ES2580162T3 - Procedimiento de optimización de la transición de una calidad de polímero a otra - Google Patents
Procedimiento de optimización de la transición de una calidad de polímero a otra Download PDFInfo
- Publication number
- ES2580162T3 ES2580162T3 ES08847638.7T ES08847638T ES2580162T3 ES 2580162 T3 ES2580162 T3 ES 2580162T3 ES 08847638 T ES08847638 T ES 08847638T ES 2580162 T3 ES2580162 T3 ES 2580162T3
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- ES
- Spain
- Prior art keywords
- polymer
- input variables
- specifications
- variables
- aij
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2400/00—Characteristics for processes of polymerization
- C08F2400/02—Control or adjustment of polymerization parameters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/05—Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Un procedimiento de reducción del tiempo de transición y la cantidad de polímero producido fuera de las especificaciones, durante el cambio de la especificación de la calidad de un homopolímero o copolímero a otra, en un reactor en suspensión de doble bucle con un sistema de catalizador de Ziegler-Natta o metaloceno y en el que el polímero se prepara a partir de un monómero(s) de olefina, comprendiendo dicho procedimiento las etapas de: a) seleccionar n variables de entrada, vinculadas a las condiciones del reactor; b) definir un modelo de red neuronal restringido de forma general**Fórmula** en la que las Xi son las n variables de entrada normalizadas y las aij y las bi son coeficientes numéricos, las Ci son funciones intermedias y Res es la estimación de la propiedad del polímero resultante escalado que corresponde a las condiciones de reacción definidas por las n variables de entrada; c) ajustar los parámetros (n+1)*n aij y (n+1) bi para reducir al mínimo el error en Res bajo restricciones apropiadas, estando dichas restricciones impuestas por las igualdades o desigualdades relacionadas con una cualquiera de las Xi, aij, bi, Ci, Res o combinación de las mismas o con cualquier derivada parcial de cualquier orden y en el que las derivadas parciales miden la variación del resultado derivado de una ecuación cuando una y sólo una de las variables ha sido cambiada por un paso infinitesimal; d) predecir en tiempo real la densidad e índice de fluidez del polímero que sale del reactor respecto a la evolución temporal de las n variables de entrada en las ecuaciones de la etapa b), e incluyendo, siempre que sea apropiado, respuestas dinámicas en la etapa a las diferentes condiciones de entrada; e) inferir valores apropiados para cualquier combinación de 2 variables de entrada Xi y Xj, conociendo las otras (n-2) variables y los valores deseados de la densidad y el índice de fluidez; f) a partir de una determinada ley de la evolución temporal de las n variables de entrada entre dos condiciones de equilibrio que corresponden a dos especificaciones del producto, calcular el tiempo en el que al menos las características de un polímero salen de las especificaciones del producto de la primera calidad del polímero y el tiempo en el que las características del último polímero alcanzan las especificaciones del producto de la segunda calidad de polímero; g) calcular el tiempo de producción fuera de las especificaciones mediante el cálculo de la diferencia entre los dos tiempos calculados en la etapa f); h) reducir al mínimo el tiempo de producción fuera de las especificaciones de la etapa g) modificando la ley de evolución de las n variables de entrada, sujeto a las limitaciones del procedimiento.
Description
Claims (1)
-
imagen1
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07120023A EP2055721A1 (en) | 2007-11-05 | 2007-11-05 | Method for optimising the transition from one polymer grade to another |
EP07120023 | 2007-11-05 | ||
PCT/EP2008/064941 WO2009059970A1 (en) | 2007-11-05 | 2008-11-04 | Method for optimising the transition from one polymer grade to another |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2580162T3 true ES2580162T3 (es) | 2016-08-19 |
Family
ID=39228347
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES08847638.7T Active ES2580162T3 (es) | 2007-11-05 | 2008-11-04 | Procedimiento de optimización de la transición de una calidad de polímero a otra |
Country Status (9)
Country | Link |
---|---|
US (1) | US8706304B2 (es) |
EP (2) | EP2055721A1 (es) |
JP (1) | JP2011503277A (es) |
KR (1) | KR101259234B1 (es) |
CN (1) | CN101842395B (es) |
EA (1) | EA017550B1 (es) |
ES (1) | ES2580162T3 (es) |
PT (1) | PT2207814T (es) |
WO (1) | WO2009059970A1 (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2055720A1 (en) * | 2007-11-05 | 2009-05-06 | Total Petrochemicals Research Feluy | Predictive model for density and melt index of polymer leaving loop reactor |
CN104656457A (zh) * | 2013-11-19 | 2015-05-27 | 中国石油天然气股份有限公司 | 一种丙烯聚合环管反应器内部压力计算方法 |
EP2995635A1 (en) * | 2014-09-11 | 2016-03-16 | Sulzer Chemtech AG | Method to minimize the transition time from one polymer grade to another polymer grade in a polymerization plant |
