ES2240272T3 - AGENT INTENDED FOR THE INHIBITOR SUPPORT OF THE DIRT FOR TEXTILE SURFACES. - Google Patents
AGENT INTENDED FOR THE INHIBITOR SUPPORT OF THE DIRT FOR TEXTILE SURFACES.Info
- Publication number
- ES2240272T3 ES2240272T3 ES01109812T ES01109812T ES2240272T3 ES 2240272 T3 ES2240272 T3 ES 2240272T3 ES 01109812 T ES01109812 T ES 01109812T ES 01109812 T ES01109812 T ES 01109812T ES 2240272 T3 ES2240272 T3 ES 2240272T3
- Authority
- ES
- Spain
- Prior art keywords
- agent
- dirt
- agent according
- active substance
- cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0031—Carpet, upholstery, fur or leather cleansers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/08—Processes in which the treating agent is applied in powder or granular form
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Agente destinado al apresto inhibidor de la suciedad para superficies textiles.Agent intended for the inhibitor sizing of dirt for textile surfaces.
El invento se refiere a un agente destinado al apresto inhibidor de la suciedad para superficies textiles, en particular para revestimientos textiles de suelos.The invention relates to an agent intended for prepared dirt inhibitor for textile surfaces, in Particular for textile floor coverings.
Los agentes conocidos destinados al apresto inhibidor de la suciedad, p.ej. de un suelo alfombrado, sirven para retardar el ensuciamiento renovado del suelo alfombrado, en particular después de un tratamiento del mismo con un agente para la limpieza de alfombras. Tales agentes destinados a retardar el ensuciamiento están basados por regla general en una resina fluorocarbonada, y se rocían en forma líquida sobre la superficie que se ha de aprestar, y después de esto se aplican por frotamiento y se distribuyen con un aparato cepillador o uno similar. En este caso, se manifiesta como desventajoso el hecho de que el agente, rociado p.ej. con frascos rociadores usuales en el sector doméstico, no se puede distribuir uniformemente. Tampoco la incorporación con un aparato cepillador consigue una distribución uniforme. El líquido que contiene el agente no es puesto en contacto por las cerdas con cada una de las fibras del revestimiento textil de suelos. Además de esto, al rociar el agente se ensucia el entorno circundante, tal como p.ej. los rodapiés, los muebles, el suelo duro, etc.Known agents intended for sizing dirt inhibitor, eg of carpeted floor, are used to retard the renewed fouling of carpeted floors, in particular after a treatment thereof with an agent for carpet cleaning. Such agents intended to delay the fouling are usually based on a resin fluorocarbon, and are sprayed in liquid form on the surface to be squeezed, and after this they are applied by rubbing and they are distributed with a brushing device or a similar one. In this case, the fact that the agent, sprayed eg with usual spray bottles in the domestic sector, It cannot be distributed evenly. Nor the incorporation with a brushing device achieves a uniform distribution. The liquid which contains the agent is not contacted by the bristles with each of the fibers of the textile floor covering. In addition to this, by spraying the agent the surrounding environment becomes dirty, such such as skirting boards, furniture, hard floor, etc.
A partir del documento de solicitud de patente europea EP-A-0392248 se conoce un agente de limpieza, que posee un material de soporte a base de partículas poliméricas hinchadas, con una alta capacidad de absorción, y de partículas de fibras orgánicas.From the patent application document European EP-A-0392248 is known a cleaning agent, which has a support material based on swollen polymer particles, with a high capacity of absorption, and organic fiber particles.
Partiendo del estado de la técnica citado al principio, el invento está basado en la misión de presentar un agente destinado al apresto inhibidor de la suciedad para superficies textiles que, con una manipulación simplificada, permita evitar ensuciamientos del entorno.Starting from the state of the art cited to In principle, the invention is based on the mission of presenting a agent intended for dirt inhibitor sizing for textile surfaces that, with simplified handling, allow avoid fouling of the environment.
