ES2132885T3 - Empleo de derivados de pirazol dificilmente volatiles con grupos hidrofilos como inhibidores de nitrificacion. - Google Patents

Empleo de derivados de pirazol dificilmente volatiles con grupos hidrofilos como inhibidores de nitrificacion.

Info

Publication number
ES2132885T3
ES2132885T3 ES96902925T ES96902925T ES2132885T3 ES 2132885 T3 ES2132885 T3 ES 2132885T3 ES 96902925 T ES96902925 T ES 96902925T ES 96902925 T ES96902925 T ES 96902925T ES 2132885 T3 ES2132885 T3 ES 2132885T3
Authority
ES
Spain
Prior art keywords
sup
sub
rest
hydrogen
halogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96902925T
Other languages
English (en)
Inventor
Stefan Rittinger
Norbert Rieber
Randall Evan Gold
Jurgen Dressel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2132885T3 publication Critical patent/ES2132885T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/16—Halogen atoms or nitro radicals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
    • Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

USO DE DERIVADOS PIRAZOLICOS DE FORMULA GENERAL (I) COMO INHIBIDORES DE NITRIFICACION, EN LA QUE LOS RESTOS R{SUP,1}, R{SUP,2}, R{SUP,3} Y R{SUP,4} TIENEN EL SIGNIFICADO SIGUIENTE: R{SUP,1}, R{SUP,2} Y R{SUP,3} HALOGENO, NITRO, HIDROGENO, C{SUB,1} {SUB,5}UIDOS ESTOS 4 RESTOS DE FORMA SIMPLE O DOBLE POR HALOGENO Y /O HIDROXILO, R{SUP,4} PUEDE SER A) UN RESTO R{SUP,4A} DE FORMULA (II), EN LA QUE R{SUP,5} Y R{SUP,6} ES HIDROGENO, C{SUB,1}C{SUB,20}-ALQUILO QUE PUEDE SER SUSTITUIDO DE FORMA SIMPLE O DOBLE POR HALOGENO Y/O HIDROXILO, UN GRUPO CARBOXILO, UN GRUPO CARBOXIMETILICO O UN DERIVADO FUNCIONAL DE LOS DOS GRUPOS MENCIONADOS EN ULTIMO LUGAR, Y R{SUP,7} ES UN RESTO CARBOXILO O UN RESTO CARBOXI-(C{SUP,1}CIONAL DE ESTOS GRUPOS, O B) UN RESTO R{SUP,4B} DE FORMULA (III), EN LA QUE R{SUB,8} Y R{SUB,9} ES HIDROGENO C{SUB,1} UB,20}-ALQUILO, C{SUB,3}C{SUB,20}-ARILO O ALQUILOARILO, PUDIENDO SER SUSTITUIDOS ESTOS RESTOS DE FORMA DOBLE O SIMPLE POR HALOGENO, Y R{SUP,10} ES HIDROGENO O UN RESTO POLI-(C{SUB,2} O)RESTO, CUYO GRUPO HIDROXILO TERMINAL PUEDE SER ETERIFICADO CON UN C{SUB,1} ON UN C{SUB,1}- A C{SUB,10}-ACIDO CARBOXILICO.
ES96902925T 1995-02-06 1996-01-26 Empleo de derivados de pirazol dificilmente volatiles con grupos hidrofilos como inhibidores de nitrificacion. Expired - Lifetime ES2132885T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19503827A DE19503827A1 (de) 1995-02-06 1995-02-06 Verwendung von schwerflüchtigen Pyrazolderivaten mit hydrophilen Gruppen als Nitrifikationsinhibitoren

Publications (1)

Publication Number Publication Date
ES2132885T3 true ES2132885T3 (es) 1999-08-16

Family

ID=7753277

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96902925T Expired - Lifetime ES2132885T3 (es) 1995-02-06 1996-01-26 Empleo de derivados de pirazol dificilmente volatiles con grupos hidrofilos como inhibidores de nitrificacion.

