ES2152706T3 - Procedimiento para la obtencion de disoluciones de polimeros dienicos en monomeros aromaticos de vinilo. - Google Patents

Procedimiento para la obtencion de disoluciones de polimeros dienicos en monomeros aromaticos de vinilo.

Info

Publication number
ES2152706T3
ES2152706T3 ES97944765T ES97944765T ES2152706T3 ES 2152706 T3 ES2152706 T3 ES 2152706T3 ES 97944765 T ES97944765 T ES 97944765T ES 97944765 T ES97944765 T ES 97944765T ES 2152706 T3 ES2152706 T3 ES 2152706T3
Authority
ES
Spain
Prior art keywords
aromatic
vinilo
monomeros
procedure
dissolutions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97944765T
Other languages
English (en)
Inventor
Stefan Latsch
Wolfgang Fischer
Hermann Gausepohl
Volker Warzelhan
Christian Schade
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE1996133273 external-priority patent/DE19633273A1/de
Priority claimed from DE1996133272 external-priority patent/DE19633272A1/de
Priority claimed from DE1997121403 external-priority patent/DE19721403A1/de
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2152706T3 publication Critical patent/ES2152706T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/50—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkaline earth metals, zinc, cadmium, mercury, copper or silver

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Silicon Polymers (AREA)

Abstract

PROCEDIMIENTO PARA LA POLIMIERIZACION ANIONICA DE DIENOS O COPOLIMERIZACION DE DIENOS Y MONOMEROS AROMATICOS DE VINILO EN UN MONOMERO AROMATICO DE VINILO O EN UNA MEZCLA DE MONOMEROS PARA DAR HOMOPOLIDIENOS O COPOLIMEROS U HOMOPOLIDIENOS Y COPOLIMEROS MEZCLADOS EN PRESENCIA DE UN ALQUILO O ARILO DE METAL DE UN ELEMENTO AL MENOS DIVALENTE SIN AÑADIR BASES DE LEWIS.
ES97944765T 1996-08-19 1997-08-18 Procedimiento para la obtencion de disoluciones de polimeros dienicos en monomeros aromaticos de vinilo. Expired - Lifetime ES2152706T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE1996133273 DE19633273A1 (de) 1996-08-19 1996-08-19 Verfahren zur anionischen Polymerisation
DE1996133272 DE19633272A1 (de) 1996-08-19 1996-08-19 Verfahren zur anionischen Polymerisation
DE1997121403 DE19721403A1 (de) 1997-05-22 1997-05-22 Verfahren zur Herstellung von Dienpolymerisatlösungen in vinylaromatischen Monomeren

Publications (1)

Publication Number Publication Date
ES2152706T3 true ES2152706T3 (es) 2001-02-01

Family

ID=27216565

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97944765T Expired - Lifetime ES2152706T3 (es) 1996-08-19 1997-08-18 Procedimiento para la obtencion de disoluciones de polimeros dienicos en monomeros aromaticos de vinilo.

Country Status (5)