El problema planteado por esta misión se resuelve con el objeto de la reivindicación 1. La solución de sustancia activa puede contener una resina fluorocarbonada o un derivado de polisiloxano, o de manera adicionalmente alternativa una combinación a base de una formulación de resina fluorocarbonada y de un derivado de polisiloxano. Como consecuencia de la composición conforme al invento, la solución de sustancia activa inhibidora de la suciedad, tal como una resina fluorocarbonada, se aplica a través de un soporte intermedio, tal como p.ej. celulosa o también otros materiales de soporte conocidos. El agente conforme al invento se esparce de manera sencillísima sobre el revestimiento textil de suelos, que se ha de aprestar, y después de esto se incorpora p.ej. por medio de un aparato cepillador en el revestimiento de suelos. En este caso se evitan ensuciamientos del entorno. Una ventaja adicional de la composición conforme al invento es el comportamiento mejorado de ensuciamiento frente a los habituales agentes inhibidores de la suciedad. De esto resulta que, después de una limpieza del revestimiento textil de suelos, se disminuye el grado de ensuciamiento esencialmente de manera correspondiente, por lo que, después de una limpieza, se alcanza un grado de ensuciamiento, que corresponde al de un suelo tratado con un agente de limpieza habitual. A fin de aumentar adicionalmente el efecto de limpieza, puede estar previsto que el agente contenga además un agente para la limpieza de materiales textiles, que contiene preferiblemente un agente tensioactivo o una mezcla de agentes tensioactivos. En este caso se puede tratar de un agente tensioactivo aniónico, no iónico, catiónico o incluso anfótero, siendo los agentes tensioactivos aniónicos, no obstante, más eficaces para el efecto de limpieza que los agentes tensioactivos no iónicos o anfóteros. En este contexto, la composición conforme al invento, con un material de soporte tal como celulosa. se manifiesta como ventajosa en el sentido de que las sustancias activas, depositadas junto a éste, siguen permaneciendo eficaces. Es sabido que los productos anti-suciedad (en inglés anti-soil) destinados a la inhibición de la suciedad, que contienen partículas catiónicas, no son compatibles con agentes tensioactivos aniónicos para realizar la limpieza. Éstos se neutralizan en soluciones y se vuelven ineficaces. Las dos sustancias activas necesitan su carga eléctrica, para entrar en contacto, por una parte, con las fibras de la alfombra (anti-soil; agente inhibidor de la suciedad) y, por otra parte, con la suciedad (agente tensioactivo, agente de limpieza). El material de soporte, en particular celulosa, tiene una afinidad diversa para los respectivos componentes, que por consiguiente son absorbidos por el material de soporte en concentración diversa, y se depositan junto a las fibras en el exterior. Por lo tanto, las partículas catiónicas y aniónicas no se neutralizan, después de lo cual ambos componentes permanecen eficaces por medio del material de soporte que actúa a modo de un catalizador. En una forma de ejecución preferida del objeto del invento, el material de soporte está mezclado con agua, realizándose adicionalmente que una mezcla de las partículas de fibras orgánicas, depositadas junto a la superficie de las partículas poliméricas saturadas con agua, es provista de una solución de sustancia activa. Como material de soporte se utilizan, por ejemplo, partículas poliméricas, muy absorbentes, hinchadas después de esto - los denominados materiales superabsorbentes -, y esto en común con partículas de fibras orgánicas, que están depositadas junto a la superficie de las partículas poliméricas. Las partículas poliméricas muy absorbentes e hinchadas, proporcionan el volumen necesario y la superficie necesaria por medio de una alta proporción de agua fijada en las partículas poliméricas. El material de soporte, o bien el material absorbente, está enteramente a disposición de la superficie de la alfombra. Éste tiende a la formación de un aglomerado, de tal manera que no se Aenarena@ en la alfombra. Las partículas de fibras orgánicas están depositadas junto a la superficie de las partículas poliméricas hinchadas. Por tanto, ellas están muy bien distribuidas y se necesita solamente una pequeña cantidad de partículas de fibras orgánicas. Una ventaja esencial adicional se ha de ver en el hecho de que son posibles unas formulaciones muy variables, en particular de la sustancia inhibidora de la suciedad. P.ej., a