ES2102651T3 - Procedimiento de isomerizacion esquematica de n-olefinas. - Google Patents
Procedimiento de isomerizacion esquematica de n-olefinas.Info
- Publication number
- ES2102651T3 ES2102651T3 ES93912292T ES93912292T ES2102651T3 ES 2102651 T3 ES2102651 T3 ES 2102651T3 ES 93912292 T ES93912292 T ES 93912292T ES 93912292 T ES93912292 T ES 93912292T ES 2102651 T3 ES2102651 T3 ES 2102651T3
- Authority
- ES
- Spain
- Prior art keywords
- olefins
- schematic
- isomerization
- zsm
- zeolite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7042—TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7046—MTT-type, e.g. ZSM-23, KZ-1, ISI-4 or EU-13
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/37—Acid treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
EN UN PROCESO PARA ISOMERIZACION DE ESQUELETO DE OLEFINAS LINEALES A N-OLEFINAS, POR EJEMPLO, N-BUTENOS A ISOBUTENOS, SOBRE UN CATALIZADOR QUE COMPRENDE UNA ZEOLITA DE POROS MEDIOS, POR EJEMPLO ZEOLITA ELEGIDA ENTRE ZSM-22, ZSM-23, Y ZSM-35, LA ZEOLITA SE PREPARA CON UN ACIDO DICARBOXILICO, POR EJEMPLO ACIDO OXALICO. EL PRETRATAMIENTO REDUCE SIGNIFICATIVAMENTE LA VELOCIDAD DE ENVEJECIMIENTO Y AUMENTA LA LONGITUD DE CICLO DEL CATALIZADOR.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/881,278 US5321194A (en) | 1992-05-11 | 1992-05-11 | N-olefin skeletal isomerization process using dicarboxylic acid treated zeolites |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2102651T3 true ES2102651T3 (es) | 1997-08-01 |
Family
ID=25378142
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES93912292T Expired - Lifetime ES2102651T3 (es) | 1992-05-11 | 1993-04-19 | Procedimiento de isomerizacion esquematica de n-olefinas. |
Country Status (10)
Country | Link |
---|---|
US (1) | US5321194A (es) |
EP (1) | EP0641299B1 (es) |
JP (1) | JPH07506831A (es) |
KR (1) | KR950700865A (es) |
AU (1) | AU667547B2 (es) |
CA (1) | CA2117525A1 (es) |
DE (1) | DE69309462T2 (es) |
ES (1) | ES2102651T3 (es) |
SG (1) | SG42335A1 (es) |
WO (1) | WO1993023353A1 (es) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5523511A (en) * | 1991-09-16 | 1996-06-04 | Mobil Oil Corporation | Highly selective n-olefin isomerization process using low zeolite content ZSM-35 catalyst |
ES2121074T3 (es) * | 1992-10-16 | 1998-11-16 | Mobil Oil Corp | Procedimiento de isomerizacion esqueletica de la olefina utilizando el zsm-35. |
US5491276A (en) * | 1992-12-12 | 1996-02-13 | Texaco Inc. | Skeletal isomerization of n-butylenes to isobutylene on zeolites |
GB9312245D0 (en) * | 1993-06-14 | 1993-07-28 | Exxon Chemical Patents Inc | Hydrocarbon treatment |
US5463160A (en) * | 1993-08-30 | 1995-10-31 | Texaco Inc. | Skeletal isomerization of n-pentenes to isopentene on pretreated zeolites |
US5523510A (en) * | 1993-08-30 | 1996-06-04 | Texaco Inc. | Treated bound ferrierite zeolites for skeletal isomerization of n-olefins to iso-olefins |
US5510560A (en) * | 1993-08-30 | 1996-04-23 | Texaco Inc. | Skeletal isomerization of n-olefins to iso-olefins on binded ferrierite zeolites |
US5510306A (en) * | 1993-12-29 | 1996-04-23 | Shell Oil Company | Process for isomerizing linear olefins to isoolefins |
US5489726A (en) * | 1994-04-26 | 1996-02-06 | Mobil Oil Corporation | Highly selective N-olefin isomerization process using multiple parallel reactors |
GB9420528D0 (en) * | 1994-10-12 | 1994-11-30 | Bp Chem Int Ltd | Skeletal isomerization of olefins |
AU5147698A (en) * | 1996-10-16 | 1998-05-11 | Mobil Oil Corporation | N-olefin skeletal isomerization process |
US5811623A (en) * | 1997-06-09 | 1998-09-22 | Catalytic Distillation Technologies | Isomerization of olefins by alkylation and dealkylation of aromatic hydrocarbons |
