ES2533072T3 - Procedimiento para la preparación de compuestos complejos de manganeso puenteados del triazaciclononano - Google Patents
Procedimiento para la preparación de compuestos complejos de manganeso puenteados del triazaciclononano Download PDFInfo
- Publication number
- ES2533072T3 ES2533072T3 ES10760913.3T ES10760913T ES2533072T3 ES 2533072 T3 ES2533072 T3 ES 2533072T3 ES 10760913 T ES10760913 T ES 10760913T ES 2533072 T3 ES2533072 T3 ES 2533072T3
- Authority
- ES
- Spain
- Prior art keywords
- manganese
- ion
- divalent
- metal
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011572 manganese Substances 0.000 title abstract description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title abstract 4
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 229910052748 manganese Inorganic materials 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 150000003839 salts Chemical class 0.000 abstract description 7
- 239000003446 ligand Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract 6
- 239000002184 metal Substances 0.000 abstract 6
- 230000003647 oxidation Effects 0.000 abstract 4
- 238000007254 oxidation reaction Methods 0.000 abstract 4
- 150000002500 ions Chemical class 0.000 abstract 3
- 150000002739 metals Chemical class 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- -1 hexafluorophosphate Chemical compound 0.000 abstract 2
- 150000004679 hydroxides Chemical class 0.000 abstract 2
- 229910000000 metal hydroxide Inorganic materials 0.000 abstract 2
- 229910044991 metal oxide Inorganic materials 0.000 abstract 2
- 150000004706 metal oxides Chemical class 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- WLDGDTPNAKWAIR-UHFFFAOYSA-N 1,4,7-trimethyl-1,4,7-triazonane Chemical compound CN1CCN(C)CCN(C)CC1 WLDGDTPNAKWAIR-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 229910001413 alkali metal ion Inorganic materials 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052742 iron Chemical group 0.000 abstract 1
- 159000000014 iron salts Chemical class 0.000 abstract 1
- 150000002696 manganese Chemical class 0.000 abstract 1
- 150000002697 manganese compounds Chemical class 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 abstract 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 229910021135 KPF6 Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
- C07F13/005—Compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
- B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0213—Complexes without C-metal linkages
- B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09290713 | 2009-09-18 | ||
| EP09290713 | 2009-09-18 | ||
| PCT/EP2010/005569 WO2011032666A1 (de) | 2009-09-18 | 2010-09-10 | Verfahren zur herstellung von verbrückten mangan-komplexen des triazacyclononans |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2533072T3 true ES2533072T3 (es) | 2015-04-07 |
Family
ID=41682826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES10760913.3T Active ES2533072T3 (es) | 2009-09-18 | 2010-09-10 | Procedimiento para la preparación de compuestos complejos de manganeso puenteados del triazaciclononano |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9012630B2 (enExample) |
| EP (1) | EP2477740B1 (enExample) |
| JP (1) | JP5688413B2 (enExample) |
| CN (1) | CN102510774B (enExample) |
| ES (1) | ES2533072T3 (enExample) |
| PL (1) | PL2477740T3 (enExample) |
| WO (1) | WO2011032666A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2103604A1 (de) | 2008-03-17 | 2009-09-23 | Evonik Degussa GmbH | Verfahren zur Herstellung von Epichlorhydrin |
| CA2791423C (en) | 2010-03-03 | 2017-06-20 | Catexel Limited | Preparation of bleaching catalysts |