este respecto, pueden pasar a utilizarse formulaciones de resinas fluorocarbonadas y/o derivados de polisiloxanos como agentes inhibidores de la suciedad en vinculación con un soporte intermedio del tipo citado. En una forma de ejecución adicional está previsto que las partículas poliméricas consistan en un poliacrilato. Se prefiere especialmente un poli(ácido acrílico) reticulado, que se presenta parcialmente como una sal de sodio. Tales polímeros muy absorbentes pueden recoger un múltiplo de su propio peso de líquidos acuosos. En este caso, se forma un gel, cuya estructura puede ser, no obstante, diversa. Tales polímeros muy activos en absorción no desprenden el líquido acuoso, es decir por regla general el agua normal que ellos han absorbido, ni siquiera bajo presión, o sólo lo hacen en una parte relativamente pequeña. Se prefiere, en el marco del invento, que el gel tenga la estructura de una masa granular (estructura de caviar). De esta manera se forman partículas poliméricas muy pequeñas, de estructura esférica, con un diámetro de aproximadamente 10-1.000 \mum en el estado hinchado. De manera correspondiente, se establece una superficie muy grande. Las fibras orgánicas pueden tener un diámetro de 5-30 \mum y una longitud de 50-400 \mum. En este caso se trata preferentemente de fibras de celulosa. Por lo demás, pueden estar previstas sustancias auxiliares y odoríferas usuales, tales como agentes conservantes, un agente antiestático, etc.The problem posed by this mission is solved for the purpose of claim 1. The substance solution active may contain a fluorocarbon resin or a derivative of polysiloxane, or additionally alternatively a combination based on a formulation of fluorocarbon resin and a derivative of polysiloxane. As a consequence of the composition according to invention, the solution of dirt-inhibiting active substance, such as a fluorocarbon resin, it is applied through a intermediate support, such as cellulose or others known support materials. The agent according to the invention is spread very simply on the textile lining of floors, to be squeezed, and after that it is incorporated, e.g. by means of a brushing device in the floor covering. In In this case, fouling of the environment is avoided. An advantage Additional composition according to the invention is the behavior Improved fouling against the usual agents dirt inhibitors It follows that, after a cleaning of the textile floor covering, the degree is decreased of fouling essentially correspondingly, so that, after cleaning, a degree of fouling is achieved, corresponding to that of a soil treated with a cleaning agent habitual. In order to further increase the cleaning effect, it may be provided that the agent also contains an agent for the cleaning of textile materials, which preferably contains a surfactant or a mixture of surfactants. In this case can be an anionic, nonionic surfactant, cationic or even amphoteric, the surfactants being anionic, however, more effective for the cleaning effect than nonionic or amphoteric surfactants. In this context, the composition according to the invention, with such a support material as cellulose It manifests itself as advantageous in the sense that active substances, deposited next to it, remain effective. It is known that anti-dirt products (in English anti-soil) intended to inhibit dirt, which contain cationic particles, are not compatible with anionic surfactants for cleaning. These they are neutralized in solutions and become ineffective. Both active substances need their electrical charge, to enter contact, on the one hand, with the fibers of the carpet (anti-soil; dirt inhibitor agent) and, by other part, with the dirt (surfactant, agent cleaning). The support material, in particular cellulose, has a diverse affinity for the respective components, which by consequently they are absorbed by the support material in diverse concentration, and are deposited next to the fibers in the Exterior. Therefore, cationic and anionic particles are not neutralize, after which both components remain effective through the support material that acts as a catalyst. In a preferred embodiment of the object of the invention, the support material is mixed with water, being made in addition to a mixture of organic fiber particles, deposited next to the surface of the polymer particles saturated with water, it is provided with a solution of active substance. As support material, for example, particles are used polymeric, very