ES2193102T3 - Compuestos de imidocromo en sistemas catalizadores para la polimerizacion de olefinas. - Google Patents

Compuestos de imidocromo en sistemas catalizadores para la polimerizacion de olefinas.

Info

Publication number
ES2193102T3
ES2193102T3 ES00956274T ES00956274T ES2193102T3 ES 2193102 T3 ES2193102 T3 ES 2193102T3 ES 00956274 T ES00956274 T ES 00956274T ES 00956274 T ES00956274 T ES 00956274T ES 2193102 T3 ES2193102 T3 ES 2193102T3
Authority
ES
Spain
Prior art keywords
compounds
olefin polymerization
imidocrome
catalyst systems
imidochrome
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES00956274T
Other languages
English (en)
Inventor
Markus Schopf
Joerg Sundermeyer
Jennifer Kipke
Konstantin A Rufanov
Walter Heitz
Uwe Peucker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Application granted granted Critical
Publication of ES2193102T3 publication Critical patent/ES2193102T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic System
    • C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic System compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms

Abstract

Sistemas catalizadores que contienen: (A) al menos un compuesto de imidocromo, obtenible mediante un procedimiento que comprende los siguientes pasos de procedimiento: (a) puesta en contacto de un compuesto de dioxocromo con un compuesto de N-sulfinilo R1-N=S=O o R2-N=S=O, donde las variables tienen el siguiente significado: R1 alquilo con 1 a 20 átomos de carbono, alquenilo con 2 a 20 átomos de carbono, arilo con 6 a 20 átomos de carbono, alquilarilo con 1 a 10 átomos de carbono en el resto alquilo y 6 a 20 átomos de carbono en el resto arilo, pudiendo portar el resto orgánico R1 también substituyentes inertes, SiR33, R2 R3C=NR4, R3C=O, R3C=O (OR4), R3C=S, (R3)2P=O, (OR3)2P=O, SO2R3,R3R4C=N, NR3R4 o BR3R4,R3,R4, independientemente entre sí, alquilo con 1 a 20 átomos de carbono, alquenilo con 2 a 20 átomos de carbono, arilo con 6 a 20 átomos de carbono, alquilarilo con 1 a 10 átomos de carbono en el resto alquilo y 6 a 20 átomos de carbono en el resto arilo, hidrógeno, si éste está unido aun átomo de carbono, pudiendo portar los restos orgánicos R3 y R4 también substituyentes inertes, (b) puesta en contacto del producto de reacción obtenido de este modo con cloro, si se empleó un compuesto de sulfinilo R1-N=S=O, y, en caso de emplear un compuesto de N-sulfinilo R2-N=S=O,, con cloro o cloruro de sulfurilo, o con ningún otro reactivo, (B) al menos un compuesto activador, y (C) en caso dado uno o varios catalizadores adicionales habituales para la polimerización de olefinas.
ES00956274T 1999-08-02 2000-07-25 Compuestos de imidocromo en sistemas catalizadores para la polimerizacion de olefinas. Expired - Lifetime ES2193102T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19935592A DE19935592A1 (de) 1999-08-02 1999-08-02 Imidochromverbindungen in Katalysatorsystemen für die Olefinpolymerisation

Publications (1)

Publication Number Publication Date
ES2193102T3 true ES2193102T3 (es) 2003-11-01

Family

ID=7916445

Family Applications (1)

Application Number Title Priority Date Filing Date
ES00956274T Expired - Lifetime ES2193102T3 (es) 1999-08-02 2000-07-25 Compuestos de imidocromo en sistemas catalizadores para la polimerizacion de olefinas.

