ES2142056T3 - Metodo para evitar la formacion de suciedad y revestimientos en reactores en fase gaseosa. - Google Patents
Metodo para evitar la formacion de suciedad y revestimientos en reactores en fase gaseosa.Info
- Publication number
- ES2142056T3 ES2142056T3 ES96910040T ES96910040T ES2142056T3 ES 2142056 T3 ES2142056 T3 ES 2142056T3 ES 96910040 T ES96910040 T ES 96910040T ES 96910040 T ES96910040 T ES 96910040T ES 2142056 T3 ES2142056 T3 ES 2142056T3
- Authority
- ES
- Spain
- Prior art keywords
- reactor
- gaseous phase
- avoid
- incrustation
- dirt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 4
- 239000007792 gaseous phase Substances 0.000 title abstract 3
- 230000015572 biosynthetic process Effects 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 238000013517 stratification Methods 0.000 abstract 2
- 239000012467 final product Substances 0.000 abstract 1
- 239000012071 phase Substances 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/2435—Loop-type reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00654—Controlling the process by measures relating to the particulate material
- B01J2208/00707—Fouling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00734—Controlling static charge
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
Abstract
UN METODO PARA LA PREVENCION DE LOS PROBLEMAS DE ESTRATIFICACION EN UN REACTOR DE FASE GASEOSA EN DICHO PROCEDIMIENTO DE POLIMERIZACION MULTIFASICO, EL CUAL COMPRENDE AL MENOS UN REACTOR EN BUCLE SEGUIDO DE UN REACTOR DE FASE GASEOSA, DONDE LA POLIMERIZACION SE CONTINUA EN PRESENCIA DE MONOMEROS AÑADIDOS, UTILIZANDO EN EL PROCEDIMIENTO UN AGENTE ANTI-INCRUSTACION PARA EVITAR LA INCRUSTACION O LA ESTRATIFICACION EN LOS REACTORES. DE ACUERDO DON LA INVENCION, ENTRE EL 30 Y EL 70 % DEL PRODUCTO FINAL SE POLIMERIZA EN EL REACTOR EN BUCLE, DONDE SE AÑADE LA CANTIDAD TOTAL DEL AGENTE ANTI-INCRUSTACION, SIENDO LA CANTIDAD DEL AGENTE MAYOR DE LO NECESARIO PARA EVITAR LA INCRUSTACION EN EL REACTOR.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI951779A FI104827B (fi) | 1995-04-12 | 1995-04-12 | Menetelmä likaantumisen ja kerrostumisen estämiseksi kaasufaasireaktoreissa |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2142056T3 true ES2142056T3 (es) | 2000-04-01 |
Family
ID=8543240
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES96910040T Expired - Lifetime ES2142056T3 (es) | 1995-04-12 | 1996-04-10 | Metodo para evitar la formacion de suciedad y revestimientos en reactores en fase gaseosa. |
Country Status (13)
Country | Link |
---|---|
US (1) | US6096837A (es) |
EP (1) | EP0820474B1 (es) |
JP (1) | JP3706973B2 (es) |
KR (1) | KR100415699B1 (es) |
CN (1) | CN1101408C (es) |
AT (1) | ATE189463T1 (es) |
AU (1) | AU706943B2 (es) |
BR (1) | BR9604903A (es) |
CA (1) | CA2218050A1 (es) |
DE (1) | DE69606526T2 (es) |
ES (1) | ES2142056T3 (es) |
FI (1) | FI104827B (es) |
WO (1) | WO1996032420A1 (es) |
Families Citing this family (72)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19615953A1 (de) * | 1996-04-22 | 1997-10-23 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums |
WO1998020045A1 (en) * | 1996-11-01 | 1998-05-14 | Union Carbide Chemicals & Plastics Technology Corporation | Reduction of fouling in olefin polymerization systems |
FI981034A (fi) * | 1998-05-08 | 1999-11-09 | Borealis Polymers Oy | HD-polyeteenikoostumukset ja menetelmä niiden valmistamiseksi |
US7354880B2 (en) | 1998-07-10 | 2008-04-08 | Univation Technologies, Llc | Catalyst composition and methods for its preparation and use in a polymerization process |