absorbent, swollen after this - the called superabsorbent materials - and this in common with organic fiber particles, which are deposited next to the surface of polymer particles. Polymer particles very absorbent and swollen, they provide the necessary volume and necessary area by means of a high proportion of fixed water in polymeric particles. The support material, or the absorbent material, is entirely available to the surface of the carpet This tends to the formation of an agglomerate, of such way that Aenarena is not on the carpet. Fiber particles organic are deposited next to the surface of the particles swollen polymers. Therefore, they are very well distributed and only a small amount of fiber particles is needed organic. An additional essential advantage has to be seen in the fact that very variable formulations are possible, in particular of the dirt inhibitor substance. For example, in this regard, formulations of fluorocarbon resins may be used and / or polysiloxane derivatives as inhibitors of dirt in connection with an intermediate support of the type mentioned. In a further embodiment it is provided that the particles Polymers consist of a polyacrylate. It is especially preferred a crosslinked poly (acrylic acid), which is partially presented Like a sodium salt Such highly absorbent polymers can collect a multiple of your own weight of aqueous liquids. In this case, a gel is formed, the structure of which can be, however, diverse. Such highly active polymers in absorption do not give off the aqueous liquid, that is as a rule the normal water that they have absorbed, not even under pressure, or just do it in a relatively small part. In the context of the invention, it is preferred that the gel has the structure of a granular mass (structure of caviar). In this way polymer particles are formed very small, spherical structure, with a diameter of approximately 10-1,000 µm in the swollen state. By way of correspondingly, a very large surface is established. Fibers organic can have a diameter of 5-30 µm and a length of 50-400 µm. In this case it is preferably cellulose fibers. For the rest, they can be provided usual auxiliary and odoriferous substances, such as preservative agents, an antistatic agent, etc.
En lo que se refiere a la receta del material de soporte se remite al documento de patente europea EP-B1 0.392.248.With regard to the recipe of the material of support is referred to the European patent document EP-B1 0.392.248.
El agente conforme al invento se explica más detalladamente a continuación con ayuda de los dibujos adjuntos, que representan solamente unos ejemplos de realización del agente. Allí muestran:The agent according to the invention is explained more in detail below with the help of the attached drawings, which they represent only some examples of embodiment of the agent. There show:
la Fig. 1 un diagrama para la representación del ensuciamiento renovado de un suelo alfombrado;Fig. 1 a diagram for the representation of renewed fouling of carpeted flooring;
la Fig. 2 un diagrama de barras para la representación del comportamiento de limpieza y ensuciamiento sobre un suelo alfombrado de terciopelo de poliamida;Fig. 2 a bar chart for the representation of cleaning and fouling behavior on a carpeted floor made of polyamide velvet;
la Fig. 3 un diagrama de barras correspondiente al de la Fig. 2 con un agente conforme al invento en una forma adicional de realización.Fig. 3 a corresponding bar chart to that of Fig. 2 with an agent according to the invention in a form Additional realization.
El diagrama representado en la Fig. 1 muestra el comportamiento de ensuciamiento renovado de un suelo alfombrado sin tratar (línea U), de un suelo alfombrado tratado con un habitual agente para la limpieza de alfombras (línea H), de un suelo alfombrado tratado con una habitual solución de sustancia activa que contiene una sustancia inhibidora de la suciedad (línea W) y de un suelo alfombrado tratado con un agente (línea WT) que consiste en una sustancia inhibidora de la suciedad y en un material de soporte.The diagram shown in Fig. 1 shows the renewed fouling behavior of carpeted floor without treat (line U), of a carpeted floor treated with a habitual carpet cleaning agent (line H), of a floor carpeting treated with a usual active substance solution that it contains a dirt-inhibiting substance (line W) and a carpeted floor treated with an agent (WT line) consisting of a dirt-inhibiting substance and in a material of support.
