ES2742679T3 - Adiciones de nanopartículas de polímero para la modificación de resina - Google Patents
Adiciones de nanopartículas de polímero para la modificación de resina Download PDFInfo
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- ES2742679T3 ES2742679T3 ES15186490T ES15186490T ES2742679T3 ES 2742679 T3 ES2742679 T3 ES 2742679T3 ES 15186490 T ES15186490 T ES 15186490T ES 15186490 T ES15186490 T ES 15186490T ES 2742679 T3 ES2742679 T3 ES 2742679T3
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- resin
- polymer nanoparticles
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- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
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- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 description 1
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- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
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- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/005—Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
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- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L79/02—Polyamines
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/06—Polysulfones; Polyethersulfones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/22—Thermoplastic resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/24—Thermosetting resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2400/00—Characterised by the use of unspecified polymers
- C08J2400/22—Thermoplastic resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2400/00—Characterised by the use of unspecified polymers
- C08J2400/24—Thermosetting resins
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Nanotechnology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Reinforced Plastic Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/493,365 US9862828B2 (en) | 2014-09-23 | 2014-09-23 | Polymer nanoparticle additions for resin modification |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2742679T3 true ES2742679T3 (es) | 2020-02-17 |
Family
ID=54325306
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES15186490T Active ES2742679T3 (es) | 2014-09-23 | 2015-09-23 | Adiciones de nanopartículas de polímero para la modificación de resina |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US9862828B2 (https=) |
| EP (1) | EP3000841B1 (https=) |
| JP (2) | JP7182845B2 (https=) |
| ES (1) | ES2742679T3 (https=) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10072126B2 (en) * | 2014-09-23 | 2018-09-11 | The Boeing Company | Soluble nanoparticles for composite performance enhancement |
| US9587076B2 (en) * | 2014-09-23 | 2017-03-07 | The Boeing Company | Polymer nanoparticles for controlling resin reaction rates |
| EP3051273A1 (en) * | 2015-02-02 | 2016-08-03 | Nokia Technologies OY | A mechanical deformation sensor based on plasmonic nanoparticles |
| US11283186B2 (en) * | 2016-03-25 | 2022-03-22 | Commscope Technologies Llc | Antennas having lenses formed of lightweight dielectric materials and related dielectric materials |
| US11431100B2 (en) | 2016-03-25 | 2022-08-30 | Commscope Technologies Llc | Antennas having lenses formed of lightweight dielectric materials and related dielectric materials |
| RU2656045C2 (ru) * | 2016-11-23 | 2018-05-30 | Федеральное государственное унитарное предприятие "Институт химических реактивов и особо чистых химических веществ Национального исследовательского центра "Курчатовский институт" | Способ получения полиимидного композитного материала, армированного наноструктурированным карбидом бора (варианты) |
| RU2673292C1 (ru) * | 2017-08-02 | 2018-11-23 | Общество с ограниченной ответственностью "ПолиКомпозиты" | Способ получения полиимидного композиционного материала, наполненного наноструктурированным карбидом кремния с модифицированной поверхностью |
| WO2019055134A1 (en) | 2017-09-15 | 2019-03-21 | Commscope Technologies Llc | METHODS FOR PREPARING COMPOSITE DIELECTRIC MATERIAL |
