ES2099724T3 - Composiciones de 1-alquino polimetalado. - Google Patents

Composiciones de 1-alquino polimetalado.

Info

Publication number
ES2099724T3
ES2099724T3 ES91115965T ES91115965T ES2099724T3 ES 2099724 T3 ES2099724 T3 ES 2099724T3 ES 91115965 T ES91115965 T ES 91115965T ES 91115965 T ES91115965 T ES 91115965T ES 2099724 T3 ES2099724 T3 ES 2099724T3
Authority
ES
Spain
Prior art keywords
conjugated
alquino
elevated
compositions
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91115965T
Other languages
English (en)
Inventor
Jung W Kang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Corp
Original Assignee
Bridgestone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridgestone Corp filed Critical Bridgestone Corp
Application granted granted Critical
Publication of ES2099724T3 publication Critical patent/ES2099724T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2291—Olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2286—Alkynes, e.g. acetylides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic System
    • C07F1/02—Lithium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/127—Anionic (co)polymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/11—Lithium

Abstract

SE DESCRIBE UNAS COMPOSICIONES HIDROCARBUROS SOLUBLES DE 1-ALQUINO POLIMETALATADAS, QUE ESTAN CARACTERIZADAS POR LA FORMULA: DONDE R ES HIDROGENO, UN GRUPO HIDROCARBIL, O R ELEVADO 1 M, M ES UN METAL ALCALINO, R ELEVADO 1 ES UN GRUPO HIDROCARBIL OLIGOMERICO DIVALENTE QUE CONSTA DE MOIETIES DERIVADOS DE UN DIENE CONJUGADO, Y DONDE EL NUMERO TOTAL DE MOIETIES DERIVADOS DEL DIENE CONJUGADO EN TODOS LOS GRUPOS R ELEVADO 1 EN LA FORMULA 1 ES DE 2 A 30. PREFERENTEMENTE, EL METAL ALCALINO ES LITIO. TAMBIEN SE DESCRIBEN LOS CATALIZADORES DE HIDROCARBUROS SOLUBLES DE 1-ALQUENO POLIMETALETADAS PARA LA POLIMERIZACION IONICA QUE COMPRENDE EL PRODUCTO DE REACCION DE UN 1-ALQUINO, UN COMPUESTO ORGANOMETALICO R (GRADOS) M Y UN DIENO 1,3-CONJUGADO DONDE R (GRADOS) ES UN GRUPO HIDROCARBILO, M ES UN METAL ALCALINO, LA RELACION MOLAR DEL DIENO CONJUGADO AL 1-ALQUILENO ES AL MENOS DE 2:1, Y LA REACCION SE REALIZA A UNA TEMPERATURA DE AL MENOS 70 C.
ES91115965T 1990-09-21 1991-09-19 Composiciones de 1-alquino polimetalado. Expired - Lifetime ES2099724T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/586,489 US5080835A (en) 1990-09-21 1990-09-21 Polymetalated 1-alkyne compositions

Publications (1)

Publication Number Publication Date
ES2099724T3 true ES2099724T3 (es) 1997-06-01

Family

ID=24345949

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91115965T Expired - Lifetime ES2099724T3 (es) 1990-09-21 1991-09-19 Composiciones de 1-alquino polimetalado.

Country Status (6)

Country Link
US (1) US5080835A (es)
EP (1) EP0476663B1 (es)
JP (1) JP3285598B2 (es)
CA (1) CA2051938C (es)
DE (1) DE69125776T2 (es)
ES (1) ES2099724T3 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5730910A (en) * 1997-01-03 1998-03-24 Bridgestone/Firestone, Inc. Method for preparing polymetalated compositions
ITMI20121495A1 (it) * 2012-09-07 2014-03-08 Versalis Spa Procedimento per la preparazione di polimeri dienici o di copolimeri statistici vinilarene-diene

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3135716A (en) * 1958-11-06 1964-06-02 Phillips Petroleum Co Process for preparing terminally reactive polymers
US3157604A (en) * 1960-10-24 1964-11-17 Phillips Petroleum Co Polymerization initiators
US3193590A (en) * 1961-08-10 1965-07-06 Phillips Petroleum Co Method of preparing organolithium polymerization initiators
US3159587A (en) * 1961-08-21 1964-12-01 Phillips Petroleum Co Organopolylithium polymerization initiators and their preparation
US3296150A (en) * 1962-08-27 1967-01-03 Phillips Petroleum Co Organopolylithium polymerization initiators and their preparation
US3303225A (en) * 1962-12-26 1967-02-07 Phillips Petroleum Co Production of polymetallated 1-acetylenes
US3438957A (en) * 1964-11-09 1969-04-15 Phillips Petroleum Co Metalated acetylenic polymers and their preparation
US3784637A (en) * 1969-01-30 1974-01-08 Phillips Petroleum Co Multifunctional polymerization initiators from vinylsilanes or vinylphosphines and organomonolithium compounds
US3640899A (en) * 1969-01-30 1972-02-08 Phillips Petroleum Co Reaction product of hydrocarbylmonolithium and 1 3-butadiene as polymerization initiator
US3644322A (en) * 1969-02-03 1972-02-22 Phillips Petroleum Co Polymerization of conjugated dienes and monovinyl aromatic compounds with multifunctional polymerization initiators
US3787510A (en) * 1969-02-03 1974-01-22 Phillips Petroleum Co Multifunctional polymerization initiators
US3668263A (en) * 1970-01-19 1972-06-06 Lithium Corp Organolithium polymerization initiators and use thereof in polymerization processes
US3725368A (en) * 1970-01-19 1973-04-03 Lithium Corp Preparation of polymers
US3954894A (en) * 1973-05-18 1976-05-04 Lithium Corporation Of America Organotrilithium polymerization initiators
JPS5223380B2 (es) * 1973-09-12 1977-06-23
US3903168A (en) * 1973-11-23 1975-09-02 Du Pont Stable anionic polymerization initiator
JPS533791B2 (es) * 1974-05-15 1978-02-09
US3975453A (en) * 1975-02-24 1976-08-17 Foote Mineral Company Process for preparing butynyllithium
US4196154A (en) * 1977-10-11 1980-04-01 The Dow Chemical Company Soluble multifunctional lithium containing initiator
US4339397A (en) * 1979-11-26 1982-07-13 Shin-Etsu Chemical Co., Ltd. Method for the preparation of a sodium salt of 1-alkyne compound
US4497748A (en) * 1981-07-13 1985-02-05 The General Tire & Rubber Company Preparation of lithium initiator for the preparation of star polymers
US4399078A (en) * 1982-03-15 1983-08-16 Lithium Corporation Of America Hydrocarbon solvent solutions of complexes of N-butyllithium and ethyllithium
DE3711920A1 (de) * 1987-04-08 1988-10-27 Basf Ag Verfahren zur herstellung multifunktioneller initiatoren fuer die anionische polymerisation, oligomere multifunktionelle initiatoren, verwendung der erhaltenen polymeren zur herstellung gegenbenenfalls funktionalisierter polymere und als prepolymere fuer andere harze

Also Published As

Publication number Publication date
JPH04253983A (ja) 1992-09-09
CA2051938A1 (en) 1992-03-22
EP0476663B1 (en) 1997-04-23
EP0476663A1 (en) 1992-03-25
DE69125776D1 (de) 1997-05-28
JP3285598B2 (ja) 2002-05-27
DE69125776T2 (de) 1997-07-31
CA2051938C (en) 2002-04-16
US5080835A (en) 1992-01-14

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