Country Status (10)

Country Link
US (1) US5972064A (es)
EP (1) EP0808297B1 (es)
JP (1) JPH11500111A (es)
AU (1) AU4714396A (es)
CA (1) CA2210529A1 (es)
DE (2) DE19503827A1 (es)
ES (1) ES2132885T3 (es)
MY (1) MY117671A (es)
TW (1) TW336226B (es)
WO (1) WO1996024566A1 (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10135423A1 (de) * 2000-08-08 2002-02-21 Piesteritz Stickstoff 1H-Pyrazol-Derivate, Verfahren zu ihrer Herstellung und ihre Verwendung als Nitrifikationsinhibitoren
DE10343277A1 (de) 2003-09-18 2005-04-21 Piesteritz Stickstoff N-(1H-Azolyl-methyl)amide, Verfahren zu ihrer Herstellung und ihre Verwendung als Nitrifikationsinhibitoren
DE102006015705B4 (de) 2006-04-04 2018-07-19 Skw Stickstoffwerke Piesteritz Gmbh 1,2-Bis-(azol-1-yl)-ethan-1,2-diol-Derivate, Verfahren zu ihrer Herstellung und ihre Verwendung als Nitrifikationsinhibitoren
DE102007007750A1 (de) 2006-08-17 2008-02-21 Bayer Cropscience Ag Avermectinderivate
DE102008020785B4 (de) 2008-04-25 2021-11-04 Skw Stickstoffwerke Piesteritz Gmbh Verwendung von einfachen Derivaten von 5-Amino-1,2,4-thiadiazol zur Hemmung bzw. Steuerung der Nitrifikation
DE102011120098B4 (de) 2011-12-02 2021-02-11 Skw Stickstoffwerke Piesteritz Gmbh N-(1H-Pyrazolyl-methyl)formamide, Verfahren zu ihrer Herstellung und ihre Verwendung als Nitrifikationsinhibitoren
BR112016013578B1 (pt) 2013-12-13 2022-02-08 Eurochem Agro Gmbh Mistura fertilizante contendo inibidor de nitrificação e processos para sua produção e para a fertilização de solos
CN107108386B (zh) * 2014-12-18 2021-05-04 巴斯夫欧洲公司 作为硝化抑制剂的炔基吡唑类
TR201815697T4 (tr) 2015-06-22 2018-11-21 Eurochem Agro Gmbh Üre ihtiva eden gübrelerin işlenmesi için karışım.
EP3615495A1 (en) * 2017-04-24 2020-03-04 EuroChem Agro GmbH Method and composition for improving nutrient acquisition of plants
AU2018387013B2 (en) 2017-12-22 2024-06-06 Basf Se Aqueous composition comprising 2-(dimethyl-1H-pyrazole-1-yl) succinic acid and ammonia
WO2019121228A1 (en) 2017-12-22 2019-06-27 Basf Se Aqueous composition comprising 2-(dimethyl-1h-pyrazole-1-yl) succinic acid and at least one metal hydroxide
WO2019121226A1 (en) 2017-12-22 2019-06-27 Basf Se Aqueous composition comprising 2-(dimethyl-1h-pyrazole-1-yl) succinic acid and at least one further acid
CA3093781A1 (en) * 2018-02-28 2019-09-06 Basf Se Use of n-functionalized alkoxy pyrazole compounds as nitrification inhibitors
DE102018208770A1 (de) 2018-06-04 2019-12-05 Eurochem Agro Gmbh Emulsion zur Behandlung von harnstoffhaltigen Düngemitteln
BR112021007858A2 (pt) 2018-11-29 2021-08-03 Basf Se mistura, método de obtenção de uma mistura e uso de uma composição
EP4317121A3 (en) 2018-12-21 2024-05-01 Basf Se Process for obtaining a fertilizer composition comprising a dmpsa nitrification inhibitor via adding dmpsa salts into the fertilizer melt
WO2020126645A1 (en) 2018-12-21 2020-06-25 Basf Se Process for preparing 2-(3, 4-dimethyl- 1 h-pyrazole-1 -yl) succinic acid and 2-(4, 5-dim ethyl- 1 h-pyrazole-1 -yl) succinic acid in a two phase solvent system
EP4211097A2 (en) 2020-09-14 2023-07-19 EuroChem Antwerpen N-heterocyclic compounds used as nitrification inhibitor
US20230357099A1 (en) 2020-09-14 2023-11-09 Eurochem Antwerpen Pyrazolo [3,4-b] pyridine-4-carboxamide nitrification inhibitor
WO2022053659A2 (en) 2020-09-14 2022-03-17 Eurochem Antwerpen Heterocyclic compounds used as nitrification inhibitor
CN112321508A (zh) * 2020-11-06 2021-02-05 浙江今晖新材料股份有限公司 一种硝化抑制剂的制备方法
WO2023169964A1 (en) 2022-03-09 2023-09-14 Eurochem Antwerpen Use of pyrazolo[3,4-b]pyridine compounds as nitrification inhibitor
EP4242195A1 (en) 2022-03-09 2023-09-13 EuroChem Antwerpen Use of pyrazolo[3,4-b]pyridine compounds as nitrification inhibitor