EP3390468B1 (en) * | 2015-12-17 | 2024-03-13 | TotalEnergies OneTech Belgium | Process for determining one or more operating conditions of an olefin polymerization reactor |
KR102479346B1 (ko) | 2018-11-12 | 2022-12-19 | 주식회사 엘지화학 | 폴리올레핀 제조 공정에서의 파울링 예측 방법 |
CN111832693B (zh) * | 2019-04-16 | 2024-05-28 | 杭州海康威视数字技术股份有限公司 | 神经网络层运算、模型训练方法、装置及设备 |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3152872A (en) * | 1964-10-13 | figure | ||
US2285721A (en) * | 1941-04-10 | 1942-06-09 | Karp Morris | Vegetable grater |
US4448736A (en) * | 1982-05-24 | 1984-05-15 | Standard Oil Company (Indiana) | Continuous in-line melt flow rate control system |
US5675253A (en) * | 1991-11-20 | 1997-10-07 | Auburn International, Inc. | Partial least square regression techniques in obtaining measurements of one or more polymer properties with an on-line nmr system |
US5650722A (en) * | 1991-11-20 | 1997-07-22 | Auburn International, Inc. | Using resin age factor to obtain measurements of improved accuracy of one or more polymer properties with an on-line NMR system |
US5519605A (en) * | 1994-10-24 | 1996-05-21 | Olin Corporation | Model predictive control apparatus and method |
US6213958B1 (en) * | 1996-08-29 | 2001-04-10 | Alan A. Winder | Method and apparatus for the acoustic emission monitoring detection, localization, and classification of metabolic bone disease |
US6106785A (en) * | 1997-06-30 | 2000-08-22 | Honeywell Inc. | Polymerization process controller |
US6122557A (en) * | 1997-12-23 | 2000-09-19 | Montell North America Inc. | Non-linear model predictive control method for controlling a gas-phase reactor including a rapid noise filter and method therefor |
BR9803848A (pt) * | 1998-10-08 | 2000-10-31 | Opp Petroquimica S A | Sistema para inferência em linha de propriedades fìsicas e quìmicas, sistema para inferência em linha de variáveis de processo, e, sistema de controle em linha |
BR9906022A (pt) * | 1999-12-30 | 2001-09-25 | Opp Petroquimica S A | Processo para a produção controlada de polietileno e seus copolìmeros |
GB0005866D0 (en) * | 2000-03-10 | 2000-05-03 | Borealis Polymers Oy | Process control system |
US6403748B1 (en) * | 2000-04-26 | 2002-06-11 | Union Carbide Chemicals & Plastics Technology Corporation | Enhancing production of resin withing specifications |
EP1195388A1 (en) * | 2000-10-04 | 2002-04-10 | ATOFINA Research | Process for producing bimodal polyethylene resins |
US6396716B1 (en) * | 2001-09-20 | 2002-05-28 | The University Of Hong Kong | Apparatus for improving stability and dynamic response of half-bridge converter |
BR0213978A (pt) * | 2001-11-09 | 2004-10-19 | Exxonmobil Chemical Patentes I | Medição on-line e controle de propriedades de polìmero por espectroscopia raman |
CN102527307A (zh) * | 2002-10-28 | 2012-07-04 | 伊内奥斯美国公司 | 采用在线仪器数据转换的化学制造工艺和方法 |
US7319040B2 (en) * | 2002-10-28 | 2008-01-15 | Ineos Usa Llc | Process control using on-line instrumentation and process models |
US7838605B2 (en) * | 2003-10-17 | 2010-11-23 | Univation Technologies, Llc | Polymerization monitoring and control using improved leading indicators |
US20050272891A1 (en) * | 2004-02-13 | 2005-12-08 | Atofina Research S.A. | Double loop technology |
JP2005339241A (ja) * | 2004-05-27 | 2005-12-08 | Nissan Motor Co Ltd | モデル予測制御装置および車両用推奨操作量生成装置 |
US7343225B2 (en) * | 2005-06-03 | 2008-03-11 | Univation Technologies, Llc | Method for reducing off-grade product production during reaction transitions |
EP1840140A1 (en) * | 2006-03-30 | 2007-10-03 | Total Petrochemicals Research Feluy | Method for making a transition between polymer grades |
WO2008030294A1 (en) * | 2006-09-07 | 2008-03-13 | Univation Technologies, Llc | Methods for on-line determination of degree of resin stickiness using a model for depression of melt initiation temperature |
-
2007
- 2007-11-05 EP EP07120023A patent/EP2055721A1/en not_active Withdrawn
-
2008
- 2008-11-04 WO PCT/EP2008/064941 patent/WO2009059970A1/en active Application Filing
- 2008-11-04 KR KR1020107009792A patent/KR101259234B1/ko active IP Right Grant
- 2008-11-04 EP EP08847638.7A patent/EP2207814B1/en active Active
- 2008-11-04 EA EA201000663A patent/EA017550B1/ru not_active IP Right Cessation
- 2008-11-04 US US12/741,382 patent/US8706304B2/en active Active
- 2008-11-04 JP JP2010532569A patent/JP2011503277A/ja active Pending
- 2008-11-04 PT PT88476387T patent/PT2207814T/pt unknown
- 2008-11-04 ES ES08847638.7T patent/ES2580162T3/es active Active
- 2008-11-04 CN CN2008801142144A patent/CN101842395B/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US8706304B2 (en) | 2014-04-22 |
KR101259234B1 (ko) | 2013-04-29 |
EP2207814B1 (en) | 2016-04-13 |
KR20100080921A (ko) | 2010-07-13 |
CN101842395B (zh) | 2013-04-17 |
PT2207814T (pt) | 2016-07-13 |
US20100324738A1 (en) | 2010-12-23 |
WO2009059970A1 (en) | 2009-05-14 |
EP2055721A1 (en) | 2009-05-06 |
JP2011503277A (ja) | 2011-01-27 |
CN101842395A (zh) | 2010-09-22 |
EP2207814A1 (en) | 2010-07-21 |
EA017550B1 (ru) | 2013-01-30 |
EA201000663A1 (ru) | 2010-12-30 |
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