ES2108804T3 - Poliuretanos puros, particularmente exentos de catalizadores. - Google Patents

Poliuretanos puros, particularmente exentos de catalizadores.

Info

Publication number
ES2108804T3
ES2108804T3 ES93119952T ES93119952T ES2108804T3 ES 2108804 T3 ES2108804 T3 ES 2108804T3 ES 93119952 T ES93119952 T ES 93119952T ES 93119952 T ES93119952 T ES 93119952T ES 2108804 T3 ES2108804 T3 ES 2108804T3
Authority
ES
Spain
Prior art keywords
preaduct
acidal
aliphaic
macrodiol
nco
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93119952T
Other languages
English (en)
Inventor
Hanns-Peter Dr Muller
Rolf Dr Dhein
Herbert Dr Hugl
Heinz Dr Pudleiner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Application granted granted Critical
Publication of ES2108804T3 publication Critical patent/ES2108804T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/773—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur halogens
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L27/00—Materials for grafts or prostheses or for coating grafts or prostheses
    • A61L27/14—Macromolecular materials
    • A61L27/18—Macromolecular materials obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L29/00—Materials for catheters, medical tubing, cannulae, or endoscopes or for coating catheters
    • A61L29/04—Macromolecular materials
    • A61L29/06—Macromolecular materials obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
    • A61L31/04—Macromolecular materials
    • A61L31/06—Macromolecular materials obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3212—Polyhydroxy compounds containing cycloaliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44—Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/02—Applications for biomedical use

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Epidemiology (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Dermatology (AREA)
  • Transplantation (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Surgery (AREA)
  • Vascular Medicine (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Wrappers (AREA)
  • Materials For Medical Uses (AREA)

Abstract

LA PRESENTE INVENCION SE REFIERE A POLIURETANO PURO CONTENIENDO DIISOCIANATO CICLOALIFATICO Y/O ALIFATICO, MACRODIOL DE MG 500 A 1000 Y PROLONGAR DE CADENA DE MG 62 A 400, OBTENIDO A TRAVES DE LA TRANSFORMACION DE DIISOCIANATO ALIFATICO Y/O CICLOALIFATICO CON UN MACRODIOL A UN PREADUCTO PRESENTANDO UN GRUPO NCO-, POR LO QUE SE EMPLEA 0,5 A 22 MOLES DE DIISOCIANATO POR MOL DE MACRODIOL Y LA PROLONGACION DE CADENA DEL PREADUCTO SE EFECTUA CON DIOLES ALIFATICOS Y/O CICLOALIFATICOS DE BAJO PESO MOLECULAR, EN CASO DADO OTRO ISOCIANATO LA RELACION NCO/OH ACION DEL PREADUCTO SE REALIZA ENTRE 90 Y 150 C Y LA PROLONGACION DE CADENA SE EFECTUA A UNA TEMPERATURA DE 120 A 230 C, CON LA MEDIDA YA QUE LAS CONDICIONES DE REACCION MENCIONADAS SE MANTIENEN POR LO MENOS LARGO TIEMPO, SE LOGRAN HASTA UNA VISCOSIDAD EN ESTADO FUNDIDO DE POR LO MENOS DE 2500 MPA,S MEDIDA A 120 C Y A CONTINUACION EN CASO DADO A UNA TEMPERATURA DE HASTA 240 C SE CONDUCE LA POLIADICION DE UN PUNTO TEMPORAL CUALQUIERA AL FINAL. ELPOLIURETANO ENCUENTRA APLICACION PREFERENTE EN LA TECNICA MEDICINAL.
ES93119952T 1992-12-23 1993-12-10 Poliuretanos puros, particularmente exentos de catalizadores. Expired - Lifetime ES2108804T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4243782 1992-12-23
DE4315173A DE4315173A1 (de) 1992-12-23 1993-05-07 Reine, insbesondere katalysatorfreie Polyurethane

Publications (1)

Publication Number Publication Date
ES2108804T3 true ES2108804T3 (es) 1998-01-01

Family

ID=25921687

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93119952T Expired - Lifetime ES2108804T3 (es) 1992-12-23 1993-12-10 Poliuretanos puros, particularmente exentos de catalizadores.