FR2798922B1 (fr) * | 1999-09-29 | 2001-12-14 | Inst Francais Du Petrole | Procede de preparation d'une zeolithe de type structural mtt utilisant des germes de materiaux zeolithiques |
FR2798923B1 (fr) * | 1999-09-29 | 2001-12-14 | Inst Francais Du Petrole | Procede de preparation d'une zeolithe de type structural mtt utilisant des precurseurs specifiques du structurant |
US6455595B1 (en) | 2000-07-24 | 2002-09-24 | Chevron U.S.A. Inc. | Methods for optimizing fischer-tropsch synthesis |
US7288181B2 (en) * | 2003-08-01 | 2007-10-30 | Exxonmobil Research And Engineering Company | Producing low sulfur naphtha products through improved olefin isomerization |
US7435865B2 (en) * | 2003-08-18 | 2008-10-14 | Vrije Universiteit Brussel | Method for separating hydrocarbons and use of a zeolite therefor |
US8450232B2 (en) * | 2009-01-14 | 2013-05-28 | Lummus Technology Inc. | Catalysts useful for the alkylation of aromatic hydrocarbons |
JP2012120977A (ja) * | 2010-12-08 | 2012-06-28 | Mitsubishi Chemicals Corp | 珪質固体触媒の製造方法及び低級炭化水素の製造方法 |
RU2475470C1 (ru) * | 2012-03-11 | 2013-02-20 | Ирина Игоревна Иванова | Способ скелетной изомеризации н-бутенов в изобутилен |
MX360442B (es) | 2012-09-14 | 2018-10-31 | Lummus Technology Inc | Propileno via metatesis sin etileno o con bajo contenido de etileno. |
CN104557403B (zh) * | 2013-10-23 | 2016-08-17 | 中国石油化工股份有限公司 | 一种正丁烯骨架异构生产异丁烯的开工方法 |
CN104557402B (zh) * | 2013-10-23 | 2016-08-17 | 中国石油化工股份有限公司 | 一种正丁烯骨架异构生产异丁烯的方法 |
EP3474989A1 (en) | 2016-06-24 | 2019-05-01 | Albemarle Corporation | Mesoporous zsm-22 for increased propylene production |
CN110105158A (zh) * | 2018-10-12 | 2019-08-09 | 新疆寰球工程公司 | 一种醚后碳四中正丁烯异构化的加工方法 |
CN115888803A (zh) * | 2022-12-26 | 2023-04-04 | 中触媒新材料股份有限公司 | 一种改性zsm-35分子筛催化剂的制备方法及应用 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3442795A (en) * | 1963-02-27 | 1969-05-06 | Mobil Oil Corp | Method for preparing highly siliceous zeolite-type materials and materials resulting therefrom |
US3992466A (en) * | 1975-08-13 | 1976-11-16 | Mobil Oil Corporation | Hydrocarbon conversion |
DE3061785D1 (en) * | 1979-08-30 | 1983-03-03 | Mobil Oil Corp | A method for producing olefins and/or ethers of high octane number |
US4388177A (en) * | 1981-01-13 | 1983-06-14 | Mobil Oil Corporation | Preparation of natural ferrierite hydrocracking catalyst and hydrocarbon conversion with catalyst |
DE3246495A1 (de) * | 1982-12-16 | 1984-06-20 | Bayer Ag, 5090 Leverkusen | Neuer katalysator, ein verfahren zu seiner herstellung und ein isomerisierungsverfahren in gegenwart dieses katalysators |
US4521333A (en) * | 1983-06-20 | 1985-06-04 | Minnesota Mining And Manufacturing Company | Intumescent silicates having improved stability |
CA1209121A (en) * | 1983-07-12 | 1986-08-05 | Guenter H. Kuehl | Preparation of zeolite zsm-12 |
GB8612815D0 (en) * | 1986-05-27 | 1986-07-02 | British Petroleum Co Plc | Restructuring of olefins |
ATE67467T1 (de) * | 1986-09-09 | 1991-10-15 | Exxon Research Engineering Co | Zeolith mit hohem siliziumgehalt (ecr-17), dieses zeolith enthaltender katalysator und umwandlung von kohlenwasserstoffen mit einem solchen katalysator. |
US4886925A (en) * | 1988-05-02 | 1989-12-12 | Mobil Oil Corp | Olefins interconversion and etherification process |
US4922048A (en) * | 1988-10-14 | 1990-05-01 | Mobil Oil Corp. | Medium-pore zeolite olefinic naphtha by-product upgrading |
US4996386A (en) * | 1989-12-21 | 1991-02-26 | Shell Oil Company | Concurrent isomerization and disproportionation of olefins |
US5057635A (en) * | 1990-02-08 | 1991-10-15 | Uop | Process for isomerizing olefins in gasoline streams |
GB9012725D0 (en) * | 1990-06-07 | 1990-08-01 | Exxon Chemical Patents Inc | Process for catalytic conversion of olefins |
