ES2556955T3 - Fluoración catalítica en fase gaseosa de 243db para dar 1234yf - Google Patents

Fluoración catalítica en fase gaseosa de 243db para dar 1234yf Download PDF

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Publication number
ES2556955T3
ES2556955T3 ES09812442.3T ES09812442T ES2556955T3 ES 2556955 T3 ES2556955 T3 ES 2556955T3 ES 09812442 T ES09812442 T ES 09812442T ES 2556955 T3 ES2556955 T3 ES 2556955T3
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Spain
Prior art keywords
gas phase
give
catalytic fluorination
tetrafluoropropene
stream
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES09812442.3T
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English (en)
Inventor
Laurent Wendlinger
Anne Pigamo
Dominique Deur-Bert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
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Arkema France SA
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Publication date
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Publication of ES2556955T3 publication Critical patent/ES2556955T3/es
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
    • C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/866—Nickel and chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/38—Separation; Purification; Stabilisation; Use of additives
    • C07C17/42—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00—Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/04—Chloro-alkenes
    • C07C21/073—Dichloro-alkenes
    • C07C21/08—Vinylidene chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/26—Fluorinating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Abstract

Procedimiento para preparar 2,3,3,3-tetrafluoropropeno (1234yf), que comprende: (i) poner en contacto 2,3-dicloro-1,1,1-trifluoropropano (243db) con fluoruro de hidrógeno HF en fase gaseosa en presencia de un catalizador de fluoración en condiciones suficientes para producir una mezcla de reacción; (ii) separar la mezcla de reacción en una primera corriente que comprende HCl, 2,3,3,3-tetrafluoropropeno (1234yf) y una segunda corriente que comprende HF, 2-cloro-3,3,3-trifluoro-1-propeno (1233xf) y 1,1,1,2,2-pentafluoropropano (245cb); (iii) recircular al menos una parte de la segunda corriente al menos en parte de vuelta a la etapa (i).

Description

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Claims (1)

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ES09812442.3T 2009-12-23 2009-12-23 Fluoración catalítica en fase gaseosa de 243db para dar 1234yf Active ES2556955T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IB2009/056056 WO2011077193A1 (en) 2009-12-23 2009-12-23 Catalytic gas phase fluorination of 243db to 1234yf

Publications (1)

Publication Number Publication Date
ES2556955T3 true ES2556955T3 (es) 2016-01-21

Family

ID=42651444

Family Applications (1)

Application Number Title Priority Date Filing Date
ES09812442.3T Active ES2556955T3 (es) 2009-12-23 2009-12-23 Fluoración catalítica en fase gaseosa de 243db para dar 1234yf

Country Status (7)

Country Link
US (1) US8207384B2 (es)
EP (1) EP2516367B1 (es)
CN (1) CN102666452B (es)
ES (1) ES2556955T3 (es)
HU (1) HUE025859T2 (es)
PL (1) PL2516367T3 (es)
WO (1) WO2011077193A1 (es)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011077191A1 (en) * 2009-12-23 2011-06-30 Arkema France Catalytic gas phase fluorination of 1230xa to 1234yf
US8680345B2 (en) 2011-01-07 2014-03-25 Honeywell International Inc. Low temperature production of 2-chloro-3,3,3-trifluoropropene
CN103313960B (zh) 2011-01-21 2016-06-08 阿克马法国公司 催化气相氟化
US8741828B2 (en) 2011-02-23 2014-06-03 Honeywell International Inc. Azeotrope and azeotrope-like compositions useful for the production of haloolefins
CN104961623A (zh) 2011-10-31 2015-10-07 大金工业株式会社 用于制备2-氯-3,3,3-三氟丙烯的方法
FR2986525B1 (fr) * 2012-02-03 2014-02-14 Arkema France Procede de production de 2,3,3,3-tetrafluoropropene
CN105189423B (zh) * 2013-03-13 2018-12-11 阿科玛股份有限公司 用于纯化及稳定氢氟烯烃和氢氯氟烯烃的方法
US9334206B2 (en) * 2013-03-15 2016-05-10 Honeywell International Inc. Integrated process to produce 2,3,3,3-tetrafluoropropene
JP5825299B2 (ja) * 2013-07-12 2015-12-02 ダイキン工業株式会社 ２，３，３，３−テトラフルオロプロペンの製造方法
JP6233352B2 (ja) * 2015-06-02 2017-11-22 ダイキン工業株式会社 含フッ素オレフィンの製造方法
GB2540427B (en) * 2015-07-17 2017-07-19 Mexichem Fluor Sa De Cv Process for the preparation of 2,3,3,3-tetrafluoropropene (1234yf)
GB2540421C (en) 2015-07-17 2018-11-14 Mexichem Fluor Sa De Cv Process for preparing 245cb from 243db
EP3347335A4 (en) * 2015-09-09 2019-03-20 The Chemours Company FC, LLC NOVEL METHOD FOR FLUORING CHLOROALKANES
FR3064629B1 (fr) * 2017-03-28 2019-04-05 Arkema France Procede de production et de purification du 2,3,3,3-tetrafluoro-1-propene
FR3064627B1 (fr) * 2017-03-28 2020-02-21 Arkema France Procede de production du 2,3,3,3-tetrafluoropropene.
FR3064628B1 (fr) * 2017-03-28 2019-04-05 Arkema France Procede de production et de purification du 2,3,3,3-tetrafluoropropene
FR3065726B1 (fr) * 2017-04-28 2019-04-19 Arkema France Procede de production et de purification du 2,3,3,3-tetrafluoropropene.
JP7287965B2 (ja) * 2019-11-13 2023-06-06 フジアン ヨンジン テクノロジー カンパニー リミテッド ２，３，３，３－テトラフルオロプロペン（１２３４ｙｆ）および２，３－ジクロロ－１，１，１－トリフルオロプロパン（２４３ｄｂ）の新しい合成方法

