ES2108338T3 - Recuperacion de catalizador acido agotado procedente de la alquilacion de hidrocarburos. - Google Patents

Recuperacion de catalizador acido agotado procedente de la alquilacion de hidrocarburos.

Info

Publication number
ES2108338T3
ES2108338T3 ES94109869T ES94109869T ES2108338T3 ES 2108338 T3 ES2108338 T3 ES 2108338T3 ES 94109869 T ES94109869 T ES 94109869T ES 94109869 T ES94109869 T ES 94109869T ES 2108338 T3 ES2108338 T3 ES 2108338T3
Authority
ES
Spain
Prior art keywords
acid
rental
hydrocarbons
recovery
acid catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94109869T
Other languages
English (en)
Inventor
Sven Ivar Hommeltoft
Claus J H Jacobsen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Topsoe AS
Original Assignee
Haldor Topsoe AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haldor Topsoe AS filed Critical Haldor Topsoe AS
Application granted granted Critical
Publication of ES2108338T3 publication Critical patent/ES2108338T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

SE PRESENTA UN METODO PARA LA RECUPERACION DE UN CATALIZADOR ACIDO A PARTIR DE ACEITE SOLUBLE EN ACIDO QUE SE FORMA EN UN PROCESO PARA LA ALQUILACION DE HIDROCARBONOS Y QUE CONTIENE CANTIDADES VALIOSAS DE CATALIZADOR ACIDO AGOTADO, DICHO METODO COMPRENDE: EL TRATAMIENTO DEL ACEITE SOLUBLE EN ACIDO CON HIDROGENO EN LA PRESENCIA DE UN CATALIZADOR QUE COMPRENDA UNO O MAS METALES ESCOGIDOS ENTRE EL GRUPO VIII DE LA TABLA PERIODICA SOPORTADOS EN UN PORTADOR RESISTENTE AL ACIDO; Y EL TRATAMIENTO DEL ACEITE SOLUBLE EN ACIDO HIDROTRATADO PARA EL PROCESO DE ALQUILACION.
ES94109869T 1993-07-06 1994-06-27 Recuperacion de catalizador acido agotado procedente de la alquilacion de hidrocarburos. Expired - Lifetime ES2108338T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DK081393A DK171701B1 (da) 1993-07-06 1993-07-06 Fremgangsmåde til genvinding af brugt syrekatalysator fra alkylering af carbonhydrider

Publications (1)

Publication Number Publication Date
ES2108338T3 true ES2108338T3 (es) 1997-12-16

Family

ID=8097863

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94109869T Expired - Lifetime ES2108338T3 (es) 1993-07-06 1994-06-27 Recuperacion de catalizador acido agotado procedente de la alquilacion de hidrocarburos.

Country Status (6)

