ES2196805T3 - Proceso para el tratamiento de gases de combustion. - Google Patents

Proceso para el tratamiento de gases de combustion.

Info

Publication number
ES2196805T3
ES2196805T3 ES99921144T ES99921144T ES2196805T3 ES 2196805 T3 ES2196805 T3 ES 2196805T3 ES 99921144 T ES99921144 T ES 99921144T ES 99921144 T ES99921144 T ES 99921144T ES 2196805 T3 ES2196805 T3 ES 2196805T3
Authority
ES
Spain
Prior art keywords
urea
dissolved
ammonia
flue gas
combustion flue
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99921144T
Other languages
English (en)
Inventor
Vincenzo Lagana
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siirtec-Nigi SpA
Original Assignee
Siirtec-Nigi SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11380095&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2196805(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Siirtec-Nigi SpA filed Critical Siirtec-Nigi SpA
Application granted granted Critical
Publication of ES2196805T3 publication Critical patent/ES2196805T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00—Ammonia; Compounds thereof
    • C01C1/02—Preparation, purification or separation of ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B01D53/56—Nitrogen oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00—Ammonia; Compounds thereof
    • C01C1/02—Preparation, purification or separation of ammonia
    • C01C1/08—Preparation of ammonia from nitrogenous organic substances
    • C01C1/086—Preparation of ammonia from nitrogenous organic substances from urea
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2067—Urea

Abstract

En un proceso para el tratamiento de gas de la combustión, en el que se inyecta amoniaco en una corriente de dichos gases de combustión, la mejora consiste en: disolver la urea en agua, formando una solución de urea disuelta; calentar y presurizar dicha solución de urea disuelta, formando una solución de urea disuelta, calentada y presurizada; hidrolizar la urea disuelta en dicha solución de urea disuelta, calentada y presurizada, formando una solución hidrolizada, que contiene amoniaco y dióxido de carbono; extraer dicho amoniaco y dióxido de carbono de la citada solución hidrolizada, poniendo en contacto dicha solución hidrolizada con vapor, lo cual deja tras de si una solución hidrolizada extraída; inyectar dicho amoniaco y dióxido de carbono en una corriente de dicho gas de combustión, y reciclar dicha solución hidrolizada extraída para disolver la citada urea tras haber llevado la presión y la temperatura a valores compatibles con la preparación de disolución de la urea.
ES99921144T 1998-05-25 1999-05-14 Proceso para el tratamiento de gases de combustion. Expired - Lifetime ES2196805T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT98MI001155A ITMI981155A1 (it) 1998-05-25 1998-05-25 Processo per la produzione di ammoniaca mediante idrolisi dell'urea

Publications (1)

Publication Number Publication Date
ES2196805T3 true ES2196805T3 (es) 2003-12-16

Family

ID=11380095

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99921144T Expired - Lifetime ES2196805T3 (es) 1998-05-25 1999-05-14 Proceso para el tratamiento de gases de combustion.

Country Status (17)

