one coat sealing.

Spread on the filling paste

However, if mixtures of coating materials are used in the form of plastic or synthetic resin coatings, for example a polyurethane coating or an epoxy resin coating, the additive mixture can also be interleaved later. After application and spreading and / or spatulation of the coating material mixture, a desired amount of the additive mixture is spread in the coating material mixture so that the mixture of the additive mixture with the mixture of lining materials take place only after application of the lining material mixture.

The filling paste, which comprises a mixture of coating materials or a mixture of coating materials and a mixture of additives, can be applied in a single layer and without joints in a single operation, simply and quickly. The resulting composite coating system has sufficiently high compressive strength and tensile strength, and the heat dissipation of the substrate, heat dissipation, is reduced as desired by adding the admixture mixture.

Definition of the additive

The main component of the additive mix is Muscovite mica, which is present in powder or granule form in a proportion of 50% to 95% by weight in the additive mix.

The proportion of muscovite mica must be present in different grain sizes. It has been found that good heat dissipation values of the resulting composite coating system are established when using at least two amounts of different grain sizes. Depending on the mixture of coating materials used, the proportion of muscovite mica should be composed of particles with a fine grain size greater than 150 pm and less than 300 pm, with a finer grain size greater than 400 pm and less than 800 pm and / or a coarse grain size with particle sizes greater than or equal to 800 pm. Good results were obtained using muscovite mica MU in the form of MU85 (mean particle size> 160 pm), MU450 (> 630 pm) and MU800 (> 800 pm). Particle size is determined by calculating the mean particle diameter on scanning electron microscope images of a random sample of the respective Muscovite mica.

A mixture of additives with muscovite mica in the form of a fine grain part and a medium grain part has given good results.

The addition of an additional portion of muscovite mica with a coarse grain size has been successful with the desired thermodynamic properties.

As experiments have shown, with a mixture of additives with a proportion of Muscovite mica with a coarse and fine grain size, as well as with a mixture of additives with a proportion of Muscovite mica with a coarse and fine grain size, The desired thermodynamic properties of the resulting composite coating systems could be achieved.

By adding the additive mixture comprising muscovite mica in high concentrations, a composite coating system can be achieved that has a sliding heat similar to that of a xylolite coating. Slip heat is used here to refer to such a low thermal conductivity that, when walking through the composite cladding system, you do not have cold feet.

Due to the different additive mix recipes itself or the proportion of the additive mix in the mix of coating materials, hard concrete, anhydrite, PU, epoxy resin coatings and other coatings can now be achieved with a desired slip heat.

At the same time, with the following components, the coating material mixtures modified by the high proportion of Muscovite mica must be adapted again to restore the leveling properties, processability, as well as the proportion of binder, segregation, etc. Therefore, it is important that any commercially available coating material mix is mixed with a balanced formulation of the ISOPOWDER additive mix and a balanced amount ratio to achieve the desired slip heat while meeting the processing and installation standards for the entire coating system.

Optional components

To maintain or restore the processing properties and mechanical strength of the coating material mixture being mixed with the additive mixture, different additives are added to the additive mixture.

At least one leveling optimizer, also called a superplasticizer, a segregation stabilizer, at least one binder, for example, Portland cement, a filler and binder, for example, carbonate of Calcium, a fire protection component, a coating stabilizer and / or a white pigment, are added to the additive mix as an additive. Depending on the desired additive mix, which is tailored to the mix of coating materials, different additive concentrations are selected, resulting in different recipes for the additive mix.

As a flow optimizer, Melflux® 2651 F was used in part also in excessive dosage to reinsure the course of a coating or leveling mortar. In the case of hard concrete coatings, this also improves the uniform distribution of sand, cement, ISOPOWDER, etc. and simplifies processability.

Starvis 3003 F was added as a stabilizer to the additive mix to control segregation if the water content was too high. This product is also applied in excessive partial dose because the main component of Muscovite mica in the additive mixture is highly absorbent and behaves like a water reservoir. However, this property is also very effective, as it counteracts the formation of cracks by slow release of moisture, especially in hard concrete coatings.

