ES2105692T3 - Procedimiento para fabricar un producto polimero extrusionado reticulado. - Google Patents

Procedimiento para fabricar un producto polimero extrusionado reticulado.

Info

Publication number
ES2105692T3
ES2105692T3 ES94913598T ES94913598T ES2105692T3 ES 2105692 T3 ES2105692 T3 ES 2105692T3 ES 94913598 T ES94913598 T ES 94913598T ES 94913598 T ES94913598 T ES 94913598T ES 2105692 T3 ES2105692 T3 ES 2105692T3
Authority
ES
Spain
Prior art keywords
polymer
liquid
procedure
reticulated
manufacturing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94913598T
Other languages
English (en)
Other versions
ES2105692T5 (es
Inventor
Werner Kempter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bernhard Rustige und Co K GmbH
Original Assignee
Bernhard Rustige und Co K GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6486181&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2105692(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Bernhard Rustige und Co K GmbH filed Critical Bernhard Rustige und Co K GmbH
Application granted granted Critical
Publication of ES2105692T3 publication Critical patent/ES2105692T3/es
Publication of ES2105692T5 publication Critical patent/ES2105692T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/203Solid polymers with solid and/or liquid additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/71Feed mechanisms
    • B01F35/717Feed mechanisms characterised by the means for feeding the components to the mixer
    • B01F35/7176Feed mechanisms characterised by the means for feeding the components to the mixer using pumps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/30Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/58Component parts, details or accessories; Auxiliary operations
    • B29B7/60Component parts, details or accessories; Auxiliary operations for feeding, e.g. end guides for the incoming material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/30Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/58Component parts, details or accessories; Auxiliary operations
    • B29B7/72Measuring, controlling or regulating
    • B29B7/726Measuring properties of mixture, e.g. temperature or density
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/74Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
    • B29B7/7476Systems, i.e. flow charts or diagrams; Plants
    • B29B7/7485Systems, i.e. flow charts or diagrams; Plants with consecutive mixers, e.g. with premixing some of the components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/80Component parts, details or accessories; Auxiliary operations
    • B29B7/82Heating or cooling
    • B29B7/826Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/80Component parts, details or accessories; Auxiliary operations
    • B29B7/88Adding charges, i.e. additives
    • B29B7/94Liquid charges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/12Making granules characterised by structure or composition
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/50Mixing liquids with solids
    • B01F23/565Mixing liquids with solids by introducing liquids in solid material, e.g. to obtain slurries
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/16Auxiliary treatment of granules
    • B29B2009/163Coating, i.e. applying a layer of liquid or solid material on the granule
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/30Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/34Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
    • B29B7/38Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
    • B29B7/40Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft
    • B29B7/42Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft with screw or helix
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/285Feeding the extrusion material to the extruder
    • B29C48/288Feeding the extrusion material to the extruder in solid form, e.g. powder or granules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/285Feeding the extrusion material to the extruder
    • B29C48/29Feeding the extrusion material to the extruder in liquid form
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/06PE, i.e. polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0005Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients

Landscapes

  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

SE DA A CONOCER UN PROCEDIMIENTO PARA LA ELABORACION DE UN PRODUCTO POLIMERO EXTRUSIONADO RETICULADO, DONDE EL POLIMERO RETICULADO SE ELABORA EN FORMA DE GRANULADO O FORMA EN POLVO CON ADITIVOS LIQUIDOS MEDIANTE EXTRUSIONADO, DE MODO QUE SE CARACTERIZAN DE TAL MANERA, QUE SE UTILIZA UN GRANULADO POLIMERO O POLVO DE POLIMERO CON SUPERFICIE POROSA FISURADA. ESTE POLIMERO DE FORMA GRANULADA/PULVERIFORME CON UNA ESTRUCTURA DE SUPERFICIE IRREGULAR SE GUIA A TRAVES DE UNA LINEA DE ALIMENTACION A UNA ZONA DE MEZCLA MEDIANTE INYECCION DE AL MENOS UN ADITIVO DE ARTICULACION LIQUIDO Y EXTRUSIONADO SUBSECUENTE DE LA MEZCLA EN UNA PRENSA DE EXTRUSION. SE OBTIENE DURANTE LA EXTRUSION UNA DISTRIBUCION MEJORADA DEL LIQUIDO A TRAVES DE PARTICULAS DE LIQUIDO DE POLIMERO, CON UNA DISPOSICION MAS UNIFORME DE AGENTE DE RETICULACION TRANSVERSAL SOBRE EL POLIMERO Y DE AQUI UN PRODUCTO RETICULADO TRANSVERSALMENTE DE MANERA HOMOGENEA.
ES94913598T 1993-04-23 1994-04-14 Procedimiento para fabricar un producto polimero extrusionado reticulado. Expired - Lifetime ES2105692T5 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4313290A DE4313290A1 (de) 1993-04-23 1993-04-23 Verfahren und Vorrichtung zur Herstellung eines vernetzten extrudierten Polymerproduktes