Country Status (8)

Country Link
US (2) US6784261B1 (es)
EP (1) EP1200453B1 (es)
JP (1) JP2003506494A (es)
AT (1) ATE232878T1 (es)
AU (1) AU6828000A (es)
DE (2) DE19935592A1 (es)
ES (1) ES2193102T3 (es)
WO (1) WO2001009148A1 (es)

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DE10028432A1 (de) 2000-06-13 2001-12-20 Basell Polyolefine Gmbh Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation
KR100914423B1 (ko) * 2001-09-14 2009-08-27 바젤 폴리올레핀 게엠베하 올레핀의 중합 방법
DE10145453A1 (de) 2001-09-14 2003-06-05 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus
JP2005538245A (ja) 2002-07-15 2005-12-15 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 担体を有する触媒組成物の製造方法
WO2004007569A1 (en) * 2002-07-15 2004-01-22 Basell Polyolefine Gmbh Preparation of catalyst systems
US20060089253A1 (en) * 2002-08-13 2006-04-27 Shahram Mihan Monocyclopentadienyl complexes
WO2004018489A1 (en) 2002-08-22 2004-03-04 Basell Polyolefine Gmbh Monocyclopentadienyl complexes
EP1569968B1 (en) 2002-11-04 2010-03-17 Basell Polyolefine GmbH Preparation of catalyst compositions having improved activity
WO2004056481A1 (en) 2002-12-20 2004-07-08 Basell Polyolefine Gmbh Monocyclopentadienyl complexes
DE10314992A1 (de) * 2003-04-02 2004-10-14 Celanese Ventures Gmbh Übergangsmetall-Katalysatoren, Verfahren zur Herstellung von diesen und deren Verwendung zur Homo- und Copolymerisation von Vinylestern; Poly(vinylester), Poly(vinylalkohole); Poly(vinylester)- Copolymere, Poly(vinylalkol)-Copolymere
ATE364641T1 (de) 2003-04-03 2007-07-15 Basell Polyolefine Gmbh Herstellung von hochmolekularen polyolefinen in gegenwart einer organischen übergangsmetallverbindung in einem gasphasen- wirbelschichtreaktor
JP2006528951A (ja) 2003-05-21 2006-12-28 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 三座の窒素含有リガンドを有する遷移金属錯体
WO2005058928A1 (en) * 2003-12-16 2005-06-30 Basell Polyolefine Gmbh Monocyclopentadienyl complexes
US7629464B2 (en) 2003-12-19 2009-12-08 Basell Polyolefine Gmbh Monocyclopentadienyl complexes
KR20060118564A (ko) * 2003-12-23 2006-11-23 바젤 폴리올레핀 게엠베하 올레핀 중합용 촉매계
CN100528914C (zh) 2003-12-23 2009-08-19 巴塞尔聚烯烃股份有限公司 负载型助催化剂的制备
DE102004020524A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
DE102004020525A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Katalysatorsystem zur Olefinpolymerisation, dessen Herstellung und Verwendung
DE102004039877A1 (de) 2004-08-17 2006-02-23 Basell Polyolefine Gmbh Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6
DE102004061618A1 (de) * 2004-12-17 2006-06-22 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
DE102005014395A1 (de) * 2005-03-24 2006-09-28 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
DE102005035477A1 (de) 2005-07-26 2007-02-01 Basell Polyolefine Gmbh Verfahren zur Steuerung der relativen Aktivität der unterschiedlichen aktiven Zentren von Hybridkatalysatoren
DE102005056775A1 (de) * 2005-11-28 2007-05-31 Basell Polyolefine Gmbh Verfahren für den Katalysatorwechsel in einem Gasphasenwirbelschichtreaktor
DE102007017903A1 (de) 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung

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Also Published As

Publication number Publication date
DE50001295D1 (de) 2003-03-27
EP1200453B1 (de) 2003-02-19
US20040214970A1 (en) 2004-10-28
WO2001009148A1 (de) 2001-02-08
US7045644B2 (en) 2006-05-16
US6784261B1 (en) 2004-08-31
JP2003506494A (ja) 2003-02-18
DE19935592A1 (de) 2001-02-08
EP1200453A1 (de) 2002-05-02
AU6828000A (en) 2001-02-19
ATE232878T1 (de) 2003-03-15

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