White Portland cement (EN 197-1 CEM I 52.5 N (sw)) was used as a binder mainly in cementitious mineral coatings, which have a very high purity content, in addition to the lack of binder content due to to the high addition of ISOPOWDER.

In addition, the use of Portland CEM I 42.5 R cement as a binder was tested and used for hard concrete coatings and siding products, which do not require a high proportion of white cement content. Here too the lack of binder ratio is replaced due to the high addition of ISOPOWDER. As a filler and binder Minema 60/10, a calcium carbonate was used, which is used in the mineral coatings that we know or are compatible with other coatings and must be added as a supplement by the high mixture of ISOPOWDER to compensate for the absorption behavior (breathability) as well as the degree of hardness. It also serves as a filler, which is very rare in part, especially in mineral coatings.

APYRAL 24 was used as a fire protection component in the tests, minimizing the combustibility of the composite coating system. With APYRAL 24, the required compensation is restored so that the corresponding products, such as STO Creativ Mineral, do not lose the certification of the fire class, despite the fact that the mixture of additives is not flammable.

As a coating stabilizer, SIHELCO 35 quartz was used, which is a very pure and high quality quartz, which was selected because it is compatible and usable in various mineral coatings and leveling mortars. Therefore, with a dose of 5% to 20% with only one type of quartz, the balance can be created to achieve the processing, the appearance and also the resistance of the usual composite coating system. Titanium dioxide (Pretiox) was used as the white pigment.

Additive in possible concentrations

The muscovite mica content of the additive mixture in the experiments was between the minimum value A in percentage by weight and the maximum value B in percentage by weight of the total mass of the additive mixture.

The additives used were used in amounts relative to the total mass of the additive mixture between A and B according to the following table, with good results achieved.

(continuation)

Formulation Example 1

BASF self-leveling putty was used as a blend of coating materials with the following composition to produce a first composite coating system:

This mixture of coating materials was mixed with a mixture of additives in the following composition:

(continuation)

The additive mix here exhibits Muscovite mica with two different grain sizes.

This first composite coating system was produced in two versions, in which in a first test I) 10% by weight (800 g of mixture of coating material, 80 g of mixture of additives 2 ', 193.6 g of water ) and in the second test II) 15% by weight of additive mixture (800 g of mixture of coating materials, 120 g of mixture of additives, 202.4 g of water) are mixed with the mixture of coating materials as mineral coating (BASF mix) and additional mixing water was added. The resulting flow properties, appearance, as well as heat conduction properties of the composite coating system were desired.

Formulation example 2

To a second mix of mineral coating materials, sold under the name "Sto Creativ Mineral", a mix of additives was added in the following composition:

Here, the Muscovite mica ratio has three different grain sizes.

In total, 3 kg of the additive was mixed with 15 kg of the "Sto Creativ Mineral" coating material mixture and mixed with additional mixing water. Therefore, the amount of the additive mixture was 20% of the mass of the coating material mixture, so that the mixing ratio corresponded to 1 part of the additive mixture to 5 parts of the material mixture Coating.

Formulation Example 3

A mixture of coating materials in the form of industrial hard concrete coating was mixed with a mixture of additives according to the following composition:

(continuation)

Again, the additive mix in each case has three different grain sizes.

Thermodynamically Verified Test Series

Various composite liner systems are applied to a 400mm long and 120mm thick square concrete block. Before taking measurements of the heat sink, the composite coating systems were fully cured and dry. Two test pieces (P1, P2) each received an identical composite coating system. Before carrying out the heat dissipation, the test samples were stored for 48 hours at a constant temperature of 20 ° C. The heat dissipation was measured in both test samples under the same conditions, in each case in two passes, and an average of the measured heat dissipation of both test samples was determined. Since two measurements were made per sample, averages of four measurements were obtained, 1AP1, 1AP2, 1BP1, 1BP2.

To measure heat dissipation and therefore perpendicular heat conduction through the test sample with the composite cladding system applied to the surface, a cylindrical copper block preheated to 52 ° C with a diameter is used 120 mm and 113 cm2 front contact surface The cylindrical copper block is thermally insulated along the circumferential surface and on the front side facing outward from the specimen. Therefore, the thermal energy of the copper block can be transmitted or passed only through the front contact surface with which the copper block is placed in the sample composite coating system. Temperature loss was determined after placing the copper block in the sample within 30 minutes.

