ES2164379T3 - Procedimiento para la obtencion de compuestos carbonilicos. - Google Patents

Procedimiento para la obtencion de compuestos carbonilicos.

Info

Publication number
ES2164379T3
ES2164379T3 ES97953759T ES97953759T ES2164379T3 ES 2164379 T3 ES2164379 T3 ES 2164379T3 ES 97953759 T ES97953759 T ES 97953759T ES 97953759 T ES97953759 T ES 97953759T ES 2164379 T3 ES2164379 T3 ES 2164379T3
Authority
ES
Spain
Prior art keywords
radical
formula
atom
hydrogen atom
atomos
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97953759T
Other languages
English (en)
Inventor
Thomas Fetzer
Dirk Demuth
Heinz Rutter
Helmuth Menig
Peter Resch
Wilhelm Ruppel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2164379T3 publication Critical patent/ES2164379T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/39Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/38Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

EL OBJETO DE LA PRESENTE INVENCION ES UN PROCEDIMIENTO PARA LA PREPARACION DE COMPUESTOS DE CARBONILO DE FORMULA (I), EN LA QUE R 1 ES UN ATOMO DE HIDROGENO O UN RADICAL ALQUILO CON 1 A 3 ATOMOS DE C, R 2 ES UN ATOMO DE HIDROGENO O UN RADICAL DE FORMULA (II), EN LA QUE R 3 ES UN ATOMO DE HIDROGENO O FORMA JUNTO CON R 4 UN ATOMO DE OXIGENO, R 4 ES EL RADICAL OR 6 , O JUNTO CON R 3 ES UN ATOMO DE OXIGENO,, R 5 ES UN ATOMO DE HIDROGENO, UN RADICAL ALQUILO CON 1 A 8 ATOMOS DE C, O UN RADICAL DE CICLOHEXILO O DE CICLOPENTILO, Y R 6 ES UN RADICAL ALQUILO CON 1 A 4 ATOMOS DE C, UN RADICAL DE CICLOHEXILO O DE CICLOPENTILO, O UN RADICAL DE FORMULA - CH 2 - CHO, O CH 2 - CH 2 - O - CH SUB,2 - CHO, MEDIANTE OXIDACION EN FASE GASEOSA DE METANOL O ALCOHOLES DE FORMULA (III), EN LA QUE R 1 Y R 5 TIENEN LOS SIGNIFICADOS ANTES INDICADOS, Y R 7 ES UN ATOMO DE HIDROGENO O UN RADICAL OR 8 , Y R 8 ES UN ATOMO DE HID ROGENO, UN RADICAL ALQUILO CON 1 A 4 ATOMOS DE C, UN RADICAL DE CICLOHEXILO O DE CICLOPENTILO,O UN RADICAL DE FORMULA CH SUB,2 - CH 2 - OH, O - CH 2 - CH 2 - O CH 2 - CH 2 - OH, CON UN GAS QUE CONTIENE OXIGENO Y EN PRESENCIA DE CATALIZADORES QUE CONTIENEN COBRE Y/O PLATA, Y CON UN COMPUESTO DE FOSFORO QUE SE EVAPORA EN LAS CONDICIONES DE LA REACCION EN UNA CANTIDAD TAL, QUE LA CANTIDAD DE FOSFORO (CALCULADA COMO P), CON RELACION A LA CANTIDAD EN PESO DEL ALCOHOL UTILIZADO, ES HASTA 20 PPM, CARACTERIZADO PORQUE LA CANTIDAD DE FOSFORO SE AÑADE EN AL MENOS DOS PARTES, ESTANDO A) LA PRIMERA PARTE AÑADIDA CON LA MEZCLA GASEOSA DE PARTIDA DE LA CARGA CATALITICA, Y B) AÑADIENDOSE OTRA PARTE DENTRO DE LA CARGA DEL CATALIZADOR.
ES97953759T 1996-12-23 1997-12-09 Procedimiento para la obtencion de compuestos carbonilicos. Expired - Lifetime ES2164379T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19654046A DE19654046A1 (de) 1996-12-23 1996-12-23 Verfahren zur Herstellung von Carbonylverbindungen

Publications (1)

Publication Number Publication Date
ES2164379T3 true ES2164379T3 (es) 2002-02-16

Family

ID=7816031

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97953759T Expired - Lifetime ES2164379T3 (es) 1996-12-23 1997-12-09 Procedimiento para la obtencion de compuestos carbonilicos.

Country Status (10)

Country Link
US (1) US6072087A (es)
EP (1) EP0946479B1 (es)
JP (1) JP2001506999A (es)
KR (1) KR20000062282A (es)
CN (1) CN1238750A (es)
CA (1) CA2274489A1 (es)
DE (2) DE19654046A1 (es)
ES (1) ES2164379T3 (es)
TW (1) TW430644B (es)
WO (1) WO1998028250A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19811288A1 (de) * 1998-03-16 1999-09-23 Basf Ag Verfahren zur Herstellung von Carbonylverbindungen
US7754175B2 (en) * 2007-08-29 2010-07-13 Dynamic Engineering, Inc. Silicon and catalyst material preparation in a process for producing trichlorosilane
CN114853604B (zh) * 2022-04-06 2023-05-30 万华化学集团股份有限公司 一种五碳醛的制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2832405A1 (de) * 1978-07-24 1980-02-14 Basf Ag Verfahren zur herstellung von glyoxal aus aethylenglykol
US4503261A (en) * 1982-07-22 1985-03-05 Basf Aktiengesellschaft Preparation of glyoxal
WO1984000955A1 (en) * 1982-08-30 1984-03-15 Mitsui Toatsu Chemicals Process for producing glyoxal
DE3643469A1 (de) * 1986-12-19 1988-06-30 Basf Ag Verfahren zur herstellung von carbonylverbindungen

Also Published As

Publication number Publication date
US6072087A (en) 2000-06-06
TW430644B (en) 2001-04-21
WO1998028250A1 (de) 1998-07-02
DE19654046A1 (de) 1998-06-25
EP0946479B1 (de) 2001-09-12
DE59704619D1 (de) 2001-10-18
KR20000062282A (ko) 2000-10-25
JP2001506999A (ja) 2001-05-29
EP0946479A1 (de) 1999-10-06
CA2274489A1 (en) 1998-07-02
CN1238750A (zh) 1999-12-15

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