ES2133441T3 - Procedimiento de hidroformilacion que emplea un sistema de catalizador a base de fosfina y rodio. - Google Patents
Procedimiento de hidroformilacion que emplea un sistema de catalizador a base de fosfina y rodio.Info
- Publication number
- ES2133441T3 ES2133441T3 ES94107243T ES94107243T ES2133441T3 ES 2133441 T3 ES2133441 T3 ES 2133441T3 ES 94107243 T ES94107243 T ES 94107243T ES 94107243 T ES94107243 T ES 94107243T ES 2133441 T3 ES2133441 T3 ES 2133441T3
- Authority
- ES
- Spain
- Prior art keywords
- ring
- carbon
- linked
- phosphine
- phosphine compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 3
- 229910052703 rhodium Inorganic materials 0.000 title abstract 2
- 239000010948 rhodium Substances 0.000 title abstract 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 title abstract 2
- 229910000073 phosphorus hydride Inorganic materials 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 5
- 229910052799 carbon Inorganic materials 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 150000001721 carbon Chemical class 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
- B01J31/2461—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
- B01J31/2471—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring with more than one complexing phosphine-P atom
- B01J31/2476—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
- B01J31/2428—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom
- B01J31/2433—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
- C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
- B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
SE PRESENTAN COMPUESTOS DE BIS-FOSFINA QUE TIENEN LA FORMULA GENERAL EN LA QUE CADA A1, A2, A3 Y A4 ES UN RADICAL DE ARILENO EN DONDE (I) CADA ATOMO DE FOSFORO P ESTA ENLAZADO A UN ATOMO DE CARBONO EN ANILLO DE A1 Y A2 Y A UN ATOMO DE CARBONO EN ANILLO DE A3 Y A4, (II) CADA A1 Y A2, Y A3 Y A4 SE ENCUENTRAN ENLAZADOS ENTRE SI MEDIANTE ATOMOS DE CARBONO EN ANILLO Y (III) CADA UNO DE LOS RESIDUOS CONSTITUYE UN ANILLO DE 5 MIEMBROS; CADA A5 Y A6 ES UN RADICAL DE ARILENO EN DONDE A5 Y A6 SE ENCUENTRAN ENLAZADOS ENTRE SI Y A LOS RESIDUOS R1-C-R2 Y R3-C-R4 MEDIANTE ATOMOS DE CARBONO EN ANILLO Y R1-C-R2 Y R3-C-R4 SE ENCUENTRAN CONECTADOS ENTRE SI A TRAVES DE UNA CADENA DE 4 ATOMOS DE CARBONO; Y R1, R2, R3 Y R4 PRESENTAN CADA UNO HIDROGENO O UN RADICAL DE HIDROCARBILO QUE CONTIENE HASTA 8 ATOMOS DE CARBONO APROXIMADAMENTE. TAMBIEN SE PRESENTAN SISTEMAS CATALIZADORES QUE CONTIENEN UNO O MAS DE LOS COMPUESTOS DE FOSFINA ANTEDICHOS Y RODIO, SOLUCIONES CATALIZADORAS QUE CONTIENEN UNO O MAS DE LOS COMPUESTOS DE FOSFINA ANTEDICHOS, RODIO Y UN SOLVENTE DE HIDROFORMILACION Y PROCESOS DE HIDROFORMILACION EN LOS QUE SE PONEN EN CONTACTO OLEFINAS CON MONOXIDO DE CARBONO, HIDROGENO Y LA SOLUCION CATALIZADORA PARA PRODUCIR ALDEHIDOS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/069,478 US5332846A (en) | 1993-06-01 | 1993-06-01 | Hydroformylation process using novel phosphine-rhodium catalyst system |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2133441T3 true ES2133441T3 (es) | 1999-09-16 |
Family
ID=22089259
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94107243T Expired - Lifetime ES2133441T3 (es) | 1993-06-01 | 1994-05-09 | Procedimiento de hidroformilacion que emplea un sistema de catalizador a base de fosfina y rodio. |
Country Status (5)
Country | Link |
---|---|
US (2) | US5332846A (es) |
EP (1) | EP0627439B1 (es) |
CA (1) | CA2124525C (es) |
DE (1) | DE69419567T2 (es) |
ES (1) | ES2133441T3 (es) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4333307A1 (de) * | 1993-09-30 | 1995-04-06 | Hoechst Ag | Cyclische Verbindungen des dreiwertigen Phosphors |
DE4433952A1 (de) * | 1994-09-23 | 1996-03-28 | Hoechst Ag | Bis-phosphepine und Verfahren zu deren Herstelllung |
US5840647A (en) * | 1997-09-15 | 1998-11-24 | Eastman Chemical Company | Hydroformylation process using novel phosphite-metal catalyst system |
WO2002000580A1 (de) * | 2000-06-26 | 2002-01-03 | Basf Aktiengesellschaft | Alkoholgemische mit 13 und 15 kohlenstoffatomen und deren verwendung in der herstellung von oberflächenaktiven substanzen |
DE10205702A1 (de) | 2001-02-13 | 2002-08-29 | Basf Ag | Verfahren zur Hydroformylierung, Liganden mit von Bisphenol A abgeleiteter Struktur und Katalysator, umfassend einen Komplex dieser Liganden |