To minimize the error caused by the heat emission from the copper block to the environment, a control measurement was performed. The copper block was heated from 20 ° C to 50 ° C, then placed on a 100mm thick insulation panel made of polystyrene and the temperature loss of the copper block was measured in 30 minutes. In this measurement, thermal energy cannot migrate through the front contact surface, since the insulation plate is heated to 50 ° C. Therefore, the heat loss through the other walls is calculated by determining a heating block loss temperature. The loss of the heating block measured at particular times is subtracted from the average of the temperature measurements as the samples cool, resulting in corrected mean temperature (corrected mean) readings of the four measurements on the two samples.

Samples 1A / 1B

The heat dissipation of a first sample 1A and a second sample 1B comprising a composite coating system with a layer thickness of 40 mm on the specimen surface was measured twice each. The composite coating system comprised a mixture of coating materials in the form of an industrial hard concrete coating (411 kg) and a mixture of mixed additives (30 kg), as well as other additives. The proportion of the additive mix was approximately 7% by mass of the coating material mix in the form of an industrial hard concrete coating. The mixture of coating materials and the mixture of mixed additives was a dry mixture which was mixed with mixing water and additives. The measured, averaged, and corrected mean values are listed in Table 1.

Table 1

Loss of temperature

min 1A P1 1AP2 1BP1 1BP2 Avg Block Loss Average Corrected Heat Dissipation Heat [K] [kJ] [K] [K] [K] [K] [K] [K]

1 0.3 1.1 1.8 2.0 1.30 0.05 1.25 3.75

2 0.6 1.3 2.1 2.5 1.63 0.10 1.52 4.57

5 1.1 1.8 2.7 3.6 2.30 0.26 2.04 6.13

1,5 2,1 3,1 4,1 2,70

0,36 2,34 7,02 (continuación)7

1.5 2.1 3.1 4.1 2.70

0.36 2.34 7.02 (continuation)

Loss of temperature

min 1A P1 1AP2 1BP1 1BP2 Avg Block Loss Average Corrected Heat Dissipation Heat [K] [kJ] [K] [K] [K] [K] [K] [K]

10 2.2 2.6 3.7 4.7 3.30 0.51 2.79 8.36

15 3.1 3.6 4.7 5.8 4.30 0.77 3.53 10.60

20 4.1 4.5 5.8 6.7 5.28 1.02 4.25 12.75

25 5.1 5.4 6.6 7.5 6.15 1.28 4.87 14.61

30 5.8 6.2 7.4 8.3 6.93 1.54 5.39 16.17

Samples 2A / 2B

The heat dissipation of a first sample 2A and a second sample 2B, in each of which a mixture of coating materials in the form of an industrial epoxy resin coating with an additive mixture spread with a total thickness of 3 mm, was arranged, it was determined in another series of tests. The additive mixture was dispersed in a 1: 1 ratio to the epoxy resin coating over the applied coating material mixture in the form of an industrial epoxy resin coating. Subsequently, a stamp was applied. The measured, averaged, and corrected mean values are listed in Table 2.

Table 2

Loss of temperature

min 2A P1 2A P2 2B P1 2B P2 Avg. Block Loss Average Corrected Heat Dissipation Heat [K] [kJ] [K] [K] [K] [K] [K] [K]

1 1.1 0.1 0.3 0.8 0.57 0.05 0.52 1.57

2 1.4 0.2 0.5 1.2 0.83 0.10 0.72 2.17

5 2.2 0.7 1.1 2.1 1.53 0.26 1.27 3.81

7 3.1 1.1 1.5 2.6 2.08 0.36 1.72 5.15

10 4.0 1.6 2.2 3.4 2.80 0.51 2.29 6.86

15 4.8 2.6 3.2 4.5 3.78 0.77 3.01 9.02

20 6.2 3.7 4.4 5.4 4.93 1.02 3.90 11.70

25 7.5 4.7 5.4 6.3 5.98 1.28 4.70 14.09

8,4 5,8 6,3 7,3 6,95

1,54 5,41 16,2430

8.4 5.8 6.3 7.3 6.95

1.54 5.41 16.24

Samples 3A / 3B

Samples 3A and 3B were prepared according to the embodiments under samples 2A / 2B with an epoxy resin coating by spreading the same amount of the additive mixture, whereby a seal was dispensed. The measured, averaged, and corrected mean values are listed in Table 3.