Country Link
US (1) US6303721B1 (es)
EP (1) EP0918806B1 (es)
DE (1) DE59702613D1 (es)
ES (1) ES2152706T3 (es)
WO (1) WO1998007766A1 (es)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19721400A1 (de) * 1997-05-22 1998-11-26 Basf Ag Verfahren zur Herstellung von Dienpolymerisatlösungen in vinylaromatischen Monomeren
CN1119361C (zh) * 1998-02-07 2003-08-27 巴斯福股份公司 制备抗冲改性的热塑性模塑组合物的工艺
DE19828104A1 (de) * 1998-06-24 1999-12-30 Basf Ag Verfahren zur Herstellung von schlagzäh modifizierten, thermoplastischen Formmassen
DE19806785A1 (de) 1998-02-18 1999-08-19 Basf Ag Verfahren zur Herstellung von Blockcopolymeren durch retardierten anionischen Polymerisation
US6391981B1 (en) 1999-04-23 2002-05-21 Kraton Polymers Us Llc Increased throughput in the manufacture of anionic polymers by reduction in polymer cement viscosity through the addition of metal alkyls
US6455651B1 (en) 1999-04-23 2002-09-24 Kraton Polymers U.S. Llc Uniform initiation of anionic polymerization using organo-substituted alkali metal initiators
KR20020009617A (ko) 1999-05-21 2002-02-01 스타르크, 카르크 입체적으로 우세한 킬레이트 촉매를 사용하는 스티렌 용액상태의 고무 재료의 제조 방법
DE19936566A1 (de) * 1999-08-04 2001-02-08 Basf Ag Verfahren zum Herstellen einer Lösung von Dienpolymerisaten in vinylaromatischen Verbindungen sowie zum Herstellen von schlagzähen vinylaromatischen Polymeren durch Polymerisation dieser Lösung
US6649671B2 (en) 2000-03-13 2003-11-18 Dow Global Technologies Inc. Concrete and process to make same
DE10022504A1 (de) * 2000-05-10 2001-11-15 Basf Ag Anionisch polymerisiertes, schlagzähes Polystyrol mit Kapselteilchenmorphologie
FR2824833A1 (fr) * 2001-05-17 2002-11-22 Mssa Procede de polymerisation anionique stereospecifique controlee du styrene
US6437043B1 (en) * 2001-09-13 2002-08-20 Fina Technology, Inc. Process and apparatus for continuous manufacture of elastomer-modified monovinylaromatic compounds
DE10152116A1 (de) * 2001-10-23 2003-04-30 Basf Ag Verfahren zur kontinuierlichen anionischen Polymerisation von schlagzähem Polystyrol
DE10218161A1 (de) * 2002-04-23 2003-11-13 Basf Ag Initiatorzusammensetzung und Verfahren zur anionischen Polymerisation
ES2307979T3 (es) 2002-07-11 2008-12-01 Kraton Polymers Research B.V. Copolimeros estirenicos de bloques y el procedimiento para su preparacion.
DE10241850A1 (de) * 2002-09-09 2004-03-18 Basf Ag Anionisch polymerisiertes schlagzähes Polystyrol mit guter Fliessfähigkeit
DE10250280A1 (de) * 2002-10-28 2004-05-13 Basf Ag Verfahren zur anionischen Polymerisation von schlagzähem Polystyrol
DE10307058A1 (de) * 2003-02-19 2004-09-02 Basf Ag Verfahren zur anionischen Polymerisation von α-Methylstyrol
DE10350998A1 (de) * 2003-10-30 2005-06-02 Basf Ag Verfahren zur anionischen Polymerisation von Monomeren in α-Methylstyrol
WO2006004376A1 (en) * 2004-07-07 2006-01-12 Lg Chem. Ltd. Method of producing cyclic olefin polymers having polar functional groups, olefin polymer produced using the method and optical anisotropic film comprising the same
US7351777B2 (en) * 2005-03-30 2008-04-01 Moore Eugene R Retarded anionic polymerization of vinyl aromatic monomers using insoluble or heterogeneous retardants
US20100016509A1 (en) 2006-08-18 2010-01-21 Kaneka Coorporation Method for producing branched vinyl polymer having functional group
US9732178B1 (en) 2008-07-24 2017-08-15 Bridgestone Corporation Block copolymers including high vinyl segments
KR101489954B1 (ko) * 2011-12-23 2015-02-04 제일모직주식회사 공액 디엔으로부터 열가소성 수지를 연속적으로 제조하는 방법 및 그로부터 제조된 열가소성 수지
SG11201610196TA (en) 2014-08-20 2017-03-30 Versalis Spa Process for the preparation of diene polymers or random vinyl arene-diene copolymers
KR102159608B1 (ko) 2016-12-22 2020-09-25 주식회사 엘지화학 변성 개시제 제조방법 및 제조장치
EP4045549A4 (en) * 2019-10-14 2023-11-22 Bridgestone Americas Tire Operations, LLC ANIONIC DISPERSION POLYMERIZATION METHOD FOR THE PRODUCTION OF RUBBER WITH STATISTIC COPOLYMERS

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3264374A (en) 1963-01-02 1966-08-02 Monsanto Co Graft copolymer formed by polymerizing butadiene in styrene with an alkylli catalyst, deactivating the catalyst and adding an organic peroxide
US3278508A (en) 1963-01-14 1966-10-11 Phillips Petroleum Co Preparation of diene polymers in the presence of an organolithium initiator and a group iib or ivb metal containing adjuvant
US3264375A (en) 1963-01-16 1966-08-02 Monsanto Co Process for the graft polymerization of styrene on alkyl lithium catalyzed polybutadiene using a peroxide catalyst
US3716495A (en) 1970-09-02 1973-02-13 Phillips Petroleum Co Polymerization initiator composition and use thereof
BE792704A (nl) 1972-01-21 1973-06-14 Shell Int Research Werkwijze ter bereiding van een polymeer uit een geconjugeerd dieen door polymerisatie in oplossing met trihydrocarbylborium in hetkatalysatorsysteem
US4153647A (en) 1977-06-15 1979-05-08 Glukhovskoi Vladimir S Process for producing-impact polystyrene
US4362849A (en) 1979-07-18 1982-12-07 The Dow Chemical Company Preparation of alkenyl aromatic monomer butadiene rubber and preparation of impact resistant resin therefrom
DE3047303A1 (de) * 1980-12-16 1982-07-29 Basf Ag, 6700 Ludwigshafen Verfahren zur kontinuierlichen herstellung von mit kautschuk modifizierten polymerisaten von vinylaromaten, verwendung derselben zum spritzgiessen, sowie formteile aus diesen
EP0304088B1 (en) * 1987-08-19 1993-01-27 Asahi Kasei Kogyo Kabushiki Kaisha A prepolymerization process for producing a conjugated diene compound prepolymer solution
FR2629085B1 (fr) 1988-03-24 1992-09-04 Atochem Procede de fabrication de polybutadiene et preparation de resine vinylaromatique choc a partir de polybutadiene
CN1208353C (zh) 1996-03-14 2005-06-29 旭化成株式会社 乙烯基聚合物的制备方法、乙烯基单体聚合引发剂和苯乙烯树脂组合物

Also Published As

Publication number Publication date
EP0918806A1 (de) 1999-06-02
EP0918806B1 (de) 2000-11-08
US6303721B1 (en) 2001-10-16
WO1998007766A1 (de) 1998-02-26
DE59702613D1 (de) 2000-12-14

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