US6794553B2 (en) * | 2001-11-09 | 2004-09-21 | Shell Oil Company | Process for the telomerization of a conjugated diene, catalyst and bidentate ligand useful therein |
CN101146812B (zh) | 2005-03-03 | 2013-10-16 | 日本曹达株式会社 | 光学活性铵盐化合物、其制造中间体和制造方法 |
US7767862B2 (en) * | 2008-08-11 | 2010-08-03 | Shell Oil Company | Ligand, catalyst and process for hydroformylation |
US20110259794A1 (en) * | 2010-04-23 | 2011-10-27 | Chevron U.S.A. Inc. | Removing chlathrate inhibitors from contaminated petroleum streams |
US8513468B2 (en) | 2010-12-30 | 2013-08-20 | Eastman Chemical Company | Process for removing degradation acids from hydroformylation reactions |
JP2016540780A (ja) | 2013-12-19 | 2016-12-28 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化プロセス |
CN106083551A (zh) * | 2016-06-30 | 2016-11-09 | 成都欣华源科技有限责任公司 | 一种丙烯氢甲酰化制备丁醛的方法 |
US9687837B1 (en) | 2016-08-31 | 2017-06-27 | Eastman Chemical Company | Stable hydroformylation catalyst for preparation of high N/Iso ratio aldehyde product |
US9975833B2 (en) | 2016-08-31 | 2018-05-22 | Eastman Chemical Company | Efficient catalyst for the formation of polyaryl hydrocarbons suitable as precursors for polydentate organophosphorus catalyst ligands |
KR20210022047A (ko) * | 2018-06-18 | 2021-03-02 | 미쯔비시 가스 케미칼 컴파니, 인코포레이티드 | 노보네인 골격을 갖는 2작용성 화합물의 제조 방법 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA701926A (en) * | 1965-01-12 | Fritzsche Hans | Reduction of phosphine oxides | |
DE1193942B (de) * | 1962-07-31 | 1965-06-03 | Shell Int Research | Verfahren zur Herstellung von tertiaeren Phosphinen |
FR2230654B1 (es) * | 1973-05-21 | 1975-11-21 | Rhone Poulenc Ind | |
US4247486A (en) * | 1977-03-11 | 1981-01-27 | Union Carbide Corporation | Cyclic hydroformylation process |
US4139565A (en) * | 1977-03-31 | 1979-02-13 | Celanese Corporation | Hydroformylation using improved catalysts comprising rhodium and diphosphino ligands |
US4152344A (en) * | 1977-08-08 | 1979-05-01 | Celanese Corporation | Phosphino-ferrocene ligands |
US4215077A (en) * | 1978-02-09 | 1980-07-29 | Kuraray Co., Ltd. | Hydroformylation of olefins |
US4760194A (en) * | 1987-02-18 | 1988-07-26 | Eastman Kodak Company | Low pressure hydroformylation catalyst employing unique ligands and process using same |
US4755624A (en) * | 1987-02-18 | 1988-07-05 | Eastman Kodak Company | Low pressure hydroformylation process |
US4694109A (en) * | 1986-06-13 | 1987-09-15 | Eastman Kodak Company | Chelate ligands for low pressure hydroformylation catalyst and process employing same |
CA1300164C (en) * | 1986-06-13 | 1992-05-05 | Thomas James Devon | Chelate ligands for low pressure hydroformylation catalyst and process employing same |
DK559887A (da) * | 1986-11-28 | 1988-05-29 | Hoffmann La Roche | Fremgangsmaade til fremstilling af carbinolderivater |
US4824977A (en) * | 1987-04-24 | 1989-04-25 | Eastman Kodak Company | Chelating ligands and catalysts and processes employing the same |
US4960949A (en) * | 1988-12-22 | 1990-10-02 | Eastman Kodak Company | Low pressure rhodium catalyzed hydroformylation of olefins |
US5206398A (en) * | 1990-05-17 | 1993-04-27 | E. I. Du Pont De Nemours And Company | Chiral phospholane transition metal catalysts |
US5008457A (en) * | 1990-05-17 | 1991-04-16 | E. I. Du Pont De Nemours And Company | Chiral phospholane transition metal catalysts |
US5171892A (en) * | 1991-07-02 | 1992-12-15 | E. I. Du Pont De Nemours And Company | Chiral phospholanes via chiral 1,4-diol cyclic sulfates |
ATE165361T1 (de) * | 1992-01-31 | 1998-05-15 | Hoffmann La Roche | Diphosphinliganden |
-
1993
- 1993-06-01 US US08/069,478 patent/US5332846A/en not_active Expired - Lifetime
-
1994
- 1994-02-22 US US08/200,023 patent/US5344988A/en not_active Expired - Lifetime
- 1994-05-09 EP EP94107243A patent/EP0627439B1/en not_active Expired - Lifetime
- 1994-05-09 ES ES94107243T patent/ES2133441T3/es not_active Expired - Lifetime
- 1994-05-09 DE DE69419567T patent/DE69419567T2/de not_active Expired - Fee Related
- 1994-05-27 CA CA002124525A patent/CA2124525C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE69419567D1 (de) | 1999-08-26 |
CA2124525C (en) | 1997-12-23 |
DE69419567T2 (de) | 1999-11-18 |
EP0627439A1 (en) | 1994-12-07 |
CA2124525A1 (en) | 1994-12-02 |
US5332846A (en) | 1994-07-26 |
EP0627439B1 (en) | 1999-07-21 |
US5344988A (en) | 1994-09-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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