Country Status (9)

Country Link
US (1) US5374704A (es)
EP (1) EP0603675B1 (es)
JP (1) JPH06228265A (es)
KR (1) KR940014477A (es)
CA (1) CA2111926A1 (es)
DE (2) DE4315173A1 (es)
DK (1) DK0603675T3 (es)
ES (1) ES2108804T3 (es)
TW (1) TW243457B (es)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19504414C2 (de) * 1995-02-10 1996-12-05 Pharmacia Gmbh Schlauch für einen medizinischen Behälter
AU2908795A (en) * 1995-03-31 1996-10-16 Mentor Corporation A male condom catheter, a method for making a male condom ca theter and a male condom catheter produced by the method
US7728049B2 (en) * 1996-10-08 2010-06-01 Zamore Alan M Irradiation conversion of thermoplastic to thermoset polymers
US7749585B2 (en) 1996-10-08 2010-07-06 Alan Zamore Reduced profile medical balloon element
US5900444A (en) * 1996-10-08 1999-05-04 Zamore; Alan Irradiation conversion of thermoplastic to thermoset polyurethane
US6656550B1 (en) 1996-10-08 2003-12-02 Alan M. Zamore Dilatation device of uniform outer diameter
GB9915932D0 (en) * 1999-07-08 1999-09-08 Sterilox Med Europ Ltd Oxidation-resistant endoscope coatings
DE10020163B4 (de) * 2000-04-25 2007-05-31 Bayer Materialscience Ag Aliphatische thermoplastische Polyurethane und ihre Verwendung
DE60102209T2 (de) 2000-12-26 2005-02-03 Ube Industries, Ltd., Ube Thermoplastische Polyurethane
US8501165B2 (en) * 2001-12-12 2013-08-06 Promethean Surgical Devices Llc In situ bonds
KR100432707B1 (ko) * 2001-12-31 2004-05-24 주식회사 디피아이 일액형 폴리우레탄 수지 조성물
US20060216267A1 (en) * 2002-08-20 2006-09-28 Kovacs Stephen G Hydrophobic elastomeric polymer chemistry device for inhibiting the growth of onychomycosis and urushiol-induced allergic contact dermatitis
DE10242075B4 (de) * 2002-09-11 2007-02-01 Curasan Ag Knochenadhäsives Polyurethanpolymer, Verfahren zu seiner Herstellung und seine Verwendungen
DE10243966A1 (de) * 2002-09-20 2004-04-01 Adiam Life Science Ag Verfahren zur Herstellung von biokompatiblen Polyurethanen
DE10243965A1 (de) * 2002-09-20 2004-04-01 Adiam Life Science Ag Verfahren zur Herstellung von biokompatiblen Polyurethanen
GB0222522D0 (en) 2002-09-27 2002-11-06 Controlled Therapeutics Sct Water-swellable polymers
US6984709B2 (en) * 2002-12-20 2006-01-10 Noveon Ip Holdings Corp. Organometallic-free polyurethanes having low extractables
EP1594908B1 (en) 2003-02-19 2012-08-01 Orteq B.V. Method for the preparation of new segmented polyurethanes with high tear and tensile strengths and method for making porous scaffolds
EP1633275B1 (en) * 2003-05-15 2017-11-29 Biomerix Corporation Reticulated elastomeric matrices, their manufacture and use in implantable devices
GB0417401D0 (en) 2004-08-05 2004-09-08 Controlled Therapeutics Sct Stabilised prostaglandin composition
US20090177226A1 (en) * 2005-05-05 2009-07-09 Jon Reinprecht Bioabsorbable Surgical Compositions
US20100100124A1 (en) * 2005-05-05 2010-04-22 Tyco Healthcare Group Lp Bioabsorbable surgical composition
US8044234B2 (en) * 2005-05-05 2011-10-25 Tyco Healthcare Group Lp Bioabsorbable surgical composition
WO2007067624A2 (en) 2005-12-06 2007-06-14 Tyco Healthcare Group Lp Bioabsorbable compounds and compositions containing them
JP2009518519A (ja) 2005-12-06 2009-05-07 タイコ ヘルスケア グループ リミテッド パートナーシップ 官能化ポリエチレングリコールのカルボジイミド架橋
EP1962867B1 (en) 2005-12-06 2013-06-19 Covidien LP Biocompatible surgical compositions
JP5088894B2 (ja) 2005-12-06 2012-12-05 タイコ ヘルスケア グループ リミテッド パートナーシップ 生体適合性組織封止剤および接着剤
JP2009518129A (ja) 2005-12-06 2009-05-07 タイコ ヘルスケア グループ リミテッド パートナーシップ 生体吸収性外科用組成物
CA2630327C (en) 2005-12-08 2015-05-26 Tyco Healthcare Group Lp Biocompatible surgical compositons
GB0613333D0 (en) 2006-07-05 2006-08-16 Controlled Therapeutics Sct Hydrophilic polyurethane compositions
GB0613638D0 (en) 2006-07-08 2006-08-16 Controlled Therapeutics Sct Polyurethane elastomers
GB0620685D0 (en) 2006-10-18 2006-11-29 Controlled Therapeutics Sct Bioresorbable polymers
JP5375606B2 (ja) * 2007-06-21 2013-12-25 株式会社カネカ 耐久性に優れた湿潤時潤滑性表面コーティング用組成物、コーティング液、表面コーティング、ならびに表面コーティング方法と、この表面コーティングを有する医療用具
US8182647B2 (en) * 2007-07-23 2012-05-22 Cohera Medical, Inc. Hydrophilic biodegradable adhesives
US8771725B2 (en) * 2007-10-12 2014-07-08 Chesson Laboratory Associates, Inc. Poly(urea-urethane) compositions useful as topical medicaments and methods of using the same
US20110105635A1 (en) * 2008-05-19 2011-05-05 Orteq B.V. Polyurethane foam for use in medical implants
EP2382255B1 (de) * 2008-12-29 2018-07-18 Basf Se Lichtleiter aus thermoplastischen polyurethanen
KR102440987B1 (ko) * 2014-07-31 2022-09-06 쓰리엠 이노베이티브 프로퍼티즈 컴파니 열가소성 폴리우레탄 조성물, 그의 물품 및 방법
TWI730948B (zh) 2014-12-08 2021-06-21 芬蘭商拜耳股份有限公司 新穎的熱塑性聚胺甲酸酯，彼等材料於製造子宮內系統之ｔ-框架之用途及由此等材料製成之ｔ-框架
WO2016151516A1 (en) * 2015-03-24 2016-09-29 Mazzucchelli 1849 S.P.A. Sheet of thermoplastic polyurethane obtained by process
CN112251016A (zh) * 2020-10-23 2021-01-22 苏州中核华东辐照有限公司 一种耐伽马照射材料及其制备方法
CN113308207B (zh) * 2021-05-31 2022-10-28 东莞市雄林新材料科技股份有限公司 一种防泼水tpu热熔胶薄膜及其制备方法