Publications (2)

Publication Number Publication Date
ES2105692T3 true ES2105692T3 (es) 1997-10-16
ES2105692T5 ES2105692T5 (es) 2002-07-01

Family

ID=6486181

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94913598T Expired - Lifetime ES2105692T5 (es) 1993-04-23 1994-04-14 Procedimiento para fabricar un producto polimero extrusionado reticulado.

Country Status (13)

Country Link
US (1) US5744553A (es)
EP (1) EP0695320B2 (es)
JP (1) JP3266201B2 (es)
KR (1) KR100274264B1 (es)
CN (1) CN1046297C (es)
AT (1) ATE154052T1 (es)
CH (1) CH685931A5 (es)
DE (2) DE4313290A1 (es)
DK (1) DK0695320T4 (es)
ES (1) ES2105692T5 (es)
GR (1) GR3024583T3 (es)
PL (1) PL173553B1 (es)
WO (1) WO1994025509A1 (es)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2247910A1 (es) * 2004-02-04 2006-03-01 Govoni Iberica, S.A. Procedimiento para la produccion de granza basicamente de polietileno reticulable, directamente extrudible, e instalacion para la realizacion del mismo.

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19724317C1 (de) * 1997-06-10 1998-08-27 Pcd Polymere Ag Segmentierte Polyolefine
US5972267A (en) * 1998-03-30 1999-10-26 Union Carbide Chemicals & Plastics Technology Corporation Process for the production of a thermosetting composition
DE19824958B4 (de) * 1998-06-03 2004-02-05 Werner Kempter Verfahren zur Herstellung eines vernetzten, extrudierten Polymerproduktes
EP1021486B1 (en) 1998-06-22 2004-09-22 General Electric Company Silane vulcanized thermoplastic elastomers
ATE255270T1 (de) * 2000-04-17 2003-12-15 Nexans Verfahren zur herstellung von mit vernetztem polyethylen überzogenen leitungsdrähten
CA2422302A1 (en) * 2000-09-14 2002-03-21 Charles F. Williams Liquid additive spray injection to polymeric powders
US20040028808A1 (en) * 2001-09-13 2004-02-12 Williams Charles F. Liquid additive spray injection to polymeric powders
US7064163B2 (en) * 2002-09-04 2006-06-20 Msi Technology Llc Polyolefin-based adhesive resins and method of making adhesive resins
US7202309B2 (en) * 2003-09-12 2007-04-10 Momentive Performance Materials Inc. Process for crosslinking thermoplastic polymers with silanes employing peroxide blends and the resulting crosslinked thermoplastic polymers
US20070297272A1 (en) * 2004-07-30 2007-12-27 Werner Kempter Method for Mixing a Plastic Granulate With an Additive and Mixing Device for Carrying Out Said Method and Device Provided With Said Mixing Device
US7326753B2 (en) * 2005-02-08 2008-02-05 Momentive Performance Materials Inc. Process for the production of crosslinked polymer employing low VOC-producing silane crosslinker and resulting crosslinked polymer
US7810986B2 (en) * 2005-11-21 2010-10-12 Process Control Corporation Systems and methods for liquid dosing of material in a blender system
US20100140843A1 (en) * 2006-10-04 2010-06-10 Silon S.R.O. Plano Nad Lu'znici Method for the manufacture of a preferably crosslinked, extruded polymer product
US20080114134A1 (en) * 2006-11-14 2008-05-15 General Electric Company Process for crosslinking thermoplastic polymers with silanes employing peroxide blends, the resulting crosslinked thermoplastic polymer composition and articles made therefrom
AT504709B1 (de) 2006-11-23 2008-09-15 Erema Verfahren und vorrichtung zur einbringung von zusatzstoffen
CN106166804B (zh) * 2016-10-14 2019-01-08 江苏华兴橡胶科技有限公司 一种再生胶用粗炼塑化系统及其粗炼方法

