ES2535201T3 - Composiciones de eliminación de oxígeno solubles polares - Google Patents
Composiciones de eliminación de oxígeno solubles polares Download PDFInfo
- Publication number
- ES2535201T3 ES2535201T3 ES12706984.7T ES12706984T ES2535201T3 ES 2535201 T3 ES2535201 T3 ES 2535201T3 ES 12706984 T ES12706984 T ES 12706984T ES 2535201 T3 ES2535201 T3 ES 2535201T3
- Authority
- ES
- Spain
- Prior art keywords
- polar
- compound
- matrix polymer
- moiety
- reactive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title 1
- 230000008030 elimination Effects 0.000 title 1
- 238000003379 elimination reaction Methods 0.000 title 1
- 229910052760 oxygen Inorganic materials 0.000 title 1
- 239000001301 oxygen Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 4
- 239000011159 matrix material Substances 0.000 abstract 4
- 229920000642 polymer Polymers 0.000 abstract 4
- 229920000728 polyester Polymers 0.000 abstract 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- QIKYZXDTTPVVAC-UHFFFAOYSA-N 4-Aminobenzamide Chemical compound NC(=O)C1=CC=C(N)C=C1 QIKYZXDTTPVVAC-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- 150000003623 transition metal compounds Chemical class 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1535—Five-membered rings
- C08K5/1539—Cyclic anhydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
- B65D81/26—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
- B65D81/266—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/14—Gas barrier composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/10—Applications used for bottles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/006—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Food Science & Technology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Wrappers (AREA)
- Polyesters Or Polycarbonates (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Gas Separation By Absorption (AREA)
- Packages (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Polyamides (AREA)
Abstract
Composición que comprende: - un primer compuesto que es un polímero de matriz seleccionado del grupo que consiste en poliésteres y náilones, - un segundo compuesto que es un catalizador de oxidación, que se selecciona del grupo que consiste en compuestos de metal de transición, cualquier molécula que contiene una N-hidroxiimida cíclica y sus derivados y combinaciones, - un tercer compuesto en el intervalo del 0,1 al 5% en peso de la composición total, que es un copolímero o cooligómero que comprende al menos un comonómero que contiene carbonos alílicos y al menos un resto "no reactivo" polar; en la que dicho al menos un comonómero que contiene carbonos alílicos es isopreno o butadieno, y en la que el resto polar no reactivo se deriva de p-aminobenzamida, y el resto "no reactivo" polar es uno en el que no se detecta reacción con el polímero de matriz de poliéster usando análisis mediante IR tras haberse combinado en estado fundido 7 partes del compuesto con el resto polar en una cámara de mezclado con 93 partes del polímero de matriz de poliéster bajo nitrógeno durante un periodo de 2 minutos a una temperatura 15ºC mayor que el punto de fusión del polímero de matriz sin el catalizador de oxidación.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161444471P | 2011-02-18 | 2011-02-18 | |
| US201161444471P | 2011-02-18 | ||
| PCT/US2012/025744 WO2012112957A1 (en) | 2011-02-18 | 2012-02-17 | Polar soluble oxygen scavenging compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2535201T3 true ES2535201T3 (es) | 2015-05-06 |
Family
ID=45787354