| RU2701249C1 (ru) * | 2019-04-02 | 2019-09-25 | Федеральное государственное унитарное предприятие "Центральный институт авиационного моторостроения имени П.И. Баранова" | Способ диспергирования трудновоспламеняемых наночастиц бора |
| KR20260012727A (ko) * | 2023-05-04 | 2026-01-27 | 인팩 테크놀로지스 - 리미티드 파트너십 | 제어된 열팽창 계수를 갖는 비전도성 폴리머 층을 형성하는 방법 |
| CN116704893B (zh) * | 2023-06-01 | 2025-11-14 | 武汉天马微电子有限公司 | 显示装置以及制备方法 |
Family Cites Families (61)
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|---|---|---|---|---|
| GB1358276A (en) | 1972-06-27 | 1974-07-03 | British Railways Board | Composites of carbon fibres and synthetic plastics materials |
| US3860565A (en) | 1973-10-01 | 1975-01-14 | Minnesota Mining & Mfg | Encapsulated isocyanurate catalyst |
| US4306040A (en) | 1980-11-03 | 1981-12-15 | Monsanto Company | Multiphase core//shell polymers |
| US4701475A (en) | 1986-06-25 | 1987-10-20 | The Dow Chemical Company | Polyurethanes reinforced with rigid rod micro fillers |
| ES2051274T3 (es) | 1986-12-25 | 1994-06-16 | Toray Industries | Materiales compuestos altamente resistentes. |
| EP0378854A1 (en) | 1989-01-19 | 1990-07-25 | General Electric Company | Expanded fiber composite structure and process for making said structure |
| EP0392348A3 (en) | 1989-04-14 | 1991-12-27 | Cytec Technology Corp. | Toughened thermosetting structural materials |
| US5618857A (en) | 1993-06-24 | 1997-04-08 | Loctite Corporation | Impregnation sealant composition of superior high temperature resistance, and method of making same |
| TW305860B (https=) | 1994-03-15 | 1997-05-21 | Toray Industries | |
| US6096669A (en) | 1997-10-28 | 2000-08-01 | Gkn Westland Aerospace Inc. | Unidirectional fiber-random mat preform |
| AU2876599A (en) | 1998-03-03 | 1999-09-20 | Ppg Industries Ohio, Inc. | Inorganic particle-coated glass fiber strands and products including the same |
| JP4204716B2 (ja) | 1999-10-15 | 2009-01-07 | 株式会社クラレ | 自立性多孔性繊維集積体およびその製造方法 |
| US7037865B1 (en) | 2000-08-08 | 2006-05-02 | Moldite, Inc. | Composite materials |
| US6503856B1 (en) | 2000-12-05 | 2003-01-07 | Hexcel Corporation | Carbon fiber sheet materials and methods of making and using the same |
| US6740185B2 (en) | 2001-02-06 | 2004-05-25 | General Electric Company | Method of preparing preforms for RTM molding processes |
| US6518330B2 (en) | 2001-02-13 | 2003-02-11 | Board Of Trustees Of University Of Illinois | Multifunctional autonomically healing composite material |
| US6531340B2 (en) | 2001-02-23 | 2003-03-11 | Micron Technology, Inc. | Low temperature die attaching material for BOC packages |
| JP4004470B2 (ja) | 2001-11-02 | 2007-11-07 | 三洋化成工業株式会社 | 複合樹脂粒子 |
| GB0203823D0 (en) | 2002-02-19 | 2002-04-03 | Hexcel Composites Ltd | Moulding materials |
| WO2003070817A1 (en) | 2002-02-19 | 2003-08-28 | Photon-X, Inc. | Athermal polymer nanocomposites |
| GB0205498D0 (en) | 2002-03-08 | 2002-04-24 | Structural Polymer Systems Ltd | Moulding material |
| JPWO2004110930A1 (ja) | 2003-06-12 | 2006-07-20 | 松下電器産業株式会社 | ナノ粒子含有複合多孔体およびその製造方法 |
| US7041740B2 (en) | 2003-09-26 | 2006-05-09 | Hexcel Corporation | Heat-settable resins |
| US7212284B2 (en) | 2004-05-12 | 2007-05-01 | General Electric Company | Method for forming nanoparticle films and application thereof |
| US8399094B2 (en) | 2004-09-01 | 2013-03-19 | Ppg Industries Ohio, Inc. | Multilayer laminated articles including polyurethane and/or poly(ureaurethane) layers and methods of making the same |
| US7435693B2 (en) | 2005-01-07 | 2008-10-14 | The Boeing Company | Toughened, non-crimped unidirectional fabric apparatus and method of making same |
| US7356231B2 (en) | 2005-02-28 | 2008-04-08 | 3M Innovative Properties Company | Composite polymer fibers |
| CN103012820B (zh) | 2005-05-09 | 2016-06-08 | Cytec技术有限公司 | 用于复合材料的树脂可溶的热塑性遮盖物 |
| US7655295B2 (en) | 2005-06-14 | 2010-02-02 | Siemens Energy, Inc. | Mix of grafted and non-grafted particles in a resin |
| WO2007018736A2 (en) | 2005-07-22 | 2007-02-15 | Appleton Papers Inc. | Encapsulated structural adhesive |
