ES2643558A2 - Proceso para producir hidrógeno líquido - Google Patents
Proceso para producir hidrógeno líquido Download PDFInfo
- Publication number
- ES2643558A2 ES2643558A2 ES201790014A ES201790014A ES2643558A2 ES 2643558 A2 ES2643558 A2 ES 2643558A2 ES 201790014 A ES201790014 A ES 201790014A ES 201790014 A ES201790014 A ES 201790014A ES 2643558 A2 ES2643558 A2 ES 2643558A2
- Authority
- ES
- Spain
- Prior art keywords
- hydrogen
- gaseous hydrogen
- generated
- metal
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000001257 hydrogen Substances 0.000 title abstract 8
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract 7
- 238000000034 method Methods 0.000 title abstract 5
- 239000007788 liquid Substances 0.000 title abstract 2
- 239000002184 metal Substances 0.000 abstract 5
- 229910052751 metal Inorganic materials 0.000 abstract 5
- 239000002253 acid Substances 0.000 abstract 3
- 230000005611 electricity Effects 0.000 abstract 2
- 238000005868 electrolysis reaction Methods 0.000 abstract 2
- 230000008929 regeneration Effects 0.000 abstract 2
- 238000011069 regeneration method Methods 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 150000007513 acids Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 238000003860 storage Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/22—Inorganic acids
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/50—Processes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B5/00—Electrogenerative processes, i.e. processes for producing compounds in which electricity is generated simultaneously
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0005—Light or noble gases
- F25J1/001—Hydrogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
- F25J1/0281—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc. characterised by the type of prime driver, e.g. hot gas expander
- F25J1/0284—Electrical motor as the prime mechanical driver
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2260/00—Coupling of processes or apparatus to other units; Integrated schemes
- F25J2260/30—Integration in an installation using renewable energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
La invención se refiere a un proceso integrado para la producción continua de hidrógeno líquido, que comprende (a) producir hidrógeno gaseoso por electrólisis; y (b) licuar dicho hidrógeno gaseoso en una unidad de licuefacción de hidrógeno, cuya unidad de licuefacción es alimentada por energía que proviene de manera esencial de fuentes renovables; y (c) cuando se necesita energía adicional, usar energía eléctrica generada en un proceso en el que se cogeneran energía eléctrica e hidrógeno por medio de un proceso integrado de electrólisis que comprende: (d) electrolizar una sal de metal o mezcla de sales de metal y agua en el correspondiente metal o metales, ácido o ácidos y oxígeno (fase de almacenamiento de electricidad) y (e) producir hidrógeno gaseoso y recuperar electricidad en una reacción de regeneración de los metal(es) y ácido(s) de la etapa (d) (fase de regeneración); en donde al menos parte del hidrógeno gaseoso generado en la etapa (e) se usa en la etapa (b) del proceso.
Description
Claims (1)
-
imagen1 imagen2
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14190677 | 2014-10-28 | ||
EP14190677 | 2014-10-28 | ||
PCT/EP2015/074712 WO2016066571A1 (en) | 2014-10-28 | 2015-10-26 | Process for producing liquid hydrogen |
Publications (3)
Publication Number | Publication Date |
---|---|
ES2643558A2 true ES2643558A2 (es) | 2017-11-23 |
ES2643558R1 ES2643558R1 (es) | 2017-12-13 |