US6180735B1 (en) | 1998-12-17 | 2001-01-30 | Univation Technologies | Catalyst composition and methods for its preparation and use in a polymerization process |
FI991015A0 (fi) * | 1999-05-04 | 1999-05-04 | Borealis As | Menetelmä alfa-olefiinipolymeerien valmistamiseksi |
BR0010321B1 (pt) * | 1999-05-07 | 2010-04-06 | processo para a (co-) polimerização de fase gasosa contìnua de olefinas em um reator de leito fluidizado. | |
EP1218418A1 (en) | 1999-09-09 | 2002-07-03 | BP Chemicals Limited | Process for the continuous gas-phase (co-)polymerisation of olefins in a fluidised bed reactor |
CN1162449C (zh) | 1999-09-09 | 2004-08-18 | 英国石油化学品有限公司 | 在流化床反应器中的烯烃连续气相聚合或共聚合法 |
US6713573B2 (en) | 2000-11-30 | 2004-03-30 | Univation Technologies, Llc | Catalyst modifiers and their use in the polymerization of olefin(s) |
US20050148742A1 (en) * | 2004-01-02 | 2005-07-07 | Hagerty Robert O. | Method for controlling sheeting in gas phase reactors |
US8034231B2 (en) * | 2008-02-20 | 2011-10-11 | Baker Hughes Incorporated | Method for reducing hydrogen sulfide evolution from asphalt |
ES2381849T3 (es) | 2008-11-17 | 2012-06-01 | Borealis Ag | Procedimiento multietapa para producir polietileno con formación de gel reducida |
EP2428526A1 (en) | 2010-09-13 | 2012-03-14 | Borealis AG | Process for producing polyethylene with improved homogeneity |
EP2570455A1 (en) | 2011-09-16 | 2013-03-20 | Borealis AG | Polyethylene composition with broad molecular weight distribution and improved homogeneity |
EP2599828A1 (en) | 2011-12-01 | 2013-06-05 | Borealis AG | Multimodal polyethylene composition for the production of pipes with improved slow crack growth resistance |
EP2740761B1 (en) | 2012-12-05 | 2016-10-19 | Borealis AG | Polyethylene composition with improved balance of slow crack growth resistance, impact performance and pipe pressure resistance for pipe applications |
EP2860204B1 (en) | 2013-10-10 | 2018-08-01 | Borealis AG | Polyethylene composition for pipe applications |
EP2860200B1 (en) | 2013-10-10 | 2017-08-02 | Borealis AG | Polyethylene composition for pipe and pipe coating applications |
EP2860203B1 (en) | 2013-10-10 | 2016-12-14 | Borealis AG | Multistage process for producing polyethylene compositions |
EP2860201A1 (en) | 2013-10-10 | 2015-04-15 | Borealis AG | High temperature resistant polyethylene and process for the production thereof |
EP2860202B1 (en) | 2013-10-10 | 2018-05-30 | Borealis AG | High temperature resistant polyethylene and process for the production thereof |
EP2883885A1 (en) | 2013-12-13 | 2015-06-17 | Borealis AG | Multistage process for producing polyethylene compositions |
EP2883887A1 (en) | 2013-12-13 | 2015-06-17 | Borealis AG | Multistage process for producing polyethylene compositions |
EP2894195B1 (en) | 2013-12-23 | 2016-09-14 | Abu Dhabi Polymers Company Limited (Borouge) | Polyethylene composition for pipe applications with improved sagging properties |
EP3037436B2 (en) | 2014-12-22 | 2020-11-18 | Borealis AG | Process for producing multimodal polyethylene in-situ blends including ultra-high molecular weight fractions |
EP3037471B1 (en) | 2014-12-22 | 2019-05-01 | Borealis AG | Process for producing multimodal polyethylene compositions |
EP3253807B1 (en) | 2015-02-05 | 2023-04-26 | Borealis AG | Process for producing polyethylene |
EP3088458B2 (en) | 2015-04-27 | 2022-10-05 | Abu Dhabi Polymers Company Limited (Borouge) L.L.C. | Polyethylene composition suitable for pipe applications |
KR20180041116A (ko) | 2015-06-10 | 2018-04-23 | 보레알리스 아게 | 멀티모달 폴리에틸렌 공중합체 |
EP3307814B1 (en) | 2015-06-10 | 2019-07-03 | Borealis AG | Multimodal copolymer of ethylene and at least two alpha-olefin comonomers and final articles made thereof |
