ES2580162T3 - Procedimiento de optimización de la transición de una calidad de polímero a otra - Google Patents

Procedimiento de optimización de la transición de una calidad de polímero a otra Download PDF

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Publication number
ES2580162T3
ES2580162T3 ES08847638.7T ES08847638T ES2580162T3 ES 2580162 T3 ES2580162 T3 ES 2580162T3 ES 08847638 T ES08847638 T ES 08847638T ES 2580162 T3 ES2580162 T3 ES 2580162T3
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polymer
input variables
specifications
variables
aij
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ES08847638.7T
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English (en)
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André Lewalle
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TotalEnergies One Tech Belgium SA
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Total Research and Technology Feluy SA
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00Characteristics for processes of polymerization
    • C08F2400/02Control or adjustment of polymerization parameters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/05Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Un procedimiento de reducción del tiempo de transición y la cantidad de polímero producido fuera de las especificaciones, durante el cambio de la especificación de la calidad de un homopolímero o copolímero a otra, en un reactor en suspensión de doble bucle con un sistema de catalizador de Ziegler-Natta o metaloceno y en el que el polímero se prepara a partir de un monómero(s) de olefina, comprendiendo dicho procedimiento las etapas de: a) seleccionar n variables de entrada, vinculadas a las condiciones del reactor; b) definir un modelo de red neuronal restringido de forma general**Fórmula** en la que las Xi son las n variables de entrada normalizadas y las aij y las bi son coeficientes numéricos, las Ci son funciones intermedias y Res es la estimación de la propiedad del polímero resultante escalado que corresponde a las condiciones de reacción definidas por las n variables de entrada; c) ajustar los parámetros (n+1)*n aij y (n+1) bi para reducir al mínimo el error en Res bajo restricciones apropiadas, estando dichas restricciones impuestas por las igualdades o desigualdades relacionadas con una cualquiera de las Xi, aij, bi, Ci, Res o combinación de las mismas o con cualquier derivada parcial de cualquier orden y en el que las derivadas parciales miden la variación del resultado derivado de una ecuación cuando una y sólo una de las variables ha sido cambiada por un paso infinitesimal; d) predecir en tiempo real la densidad e índice de fluidez del polímero que sale del reactor respecto a la evolución temporal de las n variables de entrada en las ecuaciones de la etapa b), e incluyendo, siempre que sea apropiado, respuestas dinámicas en la etapa a las diferentes condiciones de entrada; e) inferir valores apropiados para cualquier combinación de 2 variables de entrada Xi y Xj, conociendo las otras (n-2) variables y los valores deseados de la densidad y el índice de fluidez; f) a partir de una determinada ley de la evolución temporal de las n variables de entrada entre dos condiciones de equilibrio que corresponden a dos especificaciones del producto, calcular el tiempo en el que al menos las características de un polímero salen de las especificaciones del producto de la primera calidad del polímero y el tiempo en el que las características del último polímero alcanzan las especificaciones del producto de la segunda calidad de polímero; g) calcular el tiempo de producción fuera de las especificaciones mediante el cálculo de la diferencia entre los dos tiempos calculados en la etapa f); h) reducir al mínimo el tiempo de producción fuera de las especificaciones de la etapa g) modificando la ley de evolución de las n variables de entrada, sujeto a las limitaciones del procedimiento.

Description

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Claims (1)

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ES08847638.7T 2007-11-05 2008-11-04 Procedimiento de optimización de la transición de una calidad de polímero a otra Active ES2580162T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP07120023A EP2055721A1 (en) 2007-11-05 2007-11-05 Method for optimising the transition from one polymer grade to another
EP07120023 2007-11-05
PCT/EP2008/064941 WO2009059970A1 (en) 2007-11-05 2008-11-04 Method for optimising the transition from one polymer grade to another

Publications (1)

Publication Number Publication Date
ES2580162T3 true ES2580162T3 (es) 2016-08-19

Family

ID=39228347

Family Applications (1)

Application Number Title Priority Date Filing Date
ES08847638.7T Active ES2580162T3 (es) 2007-11-05 2008-11-04 Procedimiento de optimización de la transición de una calidad de polímero a otra

Country Status (9)

Country Link
US (1) US8706304B2 (es)
EP (2) EP2055721A1 (es)
JP (1) JP2011503277A (es)
KR (1) KR101259234B1 (es)
CN (1) CN101842395B (es)
EA (1) EA017550B1 (es)
ES (1) ES2580162T3 (es)
PT (1) PT2207814T (es)
WO (1) WO2009059970A1 (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
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EP2055720A1 (en) * 2007-11-05 2009-05-06 Total Petrochemicals Research Feluy Predictive model for density and melt index of polymer leaving loop reactor
CN104656457A (zh) * 2013-11-19 2015-05-27 中国石油天然气股份有限公司 一种丙烯聚合环管反应器内部压力计算方法
EP2995635A1 (en) * 2014-09-11 2016-03-16 Sulzer Chemtech AG Method to minimize the transition time from one polymer grade to another polymer grade in a polymerization plant
EP3390468B1 (en) * 2015-12-17 2024-03-13 TotalEnergies OneTech Belgium Process for determining one or more operating conditions of an olefin polymerization reactor
KR102479346B1 (ko) 2018-11-12 2022-12-19 주식회사 엘지화학 폴리올레핀 제조 공정에서의 파울링 예측 방법
CN111832693B (zh) * 2019-04-16 2024-05-28 杭州海康威视数字技术股份有限公司 神经网络层运算、模型训练方法、装置及设备

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US4448736A (en) * 1982-05-24 1984-05-15 Standard Oil Company (Indiana) Continuous in-line melt flow rate control system
US5675253A (en) * 1991-11-20 1997-10-07 Auburn International, Inc. Partial least square regression techniques in obtaining measurements of one or more polymer properties with an on-line nmr system
US5650722A (en) * 1991-11-20 1997-07-22 Auburn International, Inc. Using resin age factor to obtain measurements of improved accuracy of one or more polymer properties with an on-line NMR system
US5519605A (en) * 1994-10-24 1996-05-21 Olin Corporation Model predictive control apparatus and method
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BR9906022A (pt) * 1999-12-30 2001-09-25 Opp Petroquimica S A Processo para a produção controlada de polietileno e seus copolìmeros
GB0005866D0 (en) * 2000-03-10 2000-05-03 Borealis Polymers Oy Process control system
US6403748B1 (en) * 2000-04-26 2002-06-11 Union Carbide Chemicals & Plastics Technology Corporation Enhancing production of resin withing specifications
EP1195388A1 (en) * 2000-10-04 2002-04-10 ATOFINA Research Process for producing bimodal polyethylene resins
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BR0213978A (pt) * 2001-11-09 2004-10-19 Exxonmobil Chemical Patentes I Medição on-line e controle de propriedades de polìmero por espectroscopia raman
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Also Published As

Publication number Publication date
US8706304B2 (en) 2014-04-22
KR101259234B1 (ko) 2013-04-29
EP2207814B1 (en) 2016-04-13
KR20100080921A (ko) 2010-07-13
CN101842395B (zh) 2013-04-17
PT2207814T (pt) 2016-07-13
US20100324738A1 (en) 2010-12-23
WO2009059970A1 (en) 2009-05-14
EP2055721A1 (en) 2009-05-06
JP2011503277A (ja) 2011-01-27
CN101842395A (zh) 2010-09-22
EP2207814A1 (en) 2010-07-21
EA017550B1 (ru) 2013-01-30
EA201000663A1 (ru) 2010-12-30

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