ES2191745T3 - Procedimiento de preparacion de 6-ester de sacarosa. - Google Patents

Procedimiento de preparacion de 6-ester de sacarosa.

Info

Publication number
ES2191745T3
ES2191745T3 ES96308584T ES96308584T ES2191745T3 ES 2191745 T3 ES2191745 T3 ES 2191745T3 ES 96308584 T ES96308584 T ES 96308584T ES 96308584 T ES96308584 T ES 96308584T ES 2191745 T3 ES2191745 T3 ES 2191745T3
Authority
ES
Spain
Prior art keywords
reaction mixture
codistillation
sucrose
water
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96308584T
Other languages
English (en)
Inventor
James A White
Billy A Bradford
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson and Johnson Consumer Inc
Original Assignee
McNeil PPC Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by McNeil PPC Inc filed Critical McNeil PPC Inc
Application granted granted Critical
Publication of ES2191745T3 publication Critical patent/ES2191745T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
    • C07H13/02—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids
    • C07H13/04—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids having the esterifying carboxyl radicals attached to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
    • C07H13/02—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids
    • C07H13/04—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids having the esterifying carboxyl radicals attached to acyclic carbon atoms
    • C07H13/06—Fatty acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
    • C07H13/02—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids
    • C07H13/08—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids having the esterifying carboxyl radicals directly attached to carbocyclic rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Saccharide Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Silicon Polymers (AREA)

Abstract

SE DESCRIBE UN PROCEDIMIENTO QUE COMPRENDE HACER PASAR VAPORES DE UN DISOLVENTE CAPAZ DE ELIMINAR AGUA POR CODESTILACION, A TRAVES DE UNA MEZCLA DE REACCION QUE CONTIENE: (A) UN DISOLVENTE APROTICO, APOLAR Y (B) SUCROSA Y UN 1,3-DI-ACILOXI-1,1,3,3-TETRA(HIDROCARBIL)DIESTANNOXANO Y/O EL PRODUCTO DE REACCION DE SUCROSA Y UN 1,3-DIACILOXI-1,1,3,3-TETRA(HIDROCARBIL)DIESTANNOXANO, EN CANTIDAD SUFICIENTE Y DURANTE UN PERIODO DE TIEMPO SUFICIENTE PARA ELIMINAR SUSTANCIALMENTE TODO EL AGUA DE DICHA MEZCLA DE REACCION, POR CODESTILACION. EN UNA REALIZACION CONCRETA DE LA INVENCION, SE DESCRIBE UN PROCEDIMIENTO QUE COMPRENDE: (1) PREPARAR UNA PRIMERA MEZCLA DE REACCION QUE COMPRENDE SUCROSA Y UN DISOLVENTE APROTICO POLAR, Y, OPCIONALMENTE, CALENTAR DICHA PRIMERA MEZCLA HACIENDO PASAR VAPORES DE UN SEGUNDO DISOLVENTE, CAPAZ DE ELIMINAR AGUA POR CODESTILACION, A TRAVES DE LA MEZCLA CITADA; (2) AÑADIR UN 1,3-DIACILOXI-1,1,3,3TETRA(HIDROCARBIL)DIESTANNOXANO, A DICHA MEZCLA DE REACCION, PARA FORMAR UNA SEGUNDA MEZCLA DE REACCION; (3) PASAR LOS VAPORES DE UN SEGUNDO DISOLVENTE, CAPAZ DE ELIMINAR AGUA POR CODESTILACION, A TRAVES DE DICHA SEGUNDA MEZCLA DE REACCION, EN CANTIDAD SUFICIENTE Y DURANTE UN PERIODO DE TIEMPO SUFICIENTE, PARA ELIMINAR SUSTANCIALMENTE TODO EL AGUA DE DICHA MEZCLA DE REACCION POR CODESTILACION, FORMANDOSE POR TANTO UNA TERCERA MEZCLA DE REACCION, QUE COMPRENDE DICHO DISOLVENTE APROTICO POLAR, Y DICHO SEGUNDO DISOLVENTE, ESTANDO DICHA SEGUNDA MEZCLA DE REACCION, SUSTANCIALMENTE DESPROVISTA DE AGUA, Y; (4) AÑADIR UN ANHIDRIDO DE ACIDO CARBOXILICO A DICHA TERCERA MEZCLA DE REACCION, PARA FORMAR UNA CUARTA MEZCLA DE REACCION, Y MANTENER DICHA CUARTA MEZCLA DE REACCION A UNA TEMPERATURA Y DURANTE UN PERIODO DE TIEMPO SUFICIENTE PARA PRODUCIR SUCROSA-6ESTER.
ES96308584T 1995-11-28 1996-11-27 Procedimiento de preparacion de 6-ester de sacarosa. Expired - Lifetime ES2191745T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US766095P 1995-11-28 1995-11-28

Publications (1)

Publication Number Publication Date
ES2191745T3 true ES2191745T3 (es) 2003-09-16

Family

ID=21727452

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96308584T Expired - Lifetime ES2191745T3 (es) 1995-11-28 1996-11-27 Procedimiento de preparacion de 6-ester de sacarosa.