Una mezcla, presentada a modo de ejemplo del agente WT, puede consistir en este caso en:A mixture, presented by way of example of WT agent, may in this case consist of:
- 65 partes de una solución de sustancia activa (sustancia inhibidora de la suciedad tal como, por ejemplo, una resina fluorocarbonada)65 parts of one active substance solution (dirt inhibitor such as, for example, a fluorocarbon resin)
- 35 partes de un material de soporte (por ejemplo, celulosa)35 parts of a support material (e.g. cellulose)
A partir del diagrama representado en la Fig. 1 se puede reconocer, que, en particular, en comparación con habituales agentes W inhibidores de la suciedad, aplicados en una forma líquida, el agente WT inhibidor de la suciedad, provisto de un material de soporte, conforme al invento, inhibe mejor a lo largo de un período de tiempo de varias semanas el ensuciamiento renovado del suelo alfombrado tratado. Así, el grado de ensuciamiento delta E de la solución WT corresponde, a lo largo de un primer período de tiempo de ensuciamiento A', aproximadamente al grado de la solución W conocida multiplicado por un factor 0,5 a 0,8. Después de una primera limpieza R', con el agente WT se consigue aproximadamente un grado de ensuciamiento delta E, que corresponde al de un suelo alfombrado tratado con un habitual agente de limpieza H.From the diagram represented in Fig. 1 it can be recognized that, in particular, compared to usual W dirt-inhibiting agents, applied in a liquid form, the WT dirt inhibitor agent, provided with a support material, according to the invention, inhibits better throughout a period of time of several weeks the renewed fouling of the carpeted floor treated. Thus, the degree of fouling delta E of the WT solution corresponds, over a first period of fouling time A ', approximately to the degree of the solution Known W multiplied by a factor 0.5 to 0.8. after one first cleaning R ', with the WT agent approximately degree of fouling delta E, which corresponds to that of a soil carpeting treated with a regular cleaning agent H.
Tal como muestra el diagrama de barras en la Fig. 2, el comportamiento de ensuciamiento de un suelo alfombrado, tratado con un agente WT, se ha mejorado esencialmente con respecto al de un suelo, tratado con un habitual agente W inhibidor de la suciedad. En particular, después de varias fases de ensuciamiento (A' hasta A'''') y de varias fases de limpieza (R' hasta R'''') se muestran unos manifiestas diferencias.As the bar chart in Fig. 2, the fouling behavior of a carpeted floor, treated with a WT agent, it has been essentially improved with respect to that of a soil, treated with a usual agent W inhibitor of dirt. In particular, after several fouling phases (A 'to A' '' ') and several cleaning phases (R' to R '' '') are They show some manifest differences.
Mediante al ensuciamiento esencialmente disminuido, también el grado de ensuciamiento delta E disminuye correspondientemente de manera esencial después de una limpieza (R' hasta R''''), de tal manera que después de una limpieza se alcanza un grado de ensuciamiento delta E, que corresponde al de un suelo tratado con un agente de limpieza H habitual.By essentially fouling decreased, also the degree of fouling delta E decreases correspondingly essentially after cleaning (R ' up to R '' ''), so that after a cleaning is reached a degree of fouling delta E, which corresponds to that of a soil treated with a usual cleaning agent H.