Country Link
US (1) US5457258A (es)
EP (1) EP0633063B1 (es)
DE (1) DE69405654T2 (es)
DK (1) DK171701B1 (es)
ES (1) ES2108338T3 (es)
RU (1) RU2122991C1 (es)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3140163A (en) * 1961-03-17 1964-07-07 Bischoff Gottfried Apparatus for cleaning gases
DK173114B1 (da) * 1994-06-02 2000-01-31 Topsoe Haldor As Fremgangsmåde til genvinding af brugt sulfonsyrekatalysator samt anvendelse af fremgangsmåden
DK172906B1 (da) * 1996-06-17 1999-09-27 Topsoe Haldor As Fremgangsmåde til fjernelse af korrosive bestanddele fra en fluidastrøm
EP1044963A3 (en) * 1999-03-30 2001-05-16 Haldor Topsoe A/S Process for the recovery of perfluorinated sulphonic acids from spent acid
US20060058174A1 (en) * 2004-09-10 2006-03-16 Chevron U.S.A. Inc. Highly active slurry catalyst composition
US7737073B2 (en) * 2004-09-10 2010-06-15 Chevron U.S.A. Inc. Hydroprocessing bulk catalyst and uses thereof
US7485267B2 (en) * 2005-07-29 2009-02-03 Chevron U.S.A. Inc. Process for metals recovery from spent catalyst
US7674369B2 (en) 2006-12-29 2010-03-09 Chevron U.S.A. Inc. Process for recovering ultrafine solids from a hydrocarbon liquid
FI20085400A0 (fi) 2007-11-09 2008-04-30 Upm Kymmene Oyj Menetelmä jäteveden integroidulle käsittelylle
US7846404B2 (en) * 2007-11-28 2010-12-07 Chevron U.S.A. Inc. Process for separating and recovering base metals from used hydroprocessing catalyst
US8221710B2 (en) * 2007-11-28 2012-07-17 Sherritt International Corporation Recovering metals from complex metal sulfides
US7837960B2 (en) * 2007-11-28 2010-11-23 Chevron U.S.A. Inc. Process for separating and recovering base metals from used hydroprocessing catalyst
US7658895B2 (en) * 2007-11-28 2010-02-09 Chevron U.S.A. Inc Process for recovering base metals from spent hydroprocessing catalyst
CN102361994B (zh) * 2009-03-25 2015-04-01 雪佛龙美国公司 从含废催化剂的煤液化残余物中回收金属的方法
US8389433B2 (en) * 2009-11-24 2013-03-05 Chevron U.S.A. Hydroprocessing bulk catalyst and methods of making thereof
US8372776B2 (en) * 2009-11-24 2013-02-12 Chevron U.S.A. Inc. Hydroprocessing bulk catalyst and methods of making thereof
US8815184B2 (en) 2010-08-16 2014-08-26 Chevron U.S.A. Inc. Process for separating and recovering metals
US8704018B2 (en) 2012-07-31 2014-04-22 Chevron U.S.A. Inc. Extracted conjunct polymer naphtha
US9321037B2 (en) 2012-12-14 2016-04-26 Chevron U.S.A., Inc. Hydroprocessing co-catalyst compositions and methods of introduction thereof into hydroprocessing units
US9687823B2 (en) 2012-12-14 2017-06-27 Chevron U.S.A. Inc. Hydroprocessing co-catalyst compositions and methods of introduction thereof into hydroprocessing units

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2547838A1 (de) * 1974-12-30 1976-07-08 Texaco Development Corp Verfahren zur entfernung von fluorverbindungen aus verbrauchtem, fluorsulfonsaeure und schwefelsaeure enthaltendem alkylierungskatalysator und gegebenenfalls regenerierung des katalysators
US4033899A (en) * 1974-12-30 1977-07-05 Texaco Inc. Alkylation fluosulfonic-sulfuric acid catalyst recovery process with silica-alumina removal of fluoride compounds
US3975164A (en) * 1975-02-05 1976-08-17 Phillips Petroleum Company Apparatus for purifying HF catalyst in an alkylation process
US4130593A (en) * 1976-01-19 1978-12-19 The Standard Oil Company Alkylation process utilizing the hydrocarbon phase from a reactor for condensing a vaporous distillation effluent
JPS6031522B2 (ja) * 1976-02-27 1985-07-23 日石三菱株式会社 反応生成物から酸性物質を除去する方法
JPS5524144A (en) * 1978-08-10 1980-02-21 Nippon Petrochem Co Ltd Aralkylation process
US4677090A (en) * 1984-06-11 1987-06-30 Exxon Research And Engineering Company Liquid catalyst for hydrocarbon conversion reactions
US4962268A (en) * 1989-02-22 1990-10-09 Phillips Petroleum Company Alkylation catalyst isolation
DK168520B1 (da) * 1989-12-18 1994-04-11 Topsoe Haldor As Fremgangsmåde til væskefase-alkylering af et carbonhydrid med et olefinalkyleringsmiddel
US5202518A (en) * 1991-09-18 1993-04-13 Mobil Oil Corporation Liquid acid alkylation catalyst and isoparaffin:olefin alkylation process

Also Published As

Publication number Publication date
RU2122991C1 (ru) 1998-12-10
EP0633063B1 (en) 1997-09-17
US5457258A (en) 1995-10-10
RU94023252A (ru) 1996-05-27
DE69405654T2 (de) 1998-01-22
DK81393D0 (da) 1993-07-06
DK171701B1 (da) 1997-04-01
DE69405654D1 (de) 1997-10-23
EP0633063A1 (en) 1995-01-11
DK81393A (da) 1995-01-07

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