ES2657499T3 - Inhibidor del chamuscado de espuma de poliuretano - Google Patents

Inhibidor del chamuscado de espuma de poliuretano Download PDF

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Publication number
ES2657499T3
ES2657499T3 ES10848119.3T ES10848119T ES2657499T3 ES 2657499 T3 ES2657499 T3 ES 2657499T3 ES 10848119 T ES10848119 T ES 10848119T ES 2657499 T3 ES2657499 T3 ES 2657499T3
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Spain
Prior art keywords
butyl
tert
hydroxyphenyl
propionate
weight
Prior art date
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Active
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ES10848119.3T
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English (en)
Inventor
John M. Demassa
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Vanderbilt Chemicals LLC
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Vanderbilt Chemicals LLC
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0023Use of organic additives containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/13Phenols; Phenolates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/14Manufacture of cellular products
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805Compounds having only one group containing active hydrogen
    • C08G18/2815Monohydroxy compounds
    • C08G18/282Alkanols, cycloalkanols or arylalkanols including terpenealcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005Stabilisers against oxidation, heat, light, ozone
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/17Amines; Quaternary ammonium compounds
    • C08K5/18Amines; Quaternary ammonium compounds with aromatically bound amino groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/45Heterocyclic compounds having sulfur in the ring
    • C08K5/46Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00Manufacture of cellular products
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0008Foam properties flexible
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0083Foam properties prepared using water as the sole blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Emergency Medicine (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Una composición líquida inhibidora del chamuscado para espumas de poliuretano, que comprende: (a) uno o más compuestos fenólicos derivatizados en una cantidad de 60-80% en peso; (b) una o más aminas aromáticas en forma de un líquido en una cantidad de 15-35% en peso; (c) una hidroquinona sustituida con alquilo en una cantidad de 4-8% en peso, y (d) fenotiazina de 0 a 1% en peso, en donde el compuesto fenólico derivatizado se selecciona del grupo que consiste en tetrakis[metileno(3,5-di-terc.- butil-4-hidroxihidrocinamato)]metano; propionato de iso-octil-3-(3,5-di-terc.-butil-4-hidroxifenilo); propionato de isotridecil-3-(3,5-di-terc.-butil-4-hidroxifenilo); propionato de octadecil-3-(3,5-di-terc.-butil-4-hidroxifenilo); 2,6 di-terc.- butil-4-nonilfenol; 1,2-bis(3,5-di-terc.-butil-4-hidroxihidrocinnamoil) hidrazina; bis[3-(3,5-di-t-butil-4- hidroxifenil)propionato de 2,2'-tiodietileno; un (2,6-di-terc.-butil)fenol sustituido en la posición 4 con un resto alifático, aromático o alifático-aromático, que opcionalmente posee combinaciones de heteroátomos tales como O, N, S y P; y mezclas de los mismos.

Description

imagen1
imagen2
imagen3
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Claims (1)

  1. imagen1
ES10848119.3T 2010-03-18 2010-09-23 Inhibidor del chamuscado de espuma de poliuretano Active ES2657499T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US726950 2003-12-03
US12/726,950 US8716359B2 (en) 2010-03-18 2010-03-18 Polyurethane foam scorch inhibitor
PCT/US2010/049975 WO2011115642A1 (en) 2010-03-18 2010-09-23 Polyurethane foam scorch inhibitor

Publications (1)

Publication Number Publication Date
ES2657499T3 true ES2657499T3 (es) 2018-03-05

Family

ID=44647726

Family Applications (1)

Application Number Title Priority Date Filing Date
ES10848119.3T Active ES2657499T3 (es) 2010-03-18 2010-09-23 Inhibidor del chamuscado de espuma de poliuretano

Country Status (21)

Country Link
US (1) US8716359B2 (es)
EP (1) EP2547725B1 (es)
JP (1) JP5550779B2 (es)
CN (2) CN107090068A (es)
AR (1) AR078853A1 (es)
AU (1) AU2010348331B2 (es)
BR (1) BR112012023548A2 (es)
CA (1) CA2792850C (es)
DK (1) DK2547725T3 (es)
ES (1) ES2657499T3 (es)
HR (1) HRP20180145T1 (es)
HU (1) HUE036236T2 (es)
LT (1) LT2547725T (es)
MX (1) MX343083B (es)
MY (1) MY162355A (es)
NO (1) NO2547725T3 (es)
PL (1) PL2547725T3 (es)
RU (1) RU2535853C2 (es)
SA (1) SA111320216B1 (es)
TW (1) TWI472573B (es)
WO (1) WO2011115642A1 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2523756B (en) 2014-03-03 2017-01-11 Addivant Switzerland Gmbh Antioxidant compositions
US9481775B2 (en) * 2014-04-28 2016-11-01 Vanderbilt Chemicals, Llc Polyurethane scorch inhibitor
GB2549061B (en) 2015-09-03 2020-04-01 Si Group Switzerland Chaa Gmbh Stabilising Compositions
BR112019006636A2 (pt) * 2016-09-30 2019-07-02 Vanderbilt Chemicals Llc inibidor de pré-vulcanização de baixa emissão para espuma de poliuretano
US11166976B2 (en) 2018-11-08 2021-11-09 Aligos Therapeutics, Inc. S-antigen transport inhibiting oligonucleotide polymers and methods
GB2579405B (en) 2018-11-30 2022-09-14 Si Group Switzerland Chaa Gmbh Antioxidant compositions
GB2590910A (en) 2019-12-24 2021-07-14 Si Group Switzerland Chaa Gmbh Composition

