ES2190234T3 - Colorantes reactivos, su obtencion y uso. - Google Patents

Colorantes reactivos, su obtencion y uso.

Info

Publication number
ES2190234T3
ES2190234T3 ES99936477T ES99936477T ES2190234T3 ES 2190234 T3 ES2190234 T3 ES 2190234T3 ES 99936477 T ES99936477 T ES 99936477T ES 99936477 T ES99936477 T ES 99936477T ES 2190234 T3 ES2190234 T3 ES 2190234T3
Authority
ES
Spain
Prior art keywords
fiber
reactive group
beta
sulfatoethylsulfonyl
obtaining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99936477T
Other languages
English (en)
Inventor
Athanassios Tzikas
Rolf Deitz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Ciba SC Holding AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Application granted granted Critical
Publication of ES2190234T3 publication Critical patent/ES2190234T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/465—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an acryloyl group, a quaternised or non-quaternised aminoalkyl carbonyl group or a (—N)n—CO—A—O—X or (—N)n—CO—A—Hal group, wherein A is an alkylene or alkylidene group, X is hydrogen or an acyl radical of an organic or inorganic acid, Hal is a halogen atom, and n is 0 or 1
    • C09B62/47—Azo dyes
    • C09B62/475—Disazo or polyazo dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/4401—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system
    • C09B62/4403—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system the heterocyclic system being a triazine ring
    • C09B62/4411—Azo dyes
    • C09B62/4415—Disazo or polyazo dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/503—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl or mercaptoalkyl sulfonyl group, a quaternised or non-quaternised aminoalkyl sulfonyl group, a heterylmercapto alkyl sulfonyl group, a vinyl sulfonyl or a substituted vinyl sulfonyl group, or a thiophene-dioxide group
    • C09B62/507—Azo dyes
    • C09B62/513—Disazo or polyazo dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
    • C09B67/0046—Mixtures of two or more azo dyes
    • C09B67/0055—Mixtures of two or more disazo dyes
    • C09B67/0057—Mixtures of two or more reactive disazo dyes