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE133088C (es) *
DE131063C (es) *
US3303200A (en) * 1963-11-05 1967-02-07 American Home Prod Pyrazole-1-ethanol derivatives
US3635690A (en) * 1968-05-16 1972-01-18 Dow Chemical Co Soil treating method and composition for conserving nitrogen in soil by addition of a pyrazole thereto
US4089672A (en) * 1972-12-20 1978-05-16 The Upjohn Company 1-(Substituted-hydrocarbyl)-di- and trihalopyrazoles
DE2745833C2 (de) * 1977-10-12 1986-10-16 VEB Fahlberg-List Chemische und pharmazeutische Fabriken, DDR 3013 Magdeburg Mittel zur Hemmung bzw. Regelung der Nitrifikation von Ammoniumstickstoff in Kulturböden
FR2406616A1 (fr) * 1977-10-24 1979-05-18 Fahlberg List Veb Agents d'inhibition ou de reglage de la nitrification de l'azote ammoniacal dans les sols cultives
NL183578C (nl) * 1977-10-24 1988-12-01 Fahlberg List Veb Werkwijze ter bereiding van een middel voor het remmen of regelen van de nitrificatie van ammoniumstikstof in cultuurbodem.
DE3332271A1 (de) * 1983-09-07 1985-03-21 Bayer Ag, 5090 Leverkusen Herbizide mittel enthaltend metribuzin in kombination mit substituierten azolyl-derivaten
DE3409317A1 (de) * 1984-03-14 1985-09-19 Basf Ag, 6700 Ludwigshafen Nitrifikationsinhibierende 1-hydroxipyrazol-derivate
SU1488291A1 (ru) * 1987-01-19 1989-06-23 Dzerzhinsky Gni Pi Azotnoj Способ ингибирования процесса нитрификации карбамида в почве
DE3704359A1 (de) * 1987-02-12 1988-08-25 Basf Ag Azolhalbaminal-derivate und ihre verwendung als nitrifikationsinhibitoren

Also Published As

Publication number Publication date
WO1996024566A1 (de) 1996-08-15
TW336226B (en) 1998-07-11
EP0808297A1 (de) 1997-11-26
US5972064A (en) 1999-10-26
DE19503827A1 (de) 1996-08-08
AU4714396A (en) 1996-08-27
EP0808297B1 (de) 1999-05-12
JPH11500111A (ja) 1999-01-06
CA2210529A1 (en) 1996-08-15
DE59601878D1 (de) 1999-06-17
MY117671A (en) 2004-07-31

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