GB9116499D0 (en) * | 1991-07-31 | 1991-09-11 | British Petroleum Co Plc | Treatment method for zeolites |
US5157194A (en) * | 1991-12-20 | 1992-10-20 | Mobil Oil Corporation | Highly selective n-olefin isomerization process using microcrystalline ZSM-22 |
-
1992
- 1992-05-11 US US07/881,278 patent/US5321194A/en not_active Expired - Fee Related
-
1993
- 1993-04-19 ES ES93912292T patent/ES2102651T3/es not_active Expired - Lifetime
- 1993-04-19 SG SG1996001294A patent/SG42335A1/en unknown
- 1993-04-19 AU AU42895/93A patent/AU667547B2/en not_active Ceased
- 1993-04-19 CA CA002117525A patent/CA2117525A1/en not_active Abandoned
- 1993-04-19 DE DE69309462T patent/DE69309462T2/de not_active Expired - Fee Related
- 1993-04-19 JP JP5520230A patent/JPH07506831A/ja active Pending
- 1993-04-19 WO PCT/US1993/003621 patent/WO1993023353A1/en active IP Right Grant
- 1993-04-19 EP EP93912292A patent/EP0641299B1/en not_active Expired - Lifetime
-
1994
- 1994-10-12 KR KR1019940703629A patent/KR950700865A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
JPH07506831A (ja) | 1995-07-27 |
AU667547B2 (en) | 1996-03-28 |
EP0641299A4 (en) | 1994-12-16 |
DE69309462T2 (de) | 1997-07-10 |
WO1993023353A1 (en) | 1993-11-25 |
CA2117525A1 (en) | 1993-11-25 |
DE69309462D1 (de) | 1997-05-07 |
AU4289593A (en) | 1993-12-13 |
EP0641299B1 (en) | 1997-04-02 |
EP0641299A1 (en) | 1995-03-08 |
US5321194A (en) | 1994-06-14 |
KR950700865A (ko) | 1995-02-20 |
SG42335A1 (en) | 1997-08-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ES2102651T3 (es) | Procedimiento de isomerizacion esquematica de n-olefinas. | |
ES2127372T3 (es) | Oligomerizacion de olefinas. | |
ATE189976T1 (de) | Verfahren zur herstellung eines zeolitkatalysators für die isomerisierung von linearen olefinen zu izoolefinen | |
AR022612A1 (es) | Procedimiento para el fraccionamiento de dibutenos y empleo de las fracciones obtenidas con el mismo | |
ES2055114T3 (es) | Isomerizacion de hidrocarburos fluorados saturados. | |
ATE184586T1 (de) | Verfahren zur isomerisierung von geradlinigen olefinen in isoolefine | |
ES2054291T3 (es) | Procedimiento de produccion de alquilbencenos que utiliza un catalizador a base de zeolita y desaluminada y un catalizador a base de mordenita desaluminada. | |
ES2098948T3 (es) | Procedimientos de ensayo de analogos de acido nucleico. | |
ES2064043T3 (es) | Procedimiento para preparar decabromodifenil-alcano. | |
ATE142190T1 (de) | Herstellung von alkoholen | |
DE69116364D1 (de) | Verfahren zur katalytischen umsetzung von olefinen | |
DE69605755D1 (de) | Isomerisierung der Fettsäure | |
ITMI922177A1 (it) | Processo migliorato per la produzione di alchilbenzeni lineari | |
SG81862A1 (en) | Desking system | |
IT1013065B (it) | Processo par la fotopolimerizzazio ne dei composti organici etilenica menti insaturi e relativa composi zione | |
ES2056918T3 (es) | Composicion de metal de transicion. | |
ATE139561T1 (de) | Verwendung von reinigungsmitteln für harte oberflächen, insbesondere glas | |
MY104078A (en) | Process for the hydration of olefins | |
GB1309529A (en) | Carbenometal composition and its use as catalyst for converting olefinic hydrocarbons | |
ES2159883T3 (es) | Procedimiento para la isomerizacion del nucleo de n-olefinas. | |
ES2073370B1 (es) | Procedimiento para la preparacion del compuesto bis-(1,3-dihidroxi-propilamida) del acido l-5-(2-acetoxi-propionilamino)-2,4,6-triyodo-isoftalico. | |
ES2077753T3 (es) | Dimerizacion de olefinas catalizada con rodio. | |
ES2107043T3 (es) | Purificacion de 1,1,1,2-tetrafluoroetano. | |
KR920011581A (ko) | 촉매 지지체 및 촉매시스템의 제조방법 및 이를 사용한 이량체화 방법 | |
AR248387A1 (es) | Un proceso para alquilar una isoparafina con una olefina. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
Ref document number: 641299 Country of ref document: ES |