| KR101167733B1 (ko) | 2005-11-16 | 2012-07-23 | 삼성전기주식회사 | 캡핑 리간드가 표면에 결합되어 있는 나노입자용 분산제, 이를 이용한 나노입자의 분산방법 및 이를 포함하는 나노입자 박막 |
| JP5243965B2 (ja) | 2005-12-15 | 2013-07-24 | ハンツマン アドバンスト マテリアルズ （スイッツァランド） ゲーエムベーハー | 多相アクリル系接着剤 |
| US20080176987A1 (en) | 2007-01-22 | 2008-07-24 | Trevet Fred W | System and methods for modified resin and composite material |
| US20090004460A1 (en) | 2007-06-28 | 2009-01-01 | U.S.A. As Represented By The Administrator Of The National Aeronautics And Space Administration | Nanoparticle-Containing Thermoplastic Composites and Methods of Preparing Same |
| GB0717507D0 (en) | 2007-09-07 | 2007-10-17 | Cytec Tech Corp | Composite materials and their use |
| US20090130376A1 (en) | 2007-11-20 | 2009-05-21 | The Boeing Company | Unidirectional fiber material and fabrication method |
| US20110097568A1 (en) * | 2008-03-25 | 2011-04-28 | Toray Industries, Inc | Epoxy resin composition, fiber-reinforced composite material, and method for producing the same |
| US8288453B2 (en) | 2008-06-26 | 2012-10-16 | Ccp Composites Us | Process to disperse organic microparticles/nanoparticles into non-aqueous resin medium |
| JP5243181B2 (ja) | 2008-10-20 | 2013-07-24 | スリーエム イノベイティブ プロパティズ カンパニー | 導電性高分子複合体及び導電性高分子材料を用いた熱電素子 |
| JP5228853B2 (ja) * | 2008-12-01 | 2013-07-03 | 東レ株式会社 | エポキシ樹脂組成物、繊維強化複合材料およびそれらの製造方法 |
| US20100249277A1 (en) | 2009-03-31 | 2010-09-30 | General Electric Company | Cured composite composition |
| US20100273382A1 (en) | 2009-04-28 | 2010-10-28 | Malay Nandi | Acoustic and fire retardant foam coating composition for fibrous mat |
| EP2253677B1 (en) | 2009-05-19 | 2017-01-25 | Rohm and Haas Company | Opacifying pigment particle |
| US8080313B2 (en) * | 2009-05-28 | 2011-12-20 | Cytec Technology Corp. | Particle-toughened fiber-reinforced polymer composites |
| US20110021360A1 (en) | 2009-07-22 | 2011-01-27 | Al-Ghamdi Ahmed Abdullah S | Superconductive nanocomposite |
| CN101623266B (zh) | 2009-07-24 | 2012-08-08 | 中国科学院上海硅酸盐研究所 | 磷酸钙/嵌段共聚物复合多孔纳米球及其制备方法 |
| KR20120036890A (ko) | 2009-08-03 | 2012-04-18 | 어플라이드 나노스트럭처드 솔루션스, 엘엘씨. | 복합재 섬유에 나노입자의 결합 |
| CN102858181B (zh) | 2009-12-17 | 2016-04-20 | 马雷尔肉类加工有限公司 | 用于加工已被屠宰的动物和/或其一部分的系统和方法 |
| JP5293629B2 (ja) * | 2010-02-02 | 2013-09-18 | 東レ株式会社 | トウプリプレグ用エポキシ樹脂組成物およびトウプリプレグ |
| WO2011141826A1 (en) | 2010-05-12 | 2011-11-17 | Schlumberger Canada Limited | Method for analysis of the chemical composition of the heavy fraction petroleum |
| CN103109330B (zh) | 2010-09-17 | 2016-03-09 | 3M创新有限公司 | 纤维强化的加载纳米粒子的热固性聚合物复合线材、线缆以及方法 |
| KR20140094549A (ko) | 2011-10-24 | 2014-07-30 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 나노실리카 함유 비스말레이미드 조성물 |
| KR101326523B1 (ko) | 2012-02-23 | 2013-11-07 | 현대자동차주식회사 | 탄소나노튜브가 코팅된 상전이 물질을 함유하는 마이크로 캡슐과 탄소섬유를 함유한 전자파차폐용 고분자 복합재 및 그 제조방법 |
| KR102111816B1 (ko) | 2012-08-03 | 2020-05-15 | 오씨브이 인텔렉츄얼 캐피탈 엘엘씨 | 개선된 파이버글라스 보강 복합재 |
| KR20140037646A (ko) | 2012-09-19 | 2014-03-27 | 삼성전기주식회사 | 절연용 에폭시 수지 조성물, 절연 필름, 프리프레그 및 인쇄회로기판 |
| US9593238B2 (en) * | 2012-09-28 | 2017-03-14 | Toray Industries, Inc. | Prepreg and carbon fiber reinforced composite material |
| CN202878879U (zh) | 2012-11-05 | 2013-04-17 | 海南亚元防伪技术研究所 | 大尺寸纤维印刷系统 |
| US9611396B2 (en) | 2012-11-09 | 2017-04-04 | AnCatt | Conducting polymer nanoparticle composites |
| NL2009777C2 (en) | 2012-11-09 | 2014-05-12 | Ut Internat Ventures Holding B V | Polymer foam comprising a polymer and nanoparticles, and nanoparticles for the manufacture of such foam. |
| KR102256525B1 (ko) | 2013-11-27 | 2021-05-26 | 도레이 카부시키가이샤 | 반도체용 수지 조성물 및 반도체용 수지 필름, 및 이들을 사용한 반도체 장치 |
| ES2811753T3 (es) | 2013-12-24 | 2021-03-15 | Hexcel Composites Ltd | Mejoras para aditivos de matrices |
-
2014
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Also Published As
| Publication number | Publication date |
|---|---|
| JP7182845B2 (ja) | 2022-12-05 |
| US20160083583A1 (en) | 2016-03-24 |
| JP2020158774A (ja) | 2020-10-01 |
| EP3000841B1 (en) | 2019-05-22 |
| US9862828B2 (en) | 2018-01-09 |
| JP2016065214A (ja) | 2016-04-28 |
| EP3000841A1 (en) | 2016-03-30 |
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