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES12706984.7T Active ES2535201T3 (es) | 2011-02-18 | 2012-02-17 | Composiciones de eliminación de oxígeno solubles polares |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20140145109A1 (es) |
| EP (1) | EP2675848B1 (es) |
| CN (1) | CN103635536B (es) |
| BR (1) | BR112013021037B1 (es) |
| CA (1) | CA2827540C (es) |
| ES (1) | ES2535201T3 (es) |
| MX (1) | MX339191B (es) |
| PL (1) | PL2675848T3 (es) |
| RU (1) | RU2593453C2 (es) |
| WO (1) | WO2012112957A1 (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| LT2834296T (lt) * | 2012-04-01 | 2018-11-12 | Biochemtex S.P.A. | Polinės tirpios deguonį sugeriančios kompozicijos ir jų gaminiai |
| FR3019803B1 (fr) * | 2014-04-10 | 2016-12-23 | Fareva | Generateur aerosol en matiere plastique |
| US20170313875A1 (en) * | 2016-04-28 | 2017-11-02 | Plastipak Packaging, Inc. | Oxygen scavenging compositions, articles containing same, and methods of their use |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0150479B1 (en) * | 1983-12-26 | 1990-06-13 | Nippon Zeon Co., Ltd. | Process for modifying conjugated diene polymers |
| DE19501450A1 (de) * | 1995-01-19 | 1996-07-25 | Basf Ag | Thermoplastische Polyamidformmassen |
| US6863988B2 (en) | 1996-09-23 | 2005-03-08 | Bp Corporation North America Inc. | Oxygen scavenging monolayer bottles |
| CN100535040C (zh) * | 1998-03-25 | 2009-09-02 | 切夫里昂菲利普化学有限责任公司 | 用于塑料膜及饮料和食品容器的减少氧化产物的氧清除剂 |
| ATE434022T1 (de) * | 2001-04-26 | 2009-07-15 | Toyo Seikan Kaisha Ltd | Sauerstoffabsobierende harz-zusammensetzung und mehrschichtbehälter mit wenigstens einer schicht daraus |
| EP1704917B1 (en) * | 2003-12-04 | 2010-03-17 | Zeon Corporation | Oxygen absorber |
| RU2357977C2 (ru) * | 2004-11-30 | 2009-06-10 | Асахи Касеи Кемикалз Корпорейшн | Полиэфирная смола, формованное изделие из нее и способы их получения |
| CN104017241B (zh) * | 2007-05-10 | 2017-09-05 | 塑料包装有限公司 | 氧清除分子、包含所述氧清除分子的制品及其使用方法 |
| JP2010150488A (ja) * | 2008-12-26 | 2010-07-08 | Toyo Seikan Kaisha Ltd | 耐熱容器成形用エチレンテレフタレート系ポリエステル樹脂及びこの樹脂から成るプリフォーム |
| US8409680B2 (en) * | 2009-06-11 | 2013-04-02 | M&G Usa Corporation | Polyamide-polydiene blends with improved oxygen reactivity |
| EP2475703A4 (en) * | 2009-09-11 | 2015-04-22 | Invista Technologies Srl | METHOD FOR IMPROVED POLYESTER RESIN MIXTURES FOR OXYGEN ABSORPTION AND PRODUCTS THEREOF |
-
2012
- 2012-02-17 ES ES12706984.7T patent/ES2535201T3/es active Active
- 2012-02-17 RU RU2013142439/05A patent/RU2593453C2/ru active
- 2012-02-17 MX MX2013009503A patent/MX339191B/es active IP Right Grant
- 2012-02-17 CN CN201280009394.6A patent/CN103635536B/zh not_active Expired - Fee Related
- 2012-02-17 EP EP12706984.7A patent/EP2675848B1/en not_active Not-in-force
- 2012-02-17 CA CA2827540A patent/CA2827540C/en not_active Expired - Fee Related
- 2012-02-17 US US13/982,832 patent/US20140145109A1/en not_active Abandoned
- 2012-02-17 BR BR112013021037-0A patent/BR112013021037B1/pt not_active IP Right Cessation
- 2012-02-17 WO PCT/US2012/025744 patent/WO2012112957A1/en active Application Filing
- 2012-02-17 PL PL12706984T patent/PL2675848T3/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP2675848A1 (en) | 2013-12-25 |
| WO2012112957A1 (en) | 2012-08-23 |
| RU2593453C2 (ru) | 2016-08-10 |
| EP2675848B1 (en) | 2015-01-21 |
| RU2013142439A (ru) | 2015-04-10 |
| CN103635536B (zh) | 2016-02-24 |
| PL2675848T3 (pl) | 2015-07-31 |
| US20140145109A1 (en) | 2014-05-29 |
| CN103635536A (zh) | 2014-03-12 |
| BR112013021037A8 (pt) | 2018-07-31 |
| MX2013009503A (es) | 2014-03-27 |
| BR112013021037A2 (pt) | 2016-10-11 |
| CA2827540A1 (en) | 2012-08-23 |
| CA2827540C (en) | 2019-07-16 |
| BR112013021037B1 (pt) | 2020-05-26 |
| MX339191B (es) | 2016-05-13 |
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