ES2136940T3 - Procedimiento para eliminar so2 de gases que lo contienen, con una produccion directa de azufre elemental. - Google Patents

Procedimiento para eliminar so2 de gases que lo contienen, con una produccion directa de azufre elemental.

Info

Publication number
ES2136940T3
ES2136940T3 ES96200411T ES96200411T ES2136940T3 ES 2136940 T3 ES2136940 T3 ES 2136940T3 ES 96200411 T ES96200411 T ES 96200411T ES 96200411 T ES96200411 T ES 96200411T ES 2136940 T3 ES2136940 T3 ES 2136940T3
Authority
ES
Spain
Prior art keywords
sub
baso
procedure
eliminate
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96200411T
Other languages
English (en)
Inventor
Marco Olper
Massimo Maccagni
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Engitec Srl
Original Assignee
Engitec Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Engitec Srl filed Critical Engitec Srl
Application granted granted Critical
Publication of ES2136940T3 publication Critical patent/ES2136940T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/501Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/501Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/502Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific solution or suspension
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/02Preparation of sulfur; Purification
    • C01B17/04Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/05Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by wet processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/42Sulfides or polysulfides of magnesium, calcium, strontium, or barium
    • C01B17/44Sulfides or polysulfides of magnesium, calcium, strontium, or barium by reduction of sulfates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Industrial Gases (AREA)

Abstract

SE PRESENTA UN PROCEDIMIENTO HUMEDO DE TIPO REGENERATIVO PARA ELIMINAR EL SO{SUB,2} PRESENTE EN LOS GASES DE COMBUSTION, QUE SE CARACTERIZA PORQUE HACE QUE UNA SOLUCION ACUOSA DILUIDA DE BAS ABSORBA EL SO{SUB,2}, Y LAS REACCIONES CONSIGUIENTES FORMAN UN PRECIPITADO MIXTO DE S ELEMENTAL, BASO{SUB,3} Y BASO{SUB,4}. EL AZUFRE SE RETIRA DEL PRECIPITADO -RECUPERADO POR FILTRACIONUTILIZANDO UNA SOLUCION DE (NH{SUB,4}){SUB,2}S; SE DESTILA EL POLISULFURO RESULTANTE, CON LO QUE SE OBTIENE S PURO ELEMENTAL Y LA SOLUCION DE (NH{SUB,4}){SUB,2}S A RECICLAR. LA MEZCLA RESIDUAL DE BASO{SUB,3} Y DE BASO{SUB,4} QUE PERMANECE DESPUES DE LA EXTRACCION DEL AZUFRE SE REDUCE CON HULLA EN UN HORNO DE ALTA TEMPERATURA, PARA OBTENER BAS A RECICLAR, A MODO DE SOLUCION ACUOSA, PARA EL PASO DE ABSORCION DE SO{SUB,2}.
ES96200411T 1995-02-24 1996-02-17 Procedimiento para eliminar so2 de gases que lo contienen, con una produccion directa de azufre elemental. Expired - Lifetime ES2136940T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI950357A IT1274256B (it) 1995-02-24 1995-02-24 Processo di abbattimento di so2 dai gas che la contengono con produzione diretta di zolfo elementare

Publications (1)

Publication Number Publication Date
ES2136940T3 true ES2136940T3 (es) 1999-12-01

Family

ID=11370683

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96200411T Expired - Lifetime ES2136940T3 (es) 1995-02-24 1996-02-17 Procedimiento para eliminar so2 de gases que lo contienen, con una produccion directa de azufre elemental.

Country Status (7)

Country Link
US (1) US5618507A (es)
EP (1) EP0728698B1 (es)
JP (1) JPH08252427A (es)
AU (1) AU696509B2 (es)
DE (1) DE69603385T2 (es)
ES (1) ES2136940T3 (es)
IT (1) IT1274256B (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20000065466A (ko) * 1999-04-03 2000-11-15 이희철 배기가스 처리와 처리 부산물의 제조방법
JP4747382B1 (ja) * 2010-11-19 2011-08-17 株式会社センテック 排煙浄化処理方法
US11502322B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell with heat pump
US11502323B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell and methods of use thereof
US12040517B2 (en) 2022-11-15 2024-07-16 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell and methods of use thereof
US11855324B1 (en) 2022-11-15 2023-12-26 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell with heat pump

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3784680A (en) * 1971-12-01 1974-01-08 Basic Inc Cyclical process for recovery of elemental sulfur from waste gases
US4100260A (en) * 1976-02-04 1978-07-11 Georgia Tech Research Institute Regenerative method for quantitative removal of sulfur dioxide from stack gases
US4078048A (en) * 1977-02-16 1978-03-07 Combustion Equipment Associates, Inc. Process and apparatus for removing sulfur from stack gases in the form of elemental sulfur
FI69621C (fi) * 1984-06-27 1986-03-10 Outokumpu Oy Foerfarande foer avlaegsning och tillvaratagande av svavel somgrundaemnessvavel fraon svaveldioxid- eller svaveldioxid hocsvavelvaetehaltiga gaser
EP0205976A3 (en) * 1985-05-29 1988-08-17 METALNA strojegradnja, konstrukcije in montaza n.sol.o. Tozd Tovarna investicijska opreme n.sol.o A process for the removal of sulfur oxides from gaseous and/or liquid waste products
JPH0741309A (ja) * 1993-05-07 1995-02-10 Inco Ltd 二酸化硫黄含有ガスの脱硫方法

Also Published As

Publication number Publication date
ITMI950357A0 (it) 1995-02-24
DE69603385T2 (de) 2000-05-11
EP0728698B1 (en) 1999-07-28
AU696509B2 (en) 1998-09-10
JPH08252427A (ja) 1996-10-01
DE69603385D1 (de) 1999-09-02
EP0728698A1 (en) 1996-08-28
AU4567696A (en) 1996-09-05
ITMI950357A1 (it) 1996-08-24
IT1274256B (it) 1997-07-15
US5618507A (en) 1997-04-08

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