Country Status (9)

Country Link
EP (1) EP0776903B1 (es)
JP (1) JP4168168B2 (es)
AT (1) ATE231876T1 (es)
CA (1) CA2191412C (es)
DE (1) DE69625989T2 (es)
DK (1) DK0776903T3 (es)
ES (1) ES2191745T3 (es)
NO (1) NO307381B1 (es)
RU (1) RU2159773C2 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2365424B (en) * 2000-07-31 2002-06-26 Tate & Lyle Plc An improved method for the synthesis of sucrose-6-esters
CN100418976C (zh) 2006-04-03 2008-09-17 广州科宏食品添加物有限公司 一种三氯蔗糖的制备方法
GB0702854D0 (en) * 2007-01-09 2007-03-28 Tate & Lyle Plc Method for the synthesis of sucrose-6-esters
US8476424B2 (en) * 2008-03-20 2013-07-02 Tate & Lyle Technology Limited Removal of acids from tertiary amide solvents
GB2468936B (en) * 2009-03-27 2011-09-07 Mohamad Rami Radwan Jaber Chlorination of sucrose-6-esters
GB2469158B (en) 2009-03-31 2011-09-28 Peter J Seaberg Base-assisted formation of tin-sucrose adducts
GB2474311B (en) 2009-10-12 2012-10-17 Tate & Lyle Technology Ltd Low temperature, single solvent process for the production of sucrose-6-ester
GB2474310B (en) 2009-10-12 2012-02-29 Tate & Lyle Technology Ltd Process for the production of sucrose-6-ester
GB201110520D0 (en) 2011-05-10 2011-08-03 Tate & Lyle Technology Ltd Extraction of carboxylic acids with tin compounds
CN105111246B (zh) * 2015-08-22 2017-11-17 安徽金禾实业股份有限公司 三氯蔗糖生产中有机锡的回收方法
CN106349300B (zh) * 2016-08-30 2019-02-26 安徽金禾实业股份有限公司 三氯蔗糖酯化单溶剂反应方法
CN112480164A (zh) * 2020-12-11 2021-03-12 安徽金禾实业股份有限公司 一种蔗糖-6-乙酯生产中回收制备有机锡催化剂的方法
WO2022174382A1 (zh) * 2021-02-19 2022-08-25 安徽金禾实业股份有限公司 蔗糖-6-酯的生产设备及生产方法
US20230294012A1 (en) * 2021-02-19 2023-09-21 Anhui Jinhe Industrial Co., Ltd. Production apparatus and production method of sucrose-6-ester

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6287248A (ja) * 1985-10-11 1987-04-21 Kuraray Co Ltd エステル化触媒
US4950746A (en) 1988-07-18 1990-08-21 Noramco, Inc. Process for synthesizing sucrose derivatives by regioselective reaction
US5089608A (en) 1990-03-23 1992-02-18 Mcneil-Ppc, Inc. Selective 6-acylation of sucrose mediated by cyclic adducts of dialkyltin oxides and diols
US5034551A (en) 1990-04-23 1991-07-23 Noramco, Inc. Process for recovery of organotin esters from reaction mixtures containing the same and re-use of the recovered organotin compounds
US5023329A (en) 1990-04-23 1991-06-11 Noramco, Inc. Sucrose-6-ester production process
GR910100356A (el) 1990-08-27 1992-08-31 Mcneil Ppc Inc Καταλυόμενη μέ?οδος εστέρος-6-σακχαρόζης.
US5470969A (en) 1990-08-27 1995-11-28 Mcneil-Ppc, Inc. Catalyzed sucrose-6-ester process

Also Published As

Publication number Publication date
NO307381B1 (no) 2000-03-27
CA2191412A1 (en) 1997-05-29
EP0776903B1 (en) 2003-01-29
NO965048L (no) 1997-05-29
ATE231876T1 (de) 2003-02-15
EP0776903A1 (en) 1997-06-04
DK0776903T3 (da) 2003-05-12
JPH09309894A (ja) 1997-12-02
NO965048D0 (no) 1996-11-27
CA2191412C (en) 2005-10-11
JP4168168B2 (ja) 2008-10-22
RU2159773C2 (ru) 2000-11-27
DE69625989D1 (de) 2003-03-06
DE69625989T2 (de) 2003-11-13

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