EP3109275B1 (en) | 2015-06-22 | 2017-08-09 | Abu Dhabi Polymers Company Limited (Borouge) L.L.C. | Polyethylene composition for pipe applications with improved sagging and extrusion properties |
EP3109261B1 (en) | 2015-06-23 | 2018-12-26 | Borealis AG | Process for producing lldpe resins |
CN105237665B (zh) * | 2015-10-12 | 2017-07-11 | 浙江大学 | 一种用于生产低密度聚乙烯气相流化床反应系统的在线清洗方法 |
EP3178853B1 (en) | 2015-12-07 | 2018-07-25 | Borealis AG | Process for polymerising alpha-olefin monomers |
EP3238938A1 (en) | 2016-04-29 | 2017-11-01 | Borealis AG | Machine direction oriented films comprising multimodal copolymer of ethylene and at least two alpha-olefin comonomers |
PL3252085T3 (pl) | 2016-05-31 | 2023-02-13 | Borealis Ag | Pancerz o polepszonych właściwościach |
CN109415544B (zh) | 2016-05-31 | 2022-07-05 | 博里利斯股份公司 | 聚合物组合物以及用于生产该聚合物组合物的方法 |
WO2017220558A1 (en) | 2016-06-22 | 2017-12-28 | Borealis Ag | Polymer composition and a process for production of the polymer composition |
PL3519444T3 (pl) | 2016-09-28 | 2021-05-04 | Borealis Ag | Proces wytwarzania powlekanej rury |
CN109922960B (zh) | 2016-11-25 | 2021-09-14 | 博里利斯股份公司 | 聚烯烃膜组合物的制备方法及由其制成的膜 |
RU2736712C1 (ru) | 2016-11-25 | 2020-11-19 | Бореалис Аг | Новая композиция и способ |
KR102527286B1 (ko) * | 2016-12-07 | 2023-04-27 | 에코랍 유에스에이 인코퍼레이티드 | 석유 공정 스트림을 위한 중합체 분산제 |
EP3418330B2 (en) | 2017-06-21 | 2023-07-19 | Borealis AG | Polymer composition and a process for production of the polymer composition |
EP3479896A1 (en) | 2017-11-03 | 2019-05-08 | Borealis AG | Polymerization reactor system comprising at least one withdrawal valve |
ES2950671T3 (es) | 2018-05-30 | 2023-10-11 | Borealis Ag | Proceso para la preparación de polietileno multimodal de alta densidad |
CA3106413A1 (en) | 2018-07-19 | 2020-01-23 | Borealis Ag | Process for the preparation of an uhmwpe homopolymer |
WO2020099566A1 (en) | 2018-11-15 | 2020-05-22 | Borealis Ag | Propylene butene copolymer |
US20210395427A1 (en) | 2018-11-15 | 2021-12-23 | Borealis Ag | Propylene butene copolymer |
WO2020099562A1 (en) | 2018-11-15 | 2020-05-22 | Borealis Ag | Composition |
EP3902851A1 (en) | 2018-12-28 | 2021-11-03 | Borealis AG | A process for producing polyolefin film composition and films prepared thereof |
WO2020136164A1 (en) | 2018-12-28 | 2020-07-02 | Borealis Ag | A process for producing polyolefin film composition and films prepared thereof |
ES2960940T3 (es) | 2019-06-24 | 2024-03-07 | Borealis Ag | Proceso para preparar polipropileno con recuperación mejorada |
EP3885375B1 (en) | 2020-03-24 | 2022-08-31 | Borealis AG | Stiff blown film |
CN116601177A (zh) | 2020-11-27 | 2023-08-15 | 博里利斯股份公司 | 工艺 |
EP4029914A1 (en) | 2021-01-14 | 2022-07-20 | Borealis AG | Heterophasic polyolefin composition |
WO2022258804A1 (en) | 2021-06-11 | 2022-12-15 | Borealis Ag | A process for producing a multimodal ethylene polymer and films prepared therefrom |
EP4151677A1 (en) | 2021-09-21 | 2023-03-22 | Borealis AG | Biaxially oriented film |
CA3232754A1 (en) | 2021-09-23 | 2023-03-30 | Borealis Ag | Process for producing a propylene copolymer |
EP4155328A1 (en) | 2021-09-23 | 2023-03-29 | Borealis AG | Propylene-butene random copolymer composition with low extractable content |
EP4163323A1 (en) | 2021-10-07 | 2023-04-12 | Borealis AG | Biaxially oriented film |
EP4163309A1 (en) | 2021-10-07 | 2023-04-12 | Borealis AG | Hdpe |
EP4239015A1 (en) | 2022-03-02 | 2023-09-06 | Borealis AG | Monoaxially oriented film comprising a polyethylene composition |
EP4239014A1 (en) | 2022-03-02 | 2023-09-06 | Borealis AG | Film comprising a polyethylene composition |
