ES2560265T3 - Proceso para la fabricación de hidrocarburos nitrados - Google Patents
Proceso para la fabricación de hidrocarburos nitrados Download PDFInfo
- Publication number
- ES2560265T3 ES2560265T3 ES10765718.1T ES10765718T ES2560265T3 ES 2560265 T3 ES2560265 T3 ES 2560265T3 ES 10765718 T ES10765718 T ES 10765718T ES 2560265 T3 ES2560265 T3 ES 2560265T3
- Authority
- ES
- Spain
- Prior art keywords
- formula
- weight
- nitric acid
- nitrated
- hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229930195733 hydrocarbon Natural products 0.000 title abstract description 7
- 150000002430 hydrocarbons Chemical class 0.000 title abstract description 7
- 238000000034 method Methods 0.000 title abstract description 6
- 238000004519 manufacturing process Methods 0.000 title 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract description 12
- 229910017604 nitric acid Inorganic materials 0.000 abstract description 12
- 239000000203 mixture Substances 0.000 abstract description 6
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 4
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 125000000547 substituted alkyl group Chemical group 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 33
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 18
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 10
- 239000001294 propane Substances 0.000 description 9
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 6
- FGLBSLMDCBOPQK-UHFFFAOYSA-N 2-nitropropane Chemical compound CC(C)[N+]([O-])=O FGLBSLMDCBOPQK-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 4
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 4
- 238000006396 nitration reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- WGRUUOMGUXAKMN-UHFFFAOYSA-N nitric acid;propane Chemical compound CCC.O[N+]([O-])=O WGRUUOMGUXAKMN-UHFFFAOYSA-N 0.000 description 3
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 3
- 235000019260 propionic acid Nutrition 0.000 description 3
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 3
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 description 2
- DHPRWWYQIUXCQM-UHFFFAOYSA-N 2,2-dinitropropane Chemical compound [O-][N+](=O)C(C)(C)[N+]([O-])=O DHPRWWYQIUXCQM-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000001272 nitrous oxide Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
- C07C201/06—Preparation of nitro compounds
- C07C201/08—Preparation of nitro compounds by substitution of hydrogen atoms by nitro groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US25314309P | 2009-10-20 | 2009-10-20 | |
| US253143P | 2009-10-20 | ||
| PCT/US2010/051619 WO2011049745A1 (en) | 2009-10-20 | 2010-10-06 | Process for the manufacture of nitrated hydrocarbons |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2560265T3 true ES2560265T3 (es) | 2016-02-18 |
Family
ID=43034250
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES10765718.1T Active ES2560265T3 (es) | 2009-10-20 | 2010-10-06 | Proceso para la fabricación de hidrocarburos nitrados |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8324435B2 (OSRAM) |
| EP (1) | EP2491000B1 (OSRAM) |
| JP (1) | JP5698249B2 (OSRAM) |
| CN (1) | CN102574770B (OSRAM) |
| BR (1) | BR112012008742B1 (OSRAM) |
| ES (1) | ES2560265T3 (OSRAM) |
| WO (1) | WO2011049745A1 (OSRAM) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009129097A1 (en) * | 2008-04-16 | 2009-10-22 | Angus Chemical Company | Nitrated hydrocarbons, derivatives, and processes for their manufacture |
| US8519199B2 (en) * | 2008-04-16 | 2013-08-27 | Angus Chemical Company | Process for the manufacture of nitropropanes |
| US8431754B2 (en) * | 2009-10-20 | 2013-04-30 | Dow Global Technologies Llc | Process for nitroalkane recovery by aqueous phase recycle to nitration reactor |
| BR112012008916B1 (pt) * | 2009-10-20 | 2021-04-06 | Angus Chemical Company | Processo para sintetizar pelo menos um nitroalcano |
| JP5620504B2 (ja) * | 2009-10-20 | 2014-11-05 | ダウ グローバル テクノロジーズ エルエルシー | 分割壁カラムを使用するニトロアルカンの下流回収法 |
| CN102741217B (zh) | 2009-12-24 | 2015-04-15 | 陶氏环球技术有限责任公司 | 烃类进料灵活的高压硝化装置的设计 |
| WO2012148643A1 (en) * | 2011-04-18 | 2012-11-01 | Dow Global Technologies Llc | Apparatus and process for nitration selectivity flexibility enabled by azeotropic distillation |
| CN103588644A (zh) * | 2013-11-28 | 2014-02-19 | 临沂远博化工有限公司 | 一种生产硝基甲烷的设备 |
| CN109796345B (zh) * | 2019-01-30 | 2022-02-22 | 青岛科技大学 | 一种亚硝酸盐置换法生产硝基甲烷的尾气综合利用方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2071122A (en) * | 1937-02-16 | Process of nitrating ethane | ||
| US1967667A (en) * | 1934-07-24 | Process of nitrating paraffin hydro | ||
| US2489320A (en) * | 1949-11-29 | Nitration of paraffins | ||
| US3689576A (en) * | 1969-12-05 | 1972-09-05 | Purdue Research Foundation | Preparation of nitroalkanes by thermal decomposition of acyl nitrate |
| JPS5947359A (ja) * | 1982-09-08 | 1984-03-17 | Toshiba Corp | 封着用部材 |
| US4469904A (en) * | 1983-07-05 | 1984-09-04 | W. R. Grace & Co. | Preparation of nitro compounds by vapor phase nitration of carboxylic acids |
| US4476336A (en) * | 1983-07-05 | 1984-10-09 | W. R. Grace & Co. | Process for forming nitroparaffin |
| JPS6168450A (ja) * | 1984-09-10 | 1986-04-08 | ダブリユー・アール・グレイス・アンド・カンパニー−コネチカツト | 均一気相ニトロ化法 |
| FR2632635B1 (fr) | 1988-06-09 | 1990-10-19 | Seppic Sa | Procede de fabrication de nitromethane |
| JP4811764B2 (ja) * | 2005-11-01 | 2011-11-09 | 独立行政法人産業技術総合研究所 | ニトロ化合物の製造方法及びその製造装置 |
| WO2009129097A1 (en) * | 2008-04-16 | 2009-10-22 | Angus Chemical Company | Nitrated hydrocarbons, derivatives, and processes for their manufacture |
| US8519199B2 (en) * | 2008-04-16 | 2013-08-27 | Angus Chemical Company | Process for the manufacture of nitropropanes |
-
2010
- 2010-10-06 WO PCT/US2010/051619 patent/WO2011049745A1/en not_active Ceased
- 2010-10-06 CN CN201080047327.4A patent/CN102574770B/zh active Active
- 2010-10-06 ES ES10765718.1T patent/ES2560265T3/es active Active
- 2010-10-06 BR BR112012008742-8A patent/BR112012008742B1/pt active IP Right Grant
- 2010-10-06 JP JP2012535225A patent/JP5698249B2/ja active Active
- 2010-10-06 US US12/899,169 patent/US8324435B2/en active Active
- 2010-10-06 EP EP10765718.1A patent/EP2491000B1/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| WO2011049745A1 (en) | 2011-04-28 |
| BR112012008742B1 (pt) | 2021-08-31 |
| US20110092750A1 (en) | 2011-04-21 |
| US8324435B2 (en) | 2012-12-04 |
| EP2491000A1 (en) | 2012-08-29 |
| BR112012008742A2 (pt) | 2020-08-25 |
| EP2491000B1 (en) | 2015-11-25 |
| CN102574770A (zh) | 2012-07-11 |
| JP5698249B2 (ja) | 2015-04-08 |
| CN102574770B (zh) | 2016-08-17 |
| JP2013508368A (ja) | 2013-03-07 |
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