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FR1497772A (fr) * 1965-11-05 1967-10-13 Perfectionnements apportés aux procédés de préparation d'élastomères de polyuréthane, stables à la lumière, et produits ainsi obtenus
US4024113A (en) * 1976-04-28 1977-05-17 Ppg Industries, Inc. Polycarbonate polyurethanes based on particular aliphatic/cycloaliphatic polycarbonates
US4332927A (en) * 1980-11-14 1982-06-01 Caschem, Inc. Catalyst-containing stable polyurethane forming compositions which are non-cytotoxic when cured and separatory devices employing same
DE3341847A1 (de) * 1983-11-19 1985-06-13 Akzo Gmbh, 5600 Wuppertal Membranen aus diisocyanat-additionspolymeren fuer haemodialyse und/oder haemofiltration
DE3643465A1 (de) * 1986-12-19 1988-07-07 Akzo Gmbh Biokompatible polyurethane
CA2038605C (en) * 1990-06-15 2000-06-27 Leonard Pinchuk Crack-resistant polycarbonate urethane polymer prostheses and the like
AU664158B2 (en) * 1990-09-12 1995-11-09 Polymedica Industries, Inc Biostable polyurethane products

Also Published As

Publication number Publication date
DE59307673D1 (de) 1997-12-18
KR940014477A (ko) 1994-07-18
JPH06228265A (ja) 1994-08-16
CA2111926A1 (en) 1994-06-24
EP0603675B1 (de) 1997-11-12
DE4315173A1 (de) 1994-06-30
EP0603675A1 (de) 1994-06-29
TW243457B (es) 1995-03-21
DK0603675T3 (da) 1998-07-27
US5374704A (en) 1994-12-20

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