EP4245805A1 (en) | 2022-03-18 | 2023-09-20 | Borealis AG | Polyethylene blend for a film layer |
WO2023217750A1 (en) | 2022-05-12 | 2023-11-16 | Borealis Ag | Polyethylene copolymer for a film layer |
WO2023217751A1 (en) | 2022-05-12 | 2023-11-16 | Borealis Ag | Composition for a film layer |
EP4296289A1 (en) | 2022-06-23 | 2023-12-27 | Borealis AG | Polyethylene copolymer for a film layer |
WO2024003206A1 (en) | 2022-07-01 | 2024-01-04 | Borealis Ag | Polyethylene copolymer for a film layer |
EP4306444A1 (en) | 2022-07-14 | 2024-01-17 | Borealis AG | Composition |
EP4306442A1 (en) | 2022-07-14 | 2024-01-17 | Borealis AG | Composition |
EP4344869A1 (en) | 2022-09-30 | 2024-04-03 | Borealis AG | Multimodal ethylene copolymer composition and films comprising the same |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1443074A (en) * | 1974-01-14 | 1976-07-21 | Ici Ltd | Olefin polymerisation process |
JPS5830323B2 (ja) * | 1974-08-12 | 1983-06-28 | 昭和電工株式会社 | オレフインノ ジユウゴウホウホウ |
US3995097A (en) * | 1975-09-15 | 1976-11-30 | Phillips Petroleum Company | Prevention of fouling in polymerization reactors |
US4068054A (en) * | 1976-08-02 | 1978-01-10 | Phillips Petroleum Company | Prevention of fouling in polymerization reactors and antistatic agents |
US4182810A (en) * | 1978-04-21 | 1980-01-08 | Phillips Petroleum Company | Prevention of fouling in polymerization reactors |
US4259087A (en) * | 1978-12-15 | 1981-03-31 | Petrolite Corporation | Antistats containing acrylonitrile copolymers and polyamines |
US4740550A (en) * | 1986-06-18 | 1988-04-26 | Shell Oil Company | Multistage copolymerization process |
FR2660926B1 (fr) * | 1990-04-11 | 1992-07-31 | Bp Chemicals Snc | Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere. |
FI86867C (fi) * | 1990-12-28 | 1992-10-26 | Neste Oy | Flerstegsprocess foer framstaellning av polyeten |
FI96216C (fi) * | 1994-12-16 | 1996-05-27 | Borealis Polymers Oy | Prosessi polyeteenin valmistamiseksi |
-
1995
- 1995-04-12 FI FI951779A patent/FI104827B/fi active
-
1996
- 1996-04-10 US US08/945,225 patent/US6096837A/en not_active Expired - Lifetime
- 1996-04-10 CA CA002218050A patent/CA2218050A1/en not_active Abandoned
- 1996-04-10 KR KR1019970707157A patent/KR100415699B1/ko not_active IP Right Cessation
- 1996-04-10 CN CN96193863A patent/CN1101408C/zh not_active Expired - Lifetime
- 1996-04-10 DE DE69606526T patent/DE69606526T2/de not_active Expired - Lifetime
- 1996-04-10 ES ES96910040T patent/ES2142056T3/es not_active Expired - Lifetime
- 1996-04-10 JP JP53074396A patent/JP3706973B2/ja not_active Expired - Fee Related
- 1996-04-10 AT AT96910040T patent/ATE189463T1/de not_active IP Right Cessation
- 1996-04-10 AU AU53360/96A patent/AU706943B2/en not_active Ceased
- 1996-04-10 BR BR9604903A patent/BR9604903A/pt not_active IP Right Cessation
- 1996-04-10 WO PCT/FI1996/000189 patent/WO1996032420A1/en active IP Right Grant
- 1996-04-10 EP EP96910040A patent/EP0820474B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0820474A1 (en) | 1998-01-28 |
CN1184486A (zh) | 1998-06-10 |
AU706943B2 (en) | 1999-07-01 |
US6096837A (en) | 2000-08-01 |
KR19980703757A (ko) | 1998-12-05 |
BR9604903A (pt) | 1998-07-21 |
EP0820474B1 (en) | 2000-02-02 |
JPH11503479A (ja) | 1999-03-26 |
AU5336096A (en) | 1996-10-30 |
CN1101408C (zh) | 2003-02-12 |
FI951779A (fi) | 1996-10-13 |
FI951779A0 (fi) | 1995-04-12 |
FI104827B (fi) | 2000-04-14 |
KR100415699B1 (ko) | 2004-06-18 |
WO1996032420A1 (en) | 1996-10-17 |
JP3706973B2 (ja) | 2005-10-19 |
CA2218050A1 (en) | 1996-10-17 |
DE69606526T2 (de) | 2000-06-21 |
ATE189463T1 (de) | 2000-02-15 |
DE69606526D1 (de) | 2000-03-09 |
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