ES261335A1 - Un procedimiento para preparar polibutadieno - Google Patents
Un procedimiento para preparar polibutadienoInfo
- Publication number
- ES261335A1 ES261335A1 ES0261335A ES261335A ES261335A1 ES 261335 A1 ES261335 A1 ES 261335A1 ES 0261335 A ES0261335 A ES 0261335A ES 261335 A ES261335 A ES 261335A ES 261335 A1 ES261335 A1 ES 261335A1
- Authority
- ES
- Spain
- Prior art keywords
- compound
- aluminium
- catalyst
- butene
- tri
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000005062 Polybutadiene Substances 0.000 title abstract 3
- 229920002857 polybutadiene Polymers 0.000 title abstract 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 6
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 229910017052 cobalt Inorganic materials 0.000 abstract 3
- 239000010941 cobalt Substances 0.000 abstract 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 3
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 abstract 2
- 230000002378 acidificating effect Effects 0.000 abstract 2
- 239000004411 aluminium Substances 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 abstract 2
- -1 diethyl hydride Chemical class 0.000 abstract 2
- 229910001507 metal halide Inorganic materials 0.000 abstract 2
- 150000005309 metal halides Chemical class 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 150000002899 organoaluminium compounds Chemical class 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 abstract 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001242 acetic acid derivatives Chemical class 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- PQLAYKMGZDUDLQ-UHFFFAOYSA-K aluminium bromide Substances Br[Al](Br)Br PQLAYKMGZDUDLQ-UHFFFAOYSA-K 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 abstract 1
- 150000004648 butanoic acid derivatives Chemical class 0.000 abstract 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001805 chlorine compounds Chemical class 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 125000004836 hexamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 abstract 1
- 229910052738 indium Inorganic materials 0.000 abstract 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000005609 naphthenate group Chemical group 0.000 abstract 1
- 150000002816 nickel compounds Chemical class 0.000 abstract 1
- 150000002823 nitrates Chemical class 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 abstract 1
- 125000005474 octanoate group Chemical class 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 150000003891 oxalate salts Chemical class 0.000 abstract 1
- 125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- BZWKPZBXAMTXNQ-UHFFFAOYSA-N sulfurocyanidic acid Chemical class OS(=O)(=O)C#N BZWKPZBXAMTXNQ-UHFFFAOYSA-N 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US843540A US3066127A (en) | 1959-09-30 | 1959-09-30 | Polymerization process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES261335A1 true ES261335A1 (es) | 1961-12-16 |
Family
ID=25290310
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES0261335A Expired ES261335A1 (es) | 1959-09-30 | 1960-09-28 | Un procedimiento para preparar polibutadieno |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3066127A (en, 2012) |
| BE (1) | BE595548A (en, 2012) |
| CH (1) | CH432851A (en, 2012) |
| DE (1) | DE1143333B (en, 2012) |
| ES (1) | ES261335A1 (en, 2012) |
| GB (1) | GB884071A (en, 2012) |
| NL (2) | NL130336C (en, 2012) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3170904A (en) * | 1959-11-28 | 1965-02-23 | Bridgestone Tire Co Ltd | Production of cis-1, 4 polybutadiene with a ni-bf3 etherate-air3 catalyst |
| US3170907A (en) * | 1959-12-31 | 1965-02-23 | Bridgestone Tire Co Ltd | Production of cis-1, 4 polybutadiene with a nickel carboxylic acid salt-boron trifluoride etherate-aluminum trialkyl catalyst |
| GB906334A (en) * | 1959-12-31 | 1962-09-19 | Bridgestone Tire Co Ltd | Method of manufacturing cis-1,4-polybutadiene |
| NL294777A (en, 2012) * | 1962-07-03 | |||
| BE634251A (en, 2012) * | 1962-08-07 | |||
| NL129053C (en, 2012) * | 1963-10-17 | |||