Table 3

Loss of temperature

min 3A P1 3A P2 3B P1 3B P2 Avg Block Loss Average Corrected Heat Dissipation Heat [K] [kJ] [K] [K] [K] [K] [K] [K]

1 0.2 0.3 0.4 0.3 0.30 0.05 0.25 0.75

2 0.4 0.6 0.6 0.5 0.53 0.10 0.42 1.27

5 0.9 1.1 1.1 1.0 1.03 0.26 0.77 2.31

7 1.2 1.5 1.4 1.3 1.35 0.36 0.99 2.97

10 1.7 2.2 2.0 1.8 1.93 0.51 1.41 4.24

15 2.6 3.2 3.0 2.6 2.85 0.77 2.08 6.25

20 3.6 4.2 3.9 3.7 3.85 1.02 2.83 8.48

25 4.5 5.2 4.9 4.7 4.83 1.28 3.55 10.64

5,4 6,1 6,0 5,6 5,78

1,54 4,24 12,7230

5.4 6.1 6.0 5.6 5.78

1.54 4.24 12.72

Test samples 4A / 4B

Test samples 4A and 4B are characterized by a composite coating system with an industrial PU coating as a mixture of coating materials, which was provided by spreading the mixture of additives. In this case, a mixture of additives and a PU coating were applied in a mass ratio of 1: 1 and a 3 mm thick composite coating system was created. Subsequently, this PU coating / additive mix composition was also provided with a seal. The measured, averaged and corrected mean values are listed in Table 4.

Table 4

Loss of temperature

min 4A P1 4A P2 4B P1 4B P2 Avg. Block Loss Average Corrected Heat Dissipation Heat [K] [kJ] [K] [K] [K] [K] [K] [K]

1 0.3 0.4 1.3 0.9 0.72 0.05 0.67 2.02

2 0.6 0.6 1.6 1.2 1.00 0.10 0.90 2.69

5 1.0 1.3 2.3 2.1 1.68 0.26 1.42 4.26

7 1.3 1.8 2.7 2.6 2.10 0.36 1.74 5.22

10 2.1 2.3 3.2 3.2 2.70 0.51 2.19 6.56

15 3.0 3.5 4.3 4.3 3.78 0.77 3.01 9.02

20 4.2 4.4 5.3 5.4 4.83 1.02 3.80 11.40

25 5.3 5.6 6.2 6.5 5.90 1.28 4.62 13.86

6,3 6,4 7,1 7,3 6,78

1,54 5,24 15,7230

6.3 6.4 7.1 7.3 6.78

1.54 5.24 15.72

By analyzing the heat dissipation values after 2 and 30 minutes, the analyzed samples or composite coating systems can be classified according to the SIA 252: 2002 standard for seamless industrial floors. Composite coating systems, which have a heat loss less than or equal to 3.6 kJ after two minutes and a heat loss less than or equal to 12.6 kJ after thirty minutes, are classified as good heat resistant coatings . Composite coating systems, which have a heat loss of less than or equal to 4.5 kJ after two minutes and a heat loss of less than or equal to 22.0 kJ after thirty minutes, are classified as heat resistant coatings. The vertices of the classification are marked in Figure 1 by the corresponding points after two minutes and 30 minutes of cooling time.

Therefore, measurements on samples 2A / 2B, 3A / 3B and 4A / 4B should be classified as heat resistant composite coating systems.

Figure 2

As an example, a measurement curve of the heat dissipation in sample 3A is shown in Figure 2, where the raw data measured from the cooling of the copper block and the heat output calculated from it to the Composite coating system is plotted against time. The comparative measurement of the heat emission from the copper block to the environment has not been taken into account here.