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4010211A (en) * 1975-05-12 1977-03-01 Olin Corporation Stabilization of polyether polyols
UST968002I4 (en) * 1977-02-24 1978-03-07 Polyurethane foam stabilized against scorch with a mixture of hydroquinone and a phosphite containing secondary antioxidant
US4275173A (en) * 1980-04-21 1981-06-23 The Dow Chemical Company Stabilization of polyether polyols and polyurethane foams prepared therefrom
US4363745A (en) * 1980-04-21 1982-12-14 The Dow Chemical Company Antioxidant compositions
US4444676A (en) * 1983-04-01 1984-04-24 Atlantic Richfield Company Stabilized polyoxyalkylene polyether polyols and polyurethane foams prepared therefrom
JPS61130320A (ja) * 1984-11-29 1986-06-18 Daihachi Kagaku Kogyosho:Kk 難燃性ポリウレタンフオ−ム組成物
US4933374A (en) * 1989-05-24 1990-06-12 R. T. Vanderbilt Company, Inc. Stabilizer compositions for polyols and polyurethane foam
ES2091236T3 (es) * 1989-11-08 1996-11-01 Ciba Geigy Ag Composiciones de lubricantes.
US5143943A (en) * 1992-02-18 1992-09-01 R. T. Vanderbilt Company, Inc. Synergistic stabilizer compositions for polyols and polyurethane foam
US5219892A (en) * 1992-06-16 1993-06-15 R. T. Vanderbilt Company, Inc. Liquid stabilizer compositions for polyols and polyurethane foam
CH686306A5 (de) * 1993-09-17 1996-02-29 Ciba Geigy Ag 3-Aryl-benzofuranone als Stabilisatoren.
US5571453A (en) * 1994-10-25 1996-11-05 Uniroyal Chemical Company, Inc. Stabilized polyether polyol and polyurethane foam obtained therefrom
TW593303B (en) * 2001-09-11 2004-06-21 Ciba Sc Holding Ag Stabilization of synthetic polymers
US20030078311A1 (en) * 2001-10-19 2003-04-24 Ulrich Muller Process for the alkoxylation of organic compounds in the presence of novel framework materials
SI1483317T1 (sl) * 2002-03-13 2012-04-30 Vanderbilt Co R T Sestavek za zmanjšanje porumenelosti in inhibicijo zamreženja

Also Published As

Publication number Publication date
RU2013108250A (ru) 2014-09-10
HRP20180145T1 (hr) 2018-05-18
HUE036236T2 (hu) 2018-06-28
MX2012010778A (es) 2013-03-05
MY162355A (en) 2017-06-15
RU2535853C2 (ru) 2014-12-20
LT2547725T (lt) 2018-02-26
SA111320216B1 (ar) 2014-11-16
AU2010348331B2 (en) 2014-12-04
CA2792850C (en) 2017-03-14
CA2792850A1 (en) 2011-09-22
JP5550779B2 (ja) 2014-07-16
US8716359B2 (en) 2014-05-06
JP2013522415A (ja) 2013-06-13
EP2547725A1 (en) 2013-01-23
DK2547725T3 (da) 2018-01-29
WO2011115642A1 (en) 2011-09-22
EP2547725A4 (en) 2014-12-31
CN102834446A (zh) 2012-12-19
PL2547725T3 (pl) 2018-03-30
TW201132698A (en) 2011-10-01
EP2547725B1 (en) 2017-10-25
CN107090068A (zh) 2017-08-25
BR112012023548A2 (pt) 2018-05-15
US20110230579A1 (en) 2011-09-22
TWI472573B (zh) 2015-02-11
MX343083B (es) 2016-10-24
NO2547725T3 (es) 2018-03-24
AR078853A1 (es) 2011-12-07
AU2010348331A1 (en) 2013-07-25

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