ES2128164T3 - Procedimiento para la obtencion de alfa,beta-diaminoacrilonitrilos. - Google Patents

Procedimiento para la obtencion de alfa,beta-diaminoacrilonitrilos.

Info

Publication number
ES2128164T3
ES2128164T3 ES96905802T ES96905802T ES2128164T3 ES 2128164 T3 ES2128164 T3 ES 2128164T3 ES 96905802 T ES96905802 T ES 96905802T ES 96905802 T ES96905802 T ES 96905802T ES 2128164 T3 ES2128164 T3 ES 2128164T3
Authority
ES
Spain
Prior art keywords
sup
radicals
alkaline
radical
ring
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96905802T
Other languages
English (en)
Inventor
Michael Henningsen
Christof Kandzia
Sven Doye
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2128164T3 publication Critical patent/ES2128164T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C07C303/22Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof from sulfonic acids, by reactions not involving the formation of sulfo or halosulfonyl groups; from sulfonic halides by reactions not involving the formation of halosulfonyl groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/01Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/30Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the same unsaturated acyclic carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00Preparation of carboxylic acid nitriles
    • C07C253/08Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/32Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of salts of sulfonic acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D241/00Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/02Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
    • C07D241/06Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having one or two double bonds between ring members or between ring members and non-ring members

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Hydrogenated Pyridines (AREA)

Abstract

SE PROPONE UN PROCEDIMIENTO MEJORADO PARA LA PREPARACION DE {AL},{BE} UP,3}R{SUP,2}NC(R{SUP,1}) = C(NR{SUP,2}R{SUP,3})CN, EN DONDE R{SUP,1} CORRESPONDE A HIDROGENO, RADICALES ALIFATICOS CON 1 A 30 ATOMOS DE CARBONO, RADICALES CICLOALIFATICOS CON 3 A 8 MIEMBROS DE ANILLO O A RADICALES AROMATICOS, HETEROAROMATICOS O ARALIFATICOS CON 7 A 12 ATOMOS DE CARBONO, PUDIENDO SER ESTOS RADICALES TAMBIEN SUSTITUIDOS; R{SUP,2} Y R{SUP,3} SON IGUALES O DIFERENTES Y SIGNIFICAN HIDROGENO O UN RADICAL ALIFATICO CON 1 A 15 ATOMOS DE CARBONO, UN RADICAL CICLOALIFATICO CON 3 A 8 MIEMBROS DE ANILLO O UN RADICAL AROMATICO, HETEROCICLICO O ARALIFATICO CON 7 A 12 ATOMOS DE CARBONO Y PUDIENDO UNIRSE TAMBIEN LOS RADICALES R{SUP,2} Y R{SUP,3} CONJUNTAMENTE A UN ANILLO DE 5 PROCEDIMIENTO, EL COMPONENTE A) ES TRANSFORMADO EN EL ORDEN DESEADO CON LOS COMPONENTES B), C) Y D). A) ES UN COMPUESTO {AL} UP,1} TIENE EL SIGNIFICADO ARRIBA MENCIONADO O ES UN DERIVADO REACTIVO DE ESTE COMPUESTO DE CARBONILO; B) ES UNA SAL DE ACIDO SULFUROSO, DIOXIDO DE AZUFRE O UN REACTIVO QUE SUMINISTRA DIOXIDO DE AZUFRE; C) ES UNA AMINA DE FORMULA GENERAL HNR{SUP,2}R{SUP,3}, O UNA DIAMINA ALIFATICA DE FORMULA GENERAL R{SUP,3}HN -(CH{SUB,2}){SUB,N} LENO PUEDE PORTAR TAMBIEN UN SUSTITUYENTE R{SUP,1}, TENIENDO R{SUP,1} Y R{SUP,3} EL SIGNIFICADO ARRIBA MENCIONADO Y SIENDO N LOS NUMEROS 2 O 3, O SON DERIVADOS QUE SON CONVERTIDOS EN AMINA O DIAMINA EN CONDICIONES DE REACCION; D) ES UN ACIDO CIANHIDRICO LIQUIDO O GASEOSO O UN REACTIVO QUE SUMINISTRA ACIDO CIANHIDRICO. LA TRANSFORMACION REFERIDA A UN MOL DE COMPONENTE A, ES REALIZADA CON AL MENOS 3,5 COMPUESTOS ALCALINOS EQUIVALENTES. LA MAYOR PARTE DE LOS COMPUESTOS ALCALINOS ESTA FORMADA POR COMPUESTOS DE POTASIO, AÑADIENDOSE AL MENOS UN EQUIVALENTE ALCALINO COMO LEJIA ALCALINA LIBRE, SIEMPRE QUE LA PROPORCION DE EQUIVALENTES DE POTASIO SEA LO SUFICIENTEMENTE ELEVADA COMO PARA QUE AL FINAL DE LA REACCION TODAS LAS SALES INORGANICAS PERMANEZCAN EN LA SOLUCION PRACTICAMENTE ENTERAS.
ES96905802T 1995-03-03 1996-02-27 Procedimiento para la obtencion de alfa,beta-diaminoacrilonitrilos. Expired - Lifetime ES2128164T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19507463A DE19507463A1 (de) 1995-03-03 1995-03-03 Verfahren zur Herstellung von alpha,beta-Diaminoacrylnitrilen

Publications (1)

Publication Number Publication Date
ES2128164T3 true ES2128164T3 (es) 1999-05-01

Family

ID=7755555

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96905802T Expired - Lifetime ES2128164T3 (es) 1995-03-03 1996-02-27 Procedimiento para la obtencion de alfa,beta-diaminoacrilonitrilos.

Country Status (8)

Country Link
EP (1) EP0813518B1 (es)
JP (1) JPH11501039A (es)
KR (1) KR19980702697A (es)
CN (1) CN1177344A (es)
DE (2) DE19507463A1 (es)
DK (1) DK0813518T3 (es)
ES (1) ES2128164T3 (es)
WO (1) WO1996027582A1 (es)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3434525A1 (de) * 1984-09-20 1986-03-27 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von (alpha),(beta)-diaminoacrylnitrilen

Also Published As

Publication number Publication date
WO1996027582A1 (de) 1996-09-12
DE59601049D1 (de) 1999-02-04
JPH11501039A (ja) 1999-01-26
DE19507463A1 (de) 1996-09-05
KR19980702697A (ko) 1998-08-05
EP0813518A1 (de) 1997-12-29
CN1177344A (zh) 1998-03-25
EP0813518B1 (de) 1998-12-23
DK0813518T3 (da) 1999-08-23

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