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GB863732A (en) * 1958-04-18 1961-03-22 Phillips Petroleum Co Method of dispersing additives in solid polymers
DE2411141A1 (de) * 1974-03-08 1975-09-18 Kabel Metallwerke Ghh Verfahren zur herstellung von umhuellungen aus in anwesenheit von fluessigkeit vernetzbaren thermoplasten fuer langgestrecktes gut
DE3035709A1 (de) 1978-07-21 1982-04-29 Kabel- und Metallwerke Gutehoffnungshütte AG, 3000 Hannover Verfahren zur herstellung von extrudierbaren und feuchtigkeitsvernetzbaren mischungen
IT1099761B (it) * 1978-10-05 1985-09-28 Montedison Spa Procedimento per ottenere composizioni omogenee di polimeri olefinici in forma granulare e di additivi vari
DE2856381A1 (de) * 1978-12-27 1980-07-10 Kabel Metallwerke Ghh Verfahren zur aufbereitung gefuellter und vernetzbarer polymerer werkstoffe
US4564349A (en) * 1983-06-01 1986-01-14 Union Carbide Corporation Extruder assembly for extruding water-curable silane modified polymers
US4703093A (en) * 1985-01-16 1987-10-27 Colonial Rubber Works, Inc. Method of preparing a polymer for cross-link rotational molding and a polymer prepared by said method
DE3506164A1 (de) * 1985-02-22 1986-08-28 kabelmetal electro GmbH, 3000 Hannover Verfahren zur herstellung von vernetzbaren mischungen
GB8919895D0 (en) 1989-09-04 1989-10-18 Du Pont Canada Moisture cross-linking of polymers
US5112919A (en) 1989-10-30 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Solid feeding of silane crosslinking agents into extruder
US5076988A (en) 1990-03-09 1991-12-31 Union Carbide Chemicals And Plastics Technology Corporation Process for the extrusion of low density polyethylene
NL9000840A (nl) * 1990-04-10 1991-11-01 Wavin Bv Werkwijze en installatie voor het vervaardigen van kunststofvoortbrengsels met behulp van een warm mengsel van pvc-poeder en additieven, alsmede een voor toepassing bij deze werkwijze geschikte warmmenger.
DE4103602A1 (de) * 1991-02-07 1992-08-13 Wacker Chemie Gmbh Verfahren zur kontinuierlichen herstellung von htv-siliconmassen
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2247910A1 (es) * 2004-02-04 2006-03-01 Govoni Iberica, S.A. Procedimiento para la produccion de granza basicamente de polietileno reticulable, directamente extrudible, e instalacion para la realizacion del mismo.

Also Published As

Publication number Publication date
PL173553B1 (pl) 1998-03-31
DE59403038D1 (de) 1997-07-10
KR100274264B1 (ko) 2000-12-15
US5744553A (en) 1998-04-28
DK0695320T3 (da) 1997-12-22
CN1046297C (zh) 1999-11-10
CN1124032A (zh) 1996-06-05
ES2105692T5 (es) 2002-07-01
EP0695320A1 (de) 1996-02-07
GR3024583T3 (en) 1997-12-31
EP0695320B2 (de) 2001-12-12
DE4313290A1 (de) 1994-10-27
WO1994025509A1 (de) 1994-11-10
JPH08509262A (ja) 1996-10-01
JP3266201B2 (ja) 2002-03-18
DK0695320T4 (da) 2002-03-11
ATE154052T1 (de) 1997-06-15
KR960701926A (ko) 1996-03-28
PL311229A1 (en) 1996-02-05
CH685931A5 (de) 1995-11-15
EP0695320B1 (de) 1997-06-04

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