Abstract

Compuestos de la fórmula (1) **(Fórmula)** en la que K1 y K2 en cada caso con independencia entre sí significan un resto de la fórmula **(Fórmula)** en las que (R4)0-3 significa de 0 a 3 restos iguales o distintos, elegidos entre alquilo C1-C4; alcoxi C1-C4; alcoxi C1-C4 sustituido en la parte alquilo por hidroxi, alcoxi C1-C4 o sulfato; halógeno; carboxi; hidroxi; amino; Nmono- o N, N-di-(alquil C1-C2)amino; alcanoilamino C2-C4; ureido, sulfo; (alquil C1-C4)sulfonilo; (alquil C1-C4)sulfonilamino y el resto reactivo de la fórmula (2e) **(Fórmula)** en la que X significa halógeno, 3-carboxipiridin-1-ilo o 3-carbamoilpiridin-1-ilo, T, con independencia de su aparición, tiene el significado de X o significa hidroxi, alcoxi C1-C4, fenoxi, alquiltio C1-C4, morfolino, amino eventualmente sustituido por restos no reactivos con las fibras o un resto reactivo con las fibras de las fórmulas (3a), (3b), (3c), (3d), (3e) o (3f) **(Fórmula)** R1 y R1alpha con independencia entre sí significan en cada caso hidrógeno o alquilo C1-C4, R2 significa hidrógeno; alquilo C1-C4 eventualmente sustituido por hidroxi, sulfo, sulfato, carboxi o ciano; o un resto -alk(R3)-SO2-Y, R3 significa hidrógeno, hidroxi, sulfo, sulfato, carboxi, ciano, halógeno, (alcoxi C1-C4)carbonilo, alcanoiloxi C1-C4, carbamoílo o el grupo -SO2-Y, alk y alk1, con independencia entre sí, significan alquileno C1-C6, ¿arylen¿ significa un resto fenileno o naftileno sin sustituir o sustituido por sulfo, carboxi, alquilo C1-C4, alcoxi C1-C4 o halógeno, Y1 significa un grupo -CH(Hal)-CH2-Hal o -C(Hal)=CH2 y Hal significa cloro o bromo, Q es un resto -O- o -NR1-, en el que R1 tiene el significado definido anteriormente, W es un grupo -SO2-NR2-, -CONR2- o -NR2CO-, m es el número 0 ó 1 e Y significa vinilo o un resto -CH2-CH2-U y U significa un grupo eliminable en medio básico, (R4alpha)0-2 significa de 0 a 2 restos iguales o distintos, elegidos entre alquilo C1-C4, alcoxi C1-C4, fenoxi, halógeno, sulfo e hidroxi; R5 significa hidrógeno o alquilo C1-C4, R5a con independencia de su aparición tiene el significado de R5 o bien significa alcanoílo C2-C4, hidroxialquilo C1-C4, sulfatoalquilo C1-C4, (alcoxi C1-C4)-alquilo o fenilo eventualmente sustituido por metilo, metoxi, cloro o sulfo; R6 significa hidrógeno, alquilo C1-C4 o fenilo; (R7)0-2 significa de 0 a 2 sustituyentes iguales o distintos, elegidos entre hidroxi y el resto reactivo con las fibras de la fórmula (2a) -SO2-Y (2a) en el que Y tiene el significado definido anteriormente, R8 significa hidrógeno o alquilo C1-C4 eventualmente sustituido por hidroxi, alcoxi C1-C4, sulfato, sulfo, halógeno o ciano; R9 con independencia de su aparición tiene el mismo significado que R8 o es alcanoílo C2-C4 o benzoílo, o bien -NR8R9 significa un resto reactivo con las fibras de la fórmula (2e) indicada anteriormente; R10 y R10alpha con independencia entre sí significan en cada caso carbamoílo, sulfometilo o ciano; R11 significa hidrógeno o alquilo C1-C4, que está eventualmente sustituido por un resto de la fórmula (2e) ya definida anteriormente; R12 y R13 con independencia entre sí significan en cada caso hidrógeno o alquilo C1-C12 eventualmente sustituido por hidroxi, alcoxi C1-C4, fenoxi, sulfato, sulfo, carboxi, amino o N-mono- o N, N-di-(alquil C1-C4)amino (que a su vez puede estar sustituido en la parte alquilo por hidroxi, alcoxi C1-C4, fenoxi, sulfato, sulfo, carboxi o un resto reactivo con las fibras de la fórmula (2e) indicada anteriormente) y/o eventualmente interrumpido por -O-, excepto en el caso del metilo; R14 significa metilo o carboxi; R15 significa hidroxi o amino; (R16)0-3 significa de 0 a 3 restos iguales o distintos, elegidos entre sulfo, halógeno, hidroxi, alcoxi C1-C4 y alquilo C1-C4; (R17)0-2 significa de 0 a 2 restos iguales o distintos, elegidos entre alquilo C1-C4, alcoxi C1-C4, alcoxi C1-C4 que está sustituido en la parte alquilo por hidroxi, alcoxi C1-C4 o sulfato; alcanoilamino C2-C4, ureido, halógeno y sulfo; K significa un resto de las fórmulas (4a), (4b), (4c), (4d), (4e), (4f), (4g) o (4h) o (4j), (4k) o (4l) indicadas anteriormente y con preferencia un resto de la fórmula (4e); D significa un resto fenilo o 1- o 2-naftilo que lleva de 1 a 3 restos iguales o distintos, elegidos entre sulfo, alquilo C1-C4, alcoxi C1-C4, halógeno y un resto reactivo con las fibras de las fórmulas (2a), (2b), (2c) o (2d) -SO2-Y (2a), -CONR2-(CH2)n-SO2-Y (2b), -NH-CO-CH(Hal)-CH2-Hal (2c) o -NH-CO-C(Hal)=CH2 (2d) en las que n significa un número entero de 1 a 6 y R2, Hal e Y tienen los significados definidos anteriormente; Da es el resto de un cromóforo monoazoico o diazoico; y X e Y tienen en cada caso el significado definido antes; pero por lo menos uno de los restos K1 y K2 lleva un grupo reactivo con las fibras.
ES99936477T 1998-07-13 1999-07-05 Colorantes reactivos, su obtencion y uso. Expired - Lifetime ES2190234T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP98810659 1998-07-13

Publications (1)

Publication Number Publication Date
ES2190234T3 true ES2190234T3 (es) 2003-07-16

Family

ID=8236188

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99936477T Expired - Lifetime ES2190234T3 (es) 1998-07-13 1999-07-05 Colorantes reactivos, su obtencion y uso.

Country Status (8)

Country Link
US (1) US6518408B1 (es)
EP (1) EP1095105B1 (es)
JP (1) JP2003518141A (es)
AT (1) ATE231903T1 (es)
AU (1) AU5156499A (es)
DE (1) DE59904172D1 (es)
ES (1) ES2190234T3 (es)
WO (1) WO2000004099A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4641194B2 (ja) * 2005-02-01 2011-03-02 日本化薬株式会社 アゾ化合物、インク組成物、記録方法及び着色体
JP6198349B2 (ja) * 2013-08-01 2017-09-20 日本化薬株式会社 黒色用トリスアゾ化合物、それを含む黒色用染料組成物およびその使用

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2807260C2 (de) 1978-02-21 1986-10-09 Hoechst Ag, 6230 Frankfurt Wasserlösliche Farbstoffe, Verfahren zu deren Herstellung, ihre Verwendung als faserreaktive Farbstoffe zum Färben und Bedrucken von Fasermaterialien
TW225549B (es) 1992-04-14 1994-06-21 Bayer Ag
DE4309554A1 (de) 1993-03-24 1994-09-29 Bayer Ag Faserreaktive Azofarbstoffe

Also Published As

Publication number Publication date
EP1095105A1 (de) 2001-05-02
WO2000004099A1 (de) 2000-01-27
ATE231903T1 (de) 2003-02-15
DE59904172D1 (de) 2003-03-06
US6518408B1 (en) 2003-02-11
AU5156499A (en) 2000-02-07
JP2003518141A (ja) 2003-06-03
EP1095105B1 (de) 2003-01-29

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