Country Link
US (1) US5985224A (es)
EP (1) EP1089804B1 (es)
JP (1) JP2002516169A (es)
KR (1) KR100580930B1 (es)
CN (1) CN1168527C (es)
AT (1) ATE235300T1 (es)
AU (1) AU755072B2 (es)
CA (1) CA2331268C (es)
CZ (1) CZ294281B6 (es)
DE (1) DE69906291D1 (es)
ES (1) ES2196805T3 (es)
HK (1) HK1037986A1 (es)
IT (1) ITMI981155A1 (es)
PL (1) PL194720B1 (es)
RU (1) RU2193442C2 (es)
TR (1) TR200003469T2 (es)
WO (1) WO1999061136A1 (es)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5985222A (en) 1996-11-01 1999-11-16 Noxtech, Inc. Apparatus and method for reducing NOx from exhaust gases produced by industrial processes
US6077491A (en) 1997-03-21 2000-06-20 Ec&C Technologies Methods for the production of ammonia from urea and/or biuret, and uses for NOx and/or particulate matter removal
US6093380A (en) * 1998-10-16 2000-07-25 Siirtec Nigi, S.P.A. Method and apparatus for pollution control in exhaust gas streams from fossil fuel burning facilities
US6511644B1 (en) 2000-08-28 2003-01-28 The Chemithon Corporation Method for removing contaminants in reactors
US6436359B1 (en) * 2000-10-25 2002-08-20 Ec&C Technologies, Inc. Method for controlling the production of ammonia from urea for NOx scrubbing
WO2002043837A1 (en) * 2000-12-01 2002-06-06 Fuel Tech, Inc. Selective catalytic reduction of no, enabled by side stream urea decomposition
US7615200B2 (en) * 2000-12-01 2009-11-10 Fuel Tech, Inc. Selective catalytic reduction of NOx enabled by urea decomposition in heat-exchanger bypass
US7829033B2 (en) * 2003-07-03 2010-11-09 Fuel Tech, Inc. Selective catalytic reduction of NOx enabled by sidestream urea decomposition
US6761868B2 (en) * 2001-05-16 2004-07-13 The Chemithon Corporation Process for quantitatively converting urea to ammonia on demand
JP3820163B2 (ja) 2002-02-22 2006-09-13 三井化学株式会社 尿素濃度測定方法および装置
US7140187B2 (en) * 2002-04-15 2006-11-28 Amendola Steven C Urea based composition and system for same
US20030211024A1 (en) * 2002-05-10 2003-11-13 Wojichowski David Lee Methods of converting urea to ammonia for SCR, SNCR and flue gas conditioning
US6887449B2 (en) * 2002-11-21 2005-05-03 The Chemithon Corporation Method of quantitatively producing ammonia from urea
EP1533018A1 (en) * 2003-11-05 2005-05-25 Urea Casale S.A. Method for the treatment of combustion flue gas
CN101583412A (zh) * 2006-08-22 2009-11-18 巴布科克能源公司 使用再生式热交换器在燃烧烟道气侧流中热分解尿素
US20080267837A1 (en) * 2007-04-27 2008-10-30 Phelps Calvin E Conversion of urea to reactants for NOx reduction
CA2697369A1 (en) * 2007-08-24 2009-03-05 Powerspan Corp Method and apparatus for producing ammonium carbonate from urea
CN100588613C (zh) * 2007-08-24 2010-02-10 中电投远达环保工程有限公司 热解法尿素制氨工艺
US20090148370A1 (en) * 2007-12-06 2009-06-11 Spencer Iii Herbert W Process to produce ammonia from urea
SE532906C2 (sv) * 2008-09-23 2010-05-04 Scania Cv Abp Hydrolyskatalysator med större kanaltvärsnitt i den perifera delen än i den centrala delen samt sätt för hydrolys av ett urinämne
DE102009005677A1 (de) 2009-01-22 2010-08-05 Kruse Gmbh & Co. Kg Verfahren und Vorrichtung zur Herstellung hochreiner Harnstofflösung
US9428449B2 (en) 2013-01-16 2016-08-30 Alstom Technology Ltd Method of forming urea by integration of an ammonia production process in a urea production process and a system therefor
US9586831B2 (en) 2014-06-09 2017-03-07 Wahlco, Inc. Urea to ammonia process
CN104192862B (zh) * 2014-09-23 2016-05-11 东方电气集团东方锅炉股份有限公司 一种利用锅炉气体的尿素水解制氨方法和装置
CN104474892A (zh) * 2014-12-09 2015-04-01 邹英奎 一种脱硝粉的生产方法
CN105116719B (zh) * 2015-07-17 2017-08-25 中国华能集团公司 基于热量前馈信号的尿素水解反应器控制系统和方法
CN105921014A (zh) * 2016-05-10 2016-09-07 南宁市夏阳化工科技有限责任公司 一种车用尿素溶液的制备方法
CN113401921B (zh) * 2021-05-17 2024-03-22 许昌龙岗发电有限责任公司 一种尿素水解制氨系统及其控制方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4087513A (en) * 1977-08-12 1978-05-02 Olin Corporation Method of hydrolyzing urea contained in waste water streams
NL8100989A (nl) * 1981-02-28 1982-09-16 Unie Van Kunstmestfab Bv Werkwijze voor het verwijderen van ureum, ammoniak en kooldioxide uit verdunde waterige oplossingen.
JPH02191528A (ja) * 1989-01-20 1990-07-27 Babcock Hitachi Kk 固体還元剤を用いた脱硝装置
US5240688A (en) * 1990-08-01 1993-08-31 Fuel Tech Gmbh Process for the in-line hydrolysis of urea
JP3100191B2 (ja) * 1991-09-02 2000-10-16 三菱重工業株式会社 排煙脱硝装置
US5279108A (en) * 1992-02-28 1994-01-18 Union Oil Company Of California System for reduction of NOx in jet engine exhaust
WO1994013391A1 (en) * 1992-12-08 1994-06-23 Nalco Fuel Tech Process for improving the performance of an electrostatic precipitator
JP3638638B2 (ja) * 1994-08-24 2005-04-13 バブコック日立株式会社 固体還元剤を用いた脱硝装置
US6077491A (en) * 1997-03-21 2000-06-20 Ec&C Technologies Methods for the production of ammonia from urea and/or biuret, and uses for NOx and/or particulate matter removal

Also Published As

Publication number Publication date
TR200003469T2 (tr) 2001-04-20
HK1037986A1 (en) 2002-03-01
CZ20004394A3 (en) 2001-05-16
CA2331268C (en) 2005-01-11
KR20010043750A (ko) 2001-05-25
PL344405A1 (en) 2001-11-05
ATE235300T1 (de) 2003-04-15
CN1168527C (zh) 2004-09-29
CN1303315A (zh) 2001-07-11
DE69906291D1 (de) 2003-04-30
CA2331268A1 (en) 1999-12-02
CZ294281B6 (cs) 2004-11-10
PL194720B1 (pl) 2007-06-29
WO1999061136A1 (en) 1999-12-02
AU755072B2 (en) 2002-12-05
US5985224A (en) 1999-11-16
JP2002516169A (ja) 2002-06-04
AU3848199A (en) 1999-12-13
KR100580930B1 (ko) 2006-05-17
RU2193442C2 (ru) 2002-11-27
ITMI981155A1 (it) 1999-11-25
EP1089804A1 (en) 2001-04-11
EP1089804B1 (en) 2003-03-26

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