| ES2683005T3 (es) | 2011-09-08 | 2018-09-24 | Catexel Technologies Limited | Catalizadores |
| US9624119B2 (en) | 2014-06-13 | 2017-04-18 | Ecolab Usa Inc. | Enhanced catalyst stability in activated peroxygen and/or alkaline detergent formulations |
| CN107652436B (zh) * | 2016-07-23 | 2020-12-11 | 金华职业技术学院 | 一种不同价双核锰(ii、iii)一维双带状配位聚合物及其制备方法 |
| EP4045626A4 (en) * | 2019-10-17 | 2023-10-25 | Specialty Operations France | Metal complex and use thereof |
| CN110963558A (zh) * | 2019-11-29 | 2020-04-07 | 常熟市化创化学技术有限公司 | 类芬顿试剂及其在有机废水处理中的应用 |
| CN120005219B (zh) * | 2025-04-22 | 2025-08-29 | 天津科技大学 | 具有氧化酶特性的锰金属有机框架材料及其制备方法与应用 |
| CN121698848B (zh) * | 2026-02-09 | 2026-05-26 | 浙江大学衢州研究院 | 一种具有三氮杂环壬烷大环骨架的铁配合物及其制备方法和应用 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2100924T3 (es) | 1990-05-21 | 1997-07-01 | Unilever Nv | Activacion de blanqueador. |
| US5274147A (en) | 1991-07-11 | 1993-12-28 | Lever Brothers Company, Division Of Conopco, Inc. | Process for preparing manganese complexes |
| GB9118242D0 (en) | 1991-08-23 | 1991-10-09 | Unilever Plc | Machine dishwashing composition |
| US5153161A (en) * | 1991-11-26 | 1992-10-06 | Lever Brothers Company, Division Of Conopco, Inc. | Synthesis of manganese oxidation catalyst |
| US5256779A (en) | 1992-06-18 | 1993-10-26 | Lever Brothers Company, Division Of Conopco, Inc. | Synthesis of manganese oxidation catalyst |
| US5329024A (en) | 1993-03-30 | 1994-07-12 | National Starch And Chemical Investment Holding Corporation | Epoxidation of olefins via certain manganese complexes |
| US5385893A (en) * | 1993-05-06 | 1995-01-31 | The Dow Chemical Company | Tricyclopolyazamacrocyclophosphonic acids, complexes and derivatives thereof, for use as contrast agents |
| WO1995030733A1 (en) * | 1994-05-09 | 1995-11-16 | Unilever N.V. | Bleach catalyst composition |
| JP4216328B2 (ja) | 1994-08-19 | 2009-01-28 | デジマ テック ビー．ヴィ． | 液晶ポリエーテル |
| AU3077495A (en) | 1994-08-19 | 1996-03-14 | Unilever Plc | Detergent bleach composition |
| DE19620241A1 (de) | 1996-05-20 | 1997-11-27 | Patt R Prof Dr | Verfahren zum Delignifizieren von Zellstoffen und Verwendung eines Katalysators |
| EP1159259A1 (en) * | 1999-03-08 | 2001-12-05 | Ciba SC Holding AG | Manganese complexes of salen ligands and the use thereof |
| GB9930422D0 (en) | 1999-12-22 | 2000-02-16 | Unilever Plc | Bleach catalysts |
| DE10051317A1 (de) | 2000-10-17 | 2002-04-18 | Degussa | Übergangsmetallkomplexe mit Polydentaten Liganden zur Verstärkung der Bleich- und Delignifizierungswirkung von Persauerstoffverbindungen |
| WO2002059245A1 (en) * | 2001-01-26 | 2002-08-01 | Ciba Specialty Chemicals Holding Inc. | Process for the preparation of water-soluble granules or particles of saldimine-type manganese complexes |
| WO2002088063A1 (en) | 2001-04-27 | 2002-11-07 | Lonza Ag | Process for the production of ketones |
| ES2259771T3 (es) * | 2002-07-11 | 2006-10-16 | Ciba Specialty Chemicals Holding Inc. | Uso de compuestos de complejo metalico como catalizadores de oxidacion. |
| US7972386B2 (en) | 2005-10-12 | 2011-07-05 | Conopco, Inc. | Bleaching of substrates |
| MX2009007268A (es) | 2007-01-16 | 2009-07-10 | Unilever Nv | Blanqueo de substratos. |
-
2010
- 2010-09-10 WO PCT/EP2010/005569 patent/WO2011032666A1/de not_active Ceased
- 2010-09-10 JP JP2012529144A patent/JP5688413B2/ja active Active
- 2010-09-10 PL PL10760913T patent/PL2477740T3/pl unknown
- 2010-09-10 US US13/394,968 patent/US9012630B2/en active Active
- 2010-09-10 EP EP10760913.3A patent/EP2477740B1/de active Active
- 2010-09-10 ES ES10760913.3T patent/ES2533072T3/es active Active