| DE1251030B (de) * | 1965-04-07 | 1967-09-28 | MONTICATINI Societa Generale per 1 Industiia Mmeraria e Chnnica Mailand ("Italien) | \ erfahren zur Polymerisation von Butadien |
| US3725492A (en) * | 1970-10-26 | 1973-04-03 | Japanese Geon Co Ltd | Process for the preparation of liquid polybutadiene |
| GB1376750A (en) * | 1970-12-28 | 1974-12-11 | Sumitomo Chemical Co | Catalyst systems and their use in production of butadiene polymers |
| DE2122956C3 (de) * | 1971-05-10 | 1979-09-06 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Herstellung von flüssigen Butadienpolymerisaten |
| JPS511474B2 (en, 2012) * | 1972-09-22 | 1976-01-17 | ||
| DE2361782C3 (de) * | 1973-12-12 | 1982-05-06 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von niedermolekularem Polybutadien |
| DE2447203C3 (de) * | 1974-10-03 | 1982-03-18 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von Polybutadien |
| US3993856A (en) * | 1974-07-25 | 1976-11-23 | The Firestone Tire & Rubber Company | Process for polymerizing butadiene |
| DE2731067C3 (de) * | 1977-07-09 | 1981-11-26 | Bunawerke Hüls GmbH, 4370 Marl | Verfahren zur Herstellung von Polybutadien mit einem hohen Gehalt an Monomereneinheiten in cis-1,4- Struktur |
| US4258160A (en) * | 1977-12-22 | 1981-03-24 | The Firestone Tire & Rubber Company | Process for polymerizing butadiene |
| US4303769A (en) * | 1978-08-22 | 1981-12-01 | The B. F. Goodrich Company | Process for preparing substantially gel-free cis-1,4-polybutadiene |
| CN101389670B (zh) * | 2006-02-23 | 2012-06-27 | 巴斯夫欧洲公司 | 从含有1-丁烯、2-丁烯和异丁烯的工业c4烃料流制备端双键含量大于50%的聚异丁烯的方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB815310A (en) * | 1955-11-18 | 1959-06-24 | Bataafsche Petroleum | Process for polymerizing olefinically unsaturated hydrocarbons |
| US2781410A (en) * | 1953-04-04 | 1957-02-12 | Ziegler | Polymerization of ethylene in the presence of an aluminum trialkyl catalyst |
| DE1012460B (de) * | 1953-11-17 | 1957-07-18 | Dr Dr E H Karl Ziegler | Verfahren zur Herstellung von hochmolekularen Polyaethylenen |
| US2871276A (en) * | 1954-08-11 | 1959-01-27 | Standard Oil Co | Polymerization of alpha olefins in the presence of an air3 catalyst |
| DE1024715B (de) * | 1954-11-23 | 1958-02-20 | Du Pont | Kontinuierliches Verfahren zur Polymerisation von AEthylen allein oder in Mischung mit anderen Olefinen |
| NL107439C (en, 2012) * | 1954-12-24 | |||
| NL203326A (en, 2012) * | 1955-01-05 | |||
| US2839518A (en) * | 1955-03-22 | 1958-06-17 | Du Pont | Manufacture of polyethylene of controlled molecular weight |
| US2924579A (en) * | 1955-03-23 | 1960-02-09 | Exxon Research Engineering Co | Method of preparing aluminum chloride complex catalyst |
| DE1011620B (de) * | 1955-06-14 | 1957-07-04 | Huels Chemische Werke Ag | Verfahren zur Herstellung von Polyaethylen |
| DE1022382B (de) * | 1956-04-12 | 1958-01-09 | Hoechst Ag | Verfahren zur Polymerisation von niederen Olefinen |
| BE557561A (en, 2012) * | 1956-08-02 | |||
| US2905659A (en) * | 1956-08-07 | 1959-09-22 | Goodrich Gulf Chem Inc | Method of removing heavy metal catalyst from olefinic polymers by treatment with de-gassed water |
| US2953556A (en) * | 1957-07-18 | 1960-09-20 | Goodrich Gulf Chem Inc | Polymer recovery process |
-
0
- NL NL256428D patent/NL256428A/xx unknown
- NL NL130336D patent/NL130336C/xx active
- BE BE595548D patent/BE595548A/xx unknown
-
1959
- 1959-09-30 US US843540A patent/US3066127A/en not_active Expired - Lifetime
-
1960
- 1960-09-28 ES ES0261335A patent/ES261335A1/es not_active Expired
- 1960-09-28 DE DES70599A patent/DE1143333B/de active Pending
- 1960-09-28 GB GB33299/60A patent/GB884071A/en not_active Expired
- 1960-09-28 CH CH1092760A patent/CH432851A/de unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB884071A (en) | 1961-12-06 |
| BE595548A (en, 2012) | |
| CH432851A (de) | 1967-03-31 |
| NL130336C (en, 2012) | |
| US3066127A (en) | 1962-11-27 |
| NL256428A (en, 2012) | |
| DE1143333B (de) | 1963-02-07 |
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