ES2166372T3 - Reactivo de desalilacion y procedimiento de desalilacion que utiliza dicho reactivo. - Google Patents

Reactivo de desalilacion y procedimiento de desalilacion que utiliza dicho reactivo.

Info

Publication number
ES2166372T3
ES2166372T3 ES94913152T ES94913152T ES2166372T3 ES 2166372 T3 ES2166372 T3 ES 2166372T3 ES 94913152 T ES94913152 T ES 94913152T ES 94913152 T ES94913152 T ES 94913152T ES 2166372 T3 ES2166372 T3 ES 2166372T3
Authority
ES
Spain
Prior art keywords
reagent
pct
dealilation
solvent system
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94913152T
Other languages
English (en)
Inventor
Jean-Marie Bernard
Errol Blart
Jean-Pierre Genet
Sandrine Lemaire-Audoire
Monique Savignac
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhodia Chimie SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Chimie SAS filed Critical Rhodia Chimie SAS
Application granted granted Critical
Publication of ES2166372T3 publication Critical patent/ES2166372T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/08—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms
    • C07D295/084—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
    • C07D295/088—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/62—Preparation of compounds containing amino groups bound to a carbon skeleton by cleaving carbon-to-nitrogen, sulfur-to-nitrogen, or phosphorus-to-nitrogen bonds, e.g. hydrolysis of amides, N-dealkylation of amines or quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/08—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions not involving the formation of amino groups, hydroxy groups or etherified or esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/14—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from compounds containing already amino and carboxyl groups or derivatives thereof
    • C07C227/18—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from compounds containing already amino and carboxyl groups or derivatives thereof by reactions involving amino or carboxyl groups, e.g. hydrolysis of esters or amides, by formation of halides, salts or esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/04—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D207/10—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/16—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/40—Oxygen atoms
    • C07D211/44—Oxygen atoms attached in position 4
    • C07D211/52—Oxygen atoms attached in position 4 having an aryl radical as the second substituent in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/60—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D211/62—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals attached in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07K—PEPTIDES
    • C07K1/00—General methods for the preparation of peptides, i.e. processes for the organic chemical preparation of peptides or proteins of any length
    • C07K1/06—General methods for the preparation of peptides, i.e. processes for the organic chemical preparation of peptides or proteins of any length using protecting groups or activating agents
    • C07K1/061—General methods for the preparation of peptides, i.e. processes for the organic chemical preparation of peptides or proteins of any length using protecting groups or activating agents using protecting groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07K—PEPTIDES
    • C07K1/00—General methods for the preparation of peptides, i.e. processes for the organic chemical preparation of peptides or proteins of any length
    • C07K1/12—General methods for the preparation of peptides, i.e. processes for the organic chemical preparation of peptides or proteins of any length by hydrolysis, i.e. solvolysis in general
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Biophysics (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Analytical Chemistry (AREA)
  • Molecular Biology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Saccharide Compounds (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Catalysts (AREA)

Abstract

LA PRESENTE INVENCION SE REFIERE A UN REACTIVO UTIL PARA PARTIR UNA FUNCION PROTEGIDA, CON OCASION DE UNA SINTESIS ORGANICA POR UN GRUPO ALILO, ESTE REACTIVO SE DEFINE EN QUE COMPRENDE: A) UN SISTEMA DE SOLVENTE(S); B) UN CATALIZADOR QUE COMPRENDE AL MENOS UN ELEMENTO DE LA COLUMNA VIII DE LA CLASIFICACION PERIODICA DE LOS ELEMENTOS, ESTANDO DICHO ELEMENTO DE LA COLUMNA VIII DE LA CLASIFICACION PERIODICA COORDINADO POR AL MENOS UN AGENTE DE COORDINACION SOLUBLE EN DICHO SISTEMA DE SOLVENTE(S); C) UN COMPUESTO SOLUBLE AL MENOS PARCIALMENTE EN DICHO SISTEMA DE SOLVENTE(S) Y QUE LLEVA AL MENOS UNA FUNCION NUCLEOFILA. APLICACION ORGANICA.
ES94913152T 1993-04-09 1994-04-08 Reactivo de desalilacion y procedimiento de desalilacion que utiliza dicho reactivo. Expired - Lifetime ES2166372T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9304233A FR2703688B1 (fr) 1993-04-09 1993-04-09 Réactif de désallylation, procédé de désallylation utilisant ledit réactif.