A fin de aumentar adicionalmente el efecto de limpieza, el agente WT puede estar provisto de otros agentes tensioactivos. Así, una mezcla presentada a modo de ejemplo WT' puede consistir en:In order to further increase the effect of cleaning, the WT agent may be provided with other agents surfactants Thus, a mixture presented by way of example WT ' It can consist of:
- 4,95254.9525
- partes de aguawater parts
- 0,02250.0225
- partes de un agente conservanteparts of a preservative agent
- 0,02500.0250
- partes de un acrilatoparts of an acrylate
- 24,850024,8500
- partes de aguawater parts
- 1,45001,4500
- partes de un agente de limpieza (de manera preferida agentes tensioactivos)parts of a cleaning agent (so preferred surfactants)
- 32,500032,5000
- partes de una solución de sustancia activa (sustancia inhibidora de la suciedad, p.ej. una resina fluorocarbonada)parts of an active substance solution (dirt-inhibiting substance, eg a resin fluorocarbon)
- 0,20000.2000
- partes de un aceite de perfumeparts of a perfume oil
- 1,00001,0000
- partes de un agente conservanteparts of a preservative agent
- 35,000035,0000
- partes de un material de soporte (p.ej. celulosa).parts of a support material (e.g. cellulose).
El diagrama de barras muestra el efecto de limpieza mejorado todavía más de la solución ampliada WT' frente a la solución WT. La citada en primer lugar muestra las buenas propiedades de limpieza de agentes habituales de limpieza de alfombras con un comportamiento mejorado en lo que se refiere al ensuciamiento renovado.The bar chart shows the effect of improved cleaning even more of the WT 'extended solution versus the WT solution. The one cited first shows the good cleaning properties of usual cleaning agents of carpets with improved behavior when it comes to dirtying renewed.
Otras mezclas presentadas a modo de ejemplo, WT o bien WT' pueden consistir en:Other mixtures presented by way of example, WT or Well WT 'may consist of:
- 4,95254.9525
- partes de aguawater parts
- 0,02250.0225
- partes de un agente conservanteparts of a preservative agent
- 0,02500.0250
- partes de un acrilatoparts of an acrylate
- 25,900025,9000
- partes de aguawater parts
- 0,40000.4000
- partes de un agente de limpieza (de manera preferida, agentes tensioactivos)parts of a cleaning agent (so preferred surfactants)
- 32,500032,5000
- partes de una solución de sustancia activa (sustancia inhibidora de la suciedad, p.ej. una resina fluorocarbonada)parts of an active substance solution (dirt-inhibiting substance, eg a resin fluorocarbon)
- 35,000035,0000
- partes de un material de soporte (p,ej. celulosa)parts of a support material (e.g. cellulose)
oor
- 4,95254.9525
- partes de aguawater parts
- 0,02250.0225
- partes de un agente conservanteparts of a preservative agent
- 0,02500.0250
- partes de un acrilatoparts of an acrylate
- 25,650025,6500
- partes de aguawater parts
- 1,45001,4500
- partes de un agente humectanteparts of a wetting agent
- 0,40000.4000
- partes de un agente de limpieza (de manera preferida, un agente tensioactivo)parts of a cleaning agent (so preferred, a surfactant)
- 32,500032,5000
- partes de una solución de sustancia activa (sustancia inhibidora de la suciedad, p.ej. una resina fluorocarbonada)parts of an active substance solution (dirt-inhibiting substance, eg a resin fluorocarbon)
- 35,000035,0000
- partes de un material de soporte (p.ej. celulosa)parts of a support material (e.g. cellulose)
La resina fluorocarbonada como agente inhibidor de la suciedad se emplea, en dependencia de la proporción de materiales sólidos de la sustancia activa, en una proporción de 1,0 a 70 tantos por ciento en peso.Fluorocarbon resin as an inhibitory agent of dirt is used, depending on the proportion of solid materials of the active substance, in a proportion of 1.0 at 70 percentage points by weight.