The composite coating system comprising an epoxy resin coating as a mixture of coating materials and an equal amount of a mixture of additives in a suitable composition achieves less heat output than comparative measurements in concrete, stoneware coating systems and linoleum with a thickness of 3.5 mm. The classification values are inserted as points in Figure 2, making it easier to see. The two lowest marks for excellent heat resistant coating systems, less than or equal to 2.5 kJ after two minutes and at the same time 9.2 kJ after thirty minutes, are only achieved with much thicker coating systems such as cork linoleum, small 10mm thick parquet, as well as cork parquet and tight matting, so these insulation layers are not part of a seamless applicable coating system.

Claims (10)

1. Mixture of additives to add to a mixture of coating materials to form a composite coating system for the floor, wall or facade sector, wherein the additive mixture comprises between 50% by weight and 95% by weight of muscovite mica and the additive mixture is in the form of powder or granules, characterized because the proportion of muscovite mica in the additive mixture is composed of muscovite mica with at least two different particle sizes a first part of particles with a fine particle size greater than 150 | jm and less than 300 | jm, and a second part with an average particle size greater than 400 jm and less than or equal to 800 jm or a first part of particles with a fine particle size greater than 150 jm and less than 300 jm, a second part of particles with an average particle size greater than 400 jm and less than 800 jm, and a third of particles with a particle size thickness with average particle diameter greater than or equal to 800 | jm or a second part of an average grain size greater than 400 jm and less than 800 jm, and a third part of a coarse-grained size with average particle diameters greater than or equal to 800 jm. 2. Additive mixture according to claim 1, in which the proportion of muscovite mica in the additive mixture additionally has a third part with particles having a coarse grain size with average particle diameters greater than or equal to 800 jm. 3. Additive mixture (2) according to any of the preceding claims, wherein the additive mixture (2) further comprises additives, in the form of flow optimizers, anti-segregation stabilizers, fire protection components, coating stabilizers and / or white pigments. 4. Additive mixture (2) according to any of the preceding claims, wherein the additive mixture (2) additionally has additives, in the form of binders, for example, Portland cement and / or fillers and binders, for example , calcium carbonate. 5. Composite coating system for the floor, wall or façade sector, formed from a mixture of fluid or applicable coating materials with a spatula, characterized in that an additive mixture according to one of the preceding claims, comprising at least a proportion of muscovite mica, is added to the mixture of coating materials or spread in the mixture of coating materials, so that in composite coating systems Resulting comprising the mixture of coating materials and the mixture of additives, a mass proportion of between 6% by weight and 50% by weight of muscovite mica with at least two different grain sizes is obtained. 6. Composite coating system according to claim 5, wherein, as a mixture of coating materials, a mineral coating mixture is selected, such as a mixture of hard concrete, synthetic resin and cement, contact injection, xylolite , magnesia or anhydrite, to which is added so much mixture of additives that a mass ratio of muscovite mica of between 6% by weight and 20% by weight of the resulting composite coating system is reached. 7. Composite coating system according to claim 5, wherein a mixture of hard concrete coating is selected as the coating material mixture, to which is added so much mixture of additives that a mass proportion of muscovite mica less than or equal to 10% by weight of the resulting composite coating system is reached. 8. A composite coating system according to claim 5, wherein a coating mixture comprising synthetic resin or plastics is selected as the coating material mixture, to which so much additive mixture is added that a mass ratio of Muscovite mica between 12% by weight and 50% by weight of the resulting composite coating system. 9. A composite coating system according to claim 5, wherein a PU coating mixture or an epoxy coating mixture is selected as the coating material mixture, to which such an amount of additive mixture is added that a mass proportion of muscovite mica of between 40% by weight and 50% by weight of the resulting composite coating system. 10. Method for manufacturing a composite cladding system for the floor, wall or facade sector, comprising a mixture of cladding materials and a mixture of additives according to one of claims 1 to 4, characterized in that - the mixture of coating materials is mixed with the mixture of additives or - the additive mixture is spread in the mixture of coating materials after the application, spreading and / or spatulating of the mixture of coating materials, wherein the additive mixture comprises at least 50% by weight of muscovite mica, so that the resulting composite coating system has between 6% and 50% by weight of muscovite mica.