Publications (1)

Publication Number Publication Date
ES2166372T3 true ES2166372T3 (es) 2002-04-16

Family

ID=9445928

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94913152T Expired - Lifetime ES2166372T3 (es) 1993-04-09 1994-04-08 Reactivo de desalilacion y procedimiento de desalilacion que utiliza dicho reactivo.

Country Status (16)

Country Link
US (1) US5773617A (es)
EP (1) EP0693052B1 (es)
JP (1) JP3657605B2 (es)
KR (1) KR100340613B1 (es)
CN (1) CN1160308C (es)
AT (1) ATE211725T1 (es)
AU (1) AU697811B2 (es)
BR (1) BR9406137A (es)
CA (1) CA2160163A1 (es)
DE (1) DE69429616T2 (es)
ES (1) ES2166372T3 (es)
FI (1) FI954765A (es)
FR (1) FR2703688B1 (es)
HU (1) HU218397B (es)
NO (1) NO953976L (es)
WO (1) WO1994024088A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1044962A4 (en) * 1997-11-11 2004-03-24 Chisso Corp NOVEL PROCESS FOR CATALYTIC REMOVAL OF PROTECTIVE GROUP USING AN ALLYL GROUP
WO2006040182A1 (en) 2004-10-14 2006-04-20 Abbott Gmbh & Co. Kg Heterocyclic compounds suitable for treating disorders that respond to modulation of the dopamine d3 receptor
EP1807392A1 (en) 2004-10-14 2007-07-18 Abbott GmbH & Co. KG 6-amino(aza)indane compounds suitable for treating disorders that respond to modulation of the dopamine d3 recptor
JP4833989B2 (ja) 2004-10-14 2011-12-07 アボット ゲーエムベーハー ウント カンパニー カーゲー ドーパミンｄ３受容体の調節に応答する障害の治療に好適なアミノエチル芳香族化合物
BR112013011533A2 (pt) * 2010-11-12 2016-08-09 Bayer Ip Gmbh processo para a preparação de 2, 2 - difluoroetilamina a partir de prop-2-en-1-amina

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0194554B1 (en) * 1985-03-06 1993-09-01 Nippon Zeon Co., Ltd. Process for production of oxime derivatives
JPH0662471B2 (ja) * 1985-09-20 1994-08-17 三井石油化学工業株式会社 ２，６−ジヒドロキシナフタレンの製造方法
JPS6270392A (ja) * 1985-09-25 1987-03-31 Nippon Zeon Co Ltd オリゴヌクレオチド化合物の製造法
FR2652514A1 (fr) * 1989-06-22 1991-04-05 Rhone Poulenc Sante Nouveau catalyseur a base de palladium et son emploi.
FR2675804B1 (fr) * 1991-04-25 1995-04-07 Propeptide Sa Procede de synthese de peptides, nouveaux derives d'acides amines mis en óoeuvre dans ce procede et leurs procedes de preparation.
EP0518295A3 (en) * 1991-06-14 1993-09-01 Millipore Corporation Allyl side chain protection in peptide synthesis
FR2690153A1 (fr) * 1992-04-15 1993-10-22 Rhone Poulenc Chimie Réactif et procédé catalytique utile pour cliver une fonction protégée.

Also Published As

Publication number Publication date
KR100340613B1 (ko) 2003-02-11
FI954765A (fi) 1995-12-05
FR2703688A1 (fr) 1994-10-14
EP0693052A1 (fr) 1996-01-24
WO1994024088A1 (fr) 1994-10-27
NO953976L (no) 1995-12-08
DE69429616T2 (de) 2002-08-14
FI954765A0 (fi) 1995-10-06
AU697811B2 (en) 1998-10-15
US5773617A (en) 1998-06-30
JPH08508986A (ja) 1996-09-24
ATE211725T1 (de) 2002-01-15
HU218397B (hu) 2000-08-28
HU9502942D0 (en) 1995-12-28
DE69429616D1 (de) 2002-02-14
HUT76715A (en) 1997-10-28
EP0693052B1 (fr) 2002-01-09
JP3657605B2 (ja) 2005-06-08
NO953976D0 (no) 1995-10-06
BR9406137A (pt) 1996-02-27
FR2703688B1 (fr) 1995-05-19
CN1122594A (zh) 1996-05-15
CA2160163A1 (fr) 1994-10-27
AU6541094A (en) 1994-11-08
CN1160308C (zh) 2004-08-04

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