- 2010-09-10 CN CN201080041259.0A patent/CN102510774B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN102510774A (zh) | 2012-06-20 |
| WO2011032666A1 (de) | 2011-03-24 |
| EP2477740B1 (de) | 2015-01-21 |
| US9012630B2 (en) | 2015-04-21 |
| PL2477740T3 (pl) | 2015-06-30 |
| US20120202990A1 (en) | 2012-08-09 |
| JP2013505206A (ja) | 2013-02-14 |
| JP5688413B2 (ja) | 2015-03-25 |
| CN102510774B (zh) | 2014-07-23 |
| EP2477740A1 (de) | 2012-07-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Bąk et al. | Exploiting the mechanical bond for molecular recognition and sensing of charged species | |
| Zhou et al. | Antioxidative and anti-tumour activities of solid quercetin metal (II) complexes | |
| ES2625454T3 (es) | Procedimiento para la obtención de complejos metálicos de 3,7-diaza-biciclo[3,3,1]nonano | |
| Baniodeh et al. | Ringing the changes in FeIII/YbIII cyclic coordination clusters | |
| Thio et al. | Influence of inductive effects and steric encumbrance on the catecholase activities of copper (II) complexes of reduced Schiff base ligands | |
| Scott et al. | . mu.-Oxalato-cobalt (III) complexes | |
| Sreenivasulu et al. | Synthesis, structures and catecholase activity of a new series of dicopper (II) complexes of reduced Schiff base ligands | |
| AR091779A1 (es) | Procedimiento para la sintesis mejorada de opioides | |
| Bharti et al. | Syntheses, crystal structures and photoluminescent properties of new homoleptic and heteroleptic zinc (II) dithiocarbamato complexes | |
| Tran et al. | Monomeric dinitrosyl iron complexes: synthesis and reactivity | |
| JP2013505206A (ja) | トリアザシクロノナンの橋かけマンガン錯体の製造方法 | |
| Bhardwaj et al. | Salicylaldimine Schiff bases–Generation of self-assembled and chiral complexes with Ni (II) and Zn (II) ions. An unusual antiferromagnetic interaction in a triply bridged Ni (II) dimer | |
| Wegermann et al. | Synthesis, characterization and catalytic activity toward dye decolorization by manganese (II) mononuclear complexes | |
| Biswas et al. | Structural variations in polynuclear copper (II) complexes based on salicylaldimine type ligands along with dicyanamido co-ligand | |
| JP2014520781A5 (enExample) | ||
| Wang et al. | Well-defined polymers containing a single mid-chain viologen group: Synthesis, environment-sensitive fluorescence, and redox activity | |
| Wu et al. | Two stable cobalt (II) coordination polymers as dual-functional fluorescent sensors for efficient detection of Zn2+/Cu2+ ions and norfloxacin | |
| Jin et al. | Syntheses and structural characterization of nine coordination compounds assembled from copper acetate, 3, 5-dimethylpyrazole and carboxylates | |
| Yin et al. | Protonated 3-amino-1, 2, 4-triazole templated luminescent lanthanide isophthalates with a rare (3, 6)-connected topology | |
| Bushuev et al. | Zinc (II) and cadmium (II) complexes based on 4-(3, 5-diphenyl-1H-pyrazol-1-yl)-6-(piperidin-1-yl) pyrimidine (L): Synthesis, structure, luminescence. Double lone pair–π interactions in the structure of ZnL2Cl2 | |
| CN104558061B (zh) | 二硼酸均苯三羧酸钴铟微孔晶体及其制备方法 | |
| CN103880871B (zh) | 一种由0d→2d二重互穿结构镉配位聚合物的合成方法 | |
| GUEYE et al. | Synthesis, characterization and antioxidant activity of lanthanide (III) complexes with tridentate Schiff base ligand. X-ray crystal structure of the Ce (III) complex | |
| Yang et al. | The first hybrid organic–inorganic frameworks based on lanthanide (III) sulfate chains, in situ generated oxalate and organic pillars of 1, 4-piperazinediacetic acid | |
| Das et al. | Supramolecular assembly of binuclear [V2O3 (NTA) 2] 4− unit with [Ce (H2O) 9] 3+: Synthesis, structure, luminescent, magnetic properties and TD-DFT calculation |