ES2578629T3 - Procedimiento de síntesis mejorado de nanotubos de carbono sobre multisoportes - Google Patents

Procedimiento de síntesis mejorado de nanotubos de carbono sobre multisoportes Download PDF

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Publication number
ES2578629T3
ES2578629T3 ES12810373.6T ES12810373T ES2578629T3 ES 2578629 T3 ES2578629 T3 ES 2578629T3 ES 12810373 T ES12810373 T ES 12810373T ES 2578629 T3 ES2578629 T3 ES 2578629T3
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Prior art keywords
mixture
fibers
particles
ntc
articles
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ES12810373.6T
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English (en)
Inventor
Jinbo Bai
Anthony DICHIARA
Jinkai YUAN
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Centre National de la Recherche Scientifique CNRS
CentraleSupelec
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Centre National de la Recherche Scientifique CNRS
CentraleSupelec
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/02—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of inorganic substances
    • H01B3/12—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of inorganic substances ceramics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C01B32/162—Preparation characterised by catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C01B32/164—Preparation involving continuous processes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • H01B3/445—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds from vinylfluorides or other fluoroethylenic compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/20—Nanotubes characterized by their properties
    • C01B2202/22—Electronic properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/20—Nanotubes characterized by their properties
    • C01B2202/26—Mechanical properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/70—Nanostructure
    • Y10S977/734—Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc.
    • Y10S977/742—Carbon nanotubes, CNTs
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2918—Rod, strand, filament or fiber including free carbon or carbide or therewith [not as steel]
    • Y10T428/292—In coating or impregnation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Ceramic Engineering (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Chemical Vapour Deposition (AREA)

Abstract

Procedimiento de síntesis de nanotubos de carbono (abreviado como NTC) por deposición química en fase vapor (abreviada como CVD) en la superficie de artículos, presentándose dichos artículos en forma de una mezcla A (i) de partículas y/o fibras de un material que comprende al menos un átomo de oxígeno e (ii) de partículas y/o fibras de un material seleccionado entre los carburos y/o de un material que comprende al menos un átomo de silicio, comprendiendo dicho procedimiento las siguientes etapas, realizadas bajo una corriente de gas(es) inerte(s), opcionalmente en una mezcla con hidrógeno: (i) calentamiento en un recinto de reacción de dicha mezcla A de artículos a una temperatura comprendida entre 400 ºC y 900 ºC; (ii) introducción en dicho recinto, de una fuente de carbono compuesta por acetileno y/o xileno, y un catalizador que comprende ferroceno; (iii) exposición de dicha mezcla A, calentada, a dicha fuente de carbono y a dicho catalizador que comprende ferroceno durante un tiempo suficiente para obtener NTC en la superficie de los artículos que constituyen dicha mezcla A; (iv) recuperación de una mezcla B al finalizar la etapa (iii), opcionalmente, tras una etapa de enfriamiento, estando formada dicha mezcla B por la mezcla A de artículos que comprenden NTC en su superficie; (v) opcionalmente separación de las partículas y/o fibras de un material que comprende al menos un átomo de oxígeno, dichas partículas y/o fibras que comprenden NTC en su superficie partículas y/o fibras de un material seleccionado entre los carburos y/o que comprende al menos un átomo de silicio, comprendiendo dichas partículas y/o fibras NTC en su superficie, procedimiento en el que el material seleccionado entre los carburos y/o que comprende al menos un átomo de silicio se selecciona entre el nitruro de silicio (Si3N4), carburo de silicio (SiC), sílice (Si2O), TiC y B4C, y/o en el que el material que comprende al menos un átomo de oxígeno es AI2O3.

Description

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Claims (1)

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ES12810373.6T 2011-12-08 2012-12-07 Procedimiento de síntesis mejorado de nanotubos de carbono sobre multisoportes Active ES2578629T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1161344A FR2983846B1 (fr) 2011-12-08 2011-12-08 Procede de synthese ameliore de nanotubes de carbone sur multi-supports
FR1161344 2011-12-08
PCT/FR2012/052840 WO2013083931A1 (fr) 2011-12-08 2012-12-07 Procédé de synthèse amélioré de nanotubes de carbone sur multi-supports

Publications (1)

Publication Number Publication Date
ES2578629T3 true ES2578629T3 (es) 2016-07-28

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ES12810373.6T Active ES2578629T3 (es) 2011-12-08 2012-12-07 Procedimiento de síntesis mejorado de nanotubos de carbono sobre multisoportes

Country Status (6)

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US (1) US9779850B2 (es)
EP (1) EP2788288B1 (es)
JP (1) JP6422779B2 (es)
ES (1) ES2578629T3 (es)
FR (1) FR2983846B1 (es)
WO (1) WO2013083931A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9987608B2 (en) 2014-09-19 2018-06-05 NanoSynthesis Plus, Ltd. Methods and apparatuses for producing dispersed nanostructures
CN105347326B (zh) * 2015-11-19 2017-07-28 南昌大学 一种碳纳米葫芦结构材料的制备方法
JP6688932B1 (ja) * 2019-08-21 2020-04-28 Ｄ−Ｐｏｗｅｒ株式会社 カーボンナノチューブ（ｃｎｔ）製造に使用する材料の供給装置

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7189430B2 (en) * 2002-02-11 2007-03-13 Rensselaer Polytechnic Institute Directed assembly of highly-organized carbon nanotube architectures
US7981396B2 (en) * 2003-12-03 2011-07-19 Honda Motor Co., Ltd. Methods for production of carbon nanostructures
US20070189953A1 (en) * 2004-01-30 2007-08-16 Centre National De La Recherche Scientifique (Cnrs) Method for obtaining carbon nanotubes on supports and composites comprising same
FR2927619B1 (fr) * 2008-02-20 2011-01-14 Commissariat Energie Atomique Croissance de nanotubes de carbone sur substrats de carbone ou metalliques.
FR2939422B1 (fr) * 2008-12-08 2011-05-06 Centre Nat Rech Scient Procede de synthese de nanotubes de carbone sur materiaux micrometriques longs et particulaires

Also Published As

Publication number Publication date
US20140343210A1 (en) 2014-11-20
JP6422779B2 (ja) 2018-11-14
WO2013083931A1 (fr) 2013-06-13
EP2788288A1 (fr) 2014-10-15
FR2983846B1 (fr) 2014-01-31
JP2015507593A (ja) 2015-03-12
FR2983846A1 (fr) 2013-06-14
EP2788288B1 (fr) 2016-05-04
US9779850B2 (en) 2017-10-03

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