ES2643558B1 ES2643558B1 (es) | 2018-09-19 |
Family
ID=51795564
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES201790014A Expired - Fee Related ES2643558B1 (es) | 2014-10-28 | 2015-10-26 | Proceso para producir hidrógeno líquido |
Country Status (7)
Country | Link |
---|---|
US (1) | US20170321332A1 (es) |
CN (1) | CN107074538A (es) |
AU (1) | AU2015340752B2 (es) |
BR (1) | BR112017007390A2 (es) |
CL (1) | CL2017000975A1 (es) |
ES (1) | ES2643558B1 (es) |
WO (1) | WO2016066571A1 (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SI25573A (sl) * | 2017-12-13 | 2019-06-28 | Univerza V Novi Gorici | Postopek za shranjevanje električne energije v trdni snovi |
WO2019190305A1 (en) * | 2018-03-27 | 2019-10-03 | Harit Ecotech Sdn. Bhd. | A hydroxygen generator for reducing carbon emission and increasing fuel efficieny |
FR3098576B1 (fr) | 2019-07-08 | 2022-04-29 | Air Liquide | Procédé et installation de production d’hydrogène liquide |
EP4067533A1 (de) * | 2021-03-30 | 2022-10-05 | Linde GmbH | Verfahren und anlage zur elektrolytischen herstellung von flüssigwasserstoff |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3036805A1 (de) * | 1980-09-30 | 1982-05-06 | Karlheinz 7321 Zell Hanzlik | Verfahren zur herstellung und speicherung von treibstoff |
US4910963A (en) * | 1988-11-21 | 1990-03-27 | Vanzo Gordon F | Solar energy process |
CN1352323A (zh) * | 2000-11-03 | 2002-06-05 | 穆瑞力 | 利用太阳能和(或)风能产生氢气方法和装置 |
CN1854063A (zh) * | 2005-04-28 | 2006-11-01 | 黄潮 | 电化学锌-水制氢、储氢方法 |
US20080127646A1 (en) * | 2005-10-11 | 2008-06-05 | Doland George J | System and Method for Energy and Hydrogen Production |
EP2132820A4 (en) * | 2007-04-03 | 2014-12-24 | New Sky Energy Inc | ELECTROCHEMICAL SYSTEM, APPARATUS AND METHOD FOR GENERATING RENEWABLE HYDROGEN AND SEQUESTERING CARBON DIOXIDE |
CN101492825A (zh) * | 2009-01-05 | 2009-07-29 | 陈有孝 | 一种利用太阳能制取氢气的工艺技术 |
FR2948654B1 (fr) * | 2009-07-30 | 2015-01-16 | Gerkaro | Cogeneration d'energie electrique et d'hydrogene |
CN101892491A (zh) * | 2010-07-28 | 2010-11-24 | 张建洲 | 一种自然能源发电及电解海水或苦咸水的综合应用系统 |
CN102453922A (zh) * | 2010-11-03 | 2012-05-16 | 尹华文 | 太阳能制氢系统工程 |
EP2697855A1 (en) * | 2011-04-11 | 2014-02-19 | Antecy B.V. | Self-contained solar-powered energy supply and storage system |
EP2751307B1 (de) * | 2011-08-29 | 2015-09-09 | Karl-Hermann Busse | Energieversorgungsanlage, insbesondere für den bereich der haustechnik |
AU2014100315A4 (en) * | 2014-04-01 | 2014-05-01 | Cooper, Bretton MR | Liquid air facilitating renewable hydrogen exports |
-
2015
- 2015-10-26 WO PCT/EP2015/074712 patent/WO2016066571A1/en active Application Filing
- 2015-10-26 US US15/522,308 patent/US20170321332A1/en not_active Abandoned
- 2015-10-26 AU AU2015340752A patent/AU2015340752B2/en not_active Ceased
- 2015-10-26 ES ES201790014A patent/ES2643558B1/es not_active Expired - Fee Related
- 2015-10-26 BR BR112017007390A patent/BR112017007390A2/pt active Search and Examination
- 2015-10-26 CN CN201580058397.2A patent/CN107074538A/zh active Pending
-
2017
- 2017-04-20 CL CL2017000975A patent/CL2017000975A1/es unknown
Also Published As
Publication number | Publication date |
---|---|
AU2015340752B2 (en) | 2018-02-01 |
CL2017000975A1 (es) | 2018-01-12 |
CN107074538A (zh) | 2017-08-18 |
ES2643558R1 (es) | 2017-12-13 |
WO2016066571A1 (en) | 2016-05-06 |
BR112017007390A2 (pt) | 2018-02-14 |
ES2643558B1 (es) | 2018-09-19 |
AU2015340752A1 (en) | 2017-04-20 |
US20170321332A1 (en) | 2017-11-09 |
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Legal Events
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