Otras recetas presentadas a modo de ejemplo pueden ser las siguientes:Other recipes presented by way of example They can be the following:
Material de soporteSupport material
Solución de sustancia activaActive substance solution
oor
Material de soporteSupport material
Solución de sustancia activaActive substance solution
Seguidamente, las cantidades empleadas se indican en general en intervalos de tantos por ciento en peso:Then, the amounts used are indicated in general at intervals of as many percent by weight:
Agente inhibidor de la suciedadDirt inhibitor
Agente de limpiezaCleaning agent
Material de soporteSupport material
Otras sustanciasOther substances
Por medio del apresto conforme al invento del agente inhibidor de la suciedad, junto a la evitación del conocido perjuicio para el entorno, se consigue una manipulación mejorada. Además de esto, el agente inhibidor de la suciedad, aplicado con el soporte intermedio, se manifiesta como ventajoso también en lo que se refiere a un ensuciamiento renovado del revestimiento tratado. En comparación con el agente conocido, aplicado en una forma líquida mediante rociadura, se consigue un mejorado efecto a largo plazo frente al ensuciamiento renovado.By means of the preparation according to the invention of dirt inhibitor, together with the avoidance of the known damage to the environment, improved handling is achieved. In addition to this, the dirt inhibitor agent, applied with the intermediate support, manifests itself as advantageous also in what it refers to a renewed fouling of the treated coating. In comparison with the known agent, applied in a liquid form by spraying, an improved long-term effect is achieved in front of the renewed fouling.
Por lo demás, mediante la disposición del agente inhibidor de la suciedad y del agente de limpieza junto al material de soporte se garantiza que éstos no se neutralicen sino que permanezcan eficaces para la unión con las fibras de la alfombra (agente inhibidor de la suciedad) o con la suciedad (agente de limpieza).Otherwise, through the agent's disposition dirt inhibitor and cleaning agent next to the material support is guaranteed that these are not neutralized but that remain effective for bonding with carpet fibers (dirt inhibitory agent) or with dirt ( cleaning).
Claims (10)
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10024777 | 2000-05-19 | ||
DE10024777 | 2000-05-19 | ||
DE10032983 | 2000-07-06 | ||
DE10032983 | 2000-07-06 | ||
DE10046685 | 2000-09-21 | ||
DE10046685A DE10046685B4 (en) | 2000-05-19 | 2000-09-21 | Agent for dirt-inhibiting equipment for textile surfaces |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2240272T3 true ES2240272T3 (en) | 2005-10-16 |
Family
ID=27213868
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES01109812T Expired - Lifetime ES2240272T3 (en) | 2000-05-19 | 2001-04-21 | AGENT INTENDED FOR THE INHIBITOR SUPPORT OF THE DIRT FOR TEXTILE SURFACES. |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP1156151B1 (en) |
AT (1) | ATE298378T1 (en) |
ES (1) | ES2240272T3 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005058730A1 (en) | 2005-10-14 | 2007-04-19 | Vorwerk & Co. Interholding Gmbh | A soil repellent finish containing agent |
DE202008007978U1 (en) | 2008-03-19 | 2008-11-20 | Vorwerk & Co. Interholding Gmbh | carpet |
DE102008027573A1 (en) | 2008-03-19 | 2009-09-24 | Greving, Jens, Dr. | Carpet has two backings, where former backing has upper-sided pile fibers, and has dirt-repellent setting made by selecting pile fibers, which is broken through backing enforcing transport channels |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4279796A (en) * | 1980-03-20 | 1981-07-21 | Ann Ward Tarkinson | Carpet cleaning/coating mixture and method |
DE3927975A1 (en) * | 1989-04-13 | 1990-10-18 | Vorwerk Co Interholding | POWDERED DETERGENT |
US5714082A (en) * | 1995-06-02 | 1998-02-03 | Minnesota Mining And Manufacturing Company | Aqueous anti-soiling composition |
JPH09188847A (en) * | 1996-01-08 | 1997-07-22 | Japan Synthetic Rubber Co Ltd | Aqueous dispersion for coating |
-
2001
- 2001-04-21 ES ES01109812T patent/ES2240272T3/en not_active Expired - Lifetime
- 2001-04-21 AT AT01109812T patent/ATE298378T1/en active
- 2001-04-21 EP EP01109812A patent/EP1156151B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ATE298378T1 (en) | 2005-07-15 |
EP1156151B1 (en) | 2005-06-22 |
EP1156151A1 (en) | 2001-11-21 |
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