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4902838A (en) 1988-12-28 1990-02-20 E. I. Du Pont De Nemours And Company Isomerization of saturated fluorohydrocarbons
FR2669022B1 (fr) 1990-11-13 1992-12-31 Atochem Procede de fabrication du tetrafluoro-1,1,1,2-ethane.
US5714651A (en) 1995-12-28 1998-02-03 Elf Atochem North America, Inc. Use of polymerization inhibitor to prolong the life of a Lewis acid catalyst
EP0939071B1 (en) 1998-02-26 2003-07-30 Central Glass Company, Limited Method for producing fluorinated propane
US7485598B2 (en) 2006-06-21 2009-02-03 Arkema Inc. High pressure catalyst activation method and catalyst produced thereby
US7189884B2 (en) * 2004-04-29 2007-03-13 Honeywell International Processes for synthesis of tetrafluoropropene
US8058486B2 (en) 2004-04-29 2011-11-15 Honeywell International Inc. Integrated process to produce 2,3,3,3-tetrafluoropropene
US7335804B2 (en) * 2005-11-03 2008-02-26 Honeywell International Inc. Direct conversion of HCFC 225ca/cb mixture
EP2546224B2 (en) 2006-01-03 2023-06-14 Honeywell International Inc. Method for producing fluorinated organic compounds
WO2008002500A1 (en) 2006-06-27 2008-01-03 E. I. Du Pont De Nemours And Company Tetrafluoropropene production processes
EP2129644B1 (en) 2006-10-03 2020-07-01 Mexichem Fluor S.A. de C.V. Dehydrogenationhalogenation process for the production of c3-c6-(hydro)fluoroalkenes
ES2542306T5 (es) * 2006-10-31 2022-03-30 Chemours Co Fc Llc Procedimientos para la producción de fluoropropanos y halopropenos
US7795480B2 (en) 2007-07-25 2010-09-14 Honeywell International Inc. Method for producing 2-chloro-3,3,3,-trifluoropropene (HCFC-1233xf)
CN101597209A (zh) * 2008-03-20 2009-12-09 霍尼韦尔国际公司 用于制备2,3,3,3-四氟丙烯的一体式方法
FR2929271B1 (fr) 2008-03-28 2010-04-16 Arkema France Procede pour la preparation du 1,2,3,3,3-pentafluoropropene- 1
GB0806389D0 (en) * 2008-04-09 2008-05-14 Ineos Fluor Holdings Ltd Process
HUE059978T2 (hu) * 2008-05-07 2023-01-28 Chemours Co Fc Llc Kompozíciók

Also Published As

Publication number Publication date
CN102666452A (zh) 2012-09-12
CN102666452B (zh) 2016-01-13
US20110160499A1 (en) 2011-06-30
EP2516367B1 (en) 2015-10-07
PL2516367T3 (pl) 2016-08-31
HUE025859T2 (en) 2016-05-30
US8207384B2 (en) 2012-06-26
US20110313215A2 (en) 2011-12-22
EP2516367A1 (en) 2012-10-31
WO2011077193A1 (en) 2011-06-30

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