ES2096753T3 - Proceso para la purificacion y tapado final de polioles hechos mediante la utilizacion de catalizadores de cianuro bimetalicos. - Google Patents

Proceso para la purificacion y tapado final de polioles hechos mediante la utilizacion de catalizadores de cianuro bimetalicos.

Info

Publication number
ES2096753T3
ES2096753T3 ES92907044T ES92907044T ES2096753T3 ES 2096753 T3 ES2096753 T3 ES 2096753T3 ES 92907044 T ES92907044 T ES 92907044T ES 92907044 T ES92907044 T ES 92907044T ES 2096753 T3 ES2096753 T3 ES 2096753T3
Authority
ES
Spain
Prior art keywords
polyol
ethylene oxide
base
waste
bimetallic cyanide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92907044T
Other languages
English (en)
Inventor
John Warren Reisch
Michael M Martinez
Maurice Raes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Olin Corp
Original Assignee
Olin Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Olin Corp filed Critical Olin Corp
Application granted granted Critical
Publication of ES2096753T3 publication Critical patent/ES2096753T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/30—Post-polymerisation treatment, e.g. recovery, purification, drying

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Polyethers (AREA)

Abstract

UN PROCESO PARA LA PRODUCCION DE UN POLIOL TAPADO CON OXIDO DE ETILENO, EN DONDE EL POLIOL SE PRODUCE UTILIZANDO UN CATALIZADOR DE CIANURO BIMETALICO, QUE CONSISTE, DESPUES DE LA FORMACION DEL POLIOL, EN LOS PASOS SIGUIENTES: (A) PONER EN CONTACTO UN POLIOL QUE CONTENGA UNO O VARIOS RESIDUOS DEL CATALIZADOR CON UNA CANTIDAD EFECTIVA DE UN OXIDANTE PARA HACER QUE DICHO(S) RESIDUO(S) DEL CATALIZADOR FORMEN RESIDUOS INSOLUBLES QUE SON INSOLUBLES EN EL POLIOL; (B) SEPARAR LOS RESIDUOS INSOLUBLES DEL POLIOL PARA OBTENER UN POLIOL QUE NO CONTENGA ESENCIALMENTE RESIDUOS DEL CATALIZADOR DE CIANURO BIMETALICO; (C) TRATAR DICHO POLIOL SIN RESIDUOS DEL CATALIZADOR DE CIANURO BIMETALICO CON UNA BASE PARA OBTENER UN POLIOL TRATADO CON UNA BASE; (D) PONER EN CONTACTO DICHO POLIOL TRATADO CON UNA BASE CON OXIDO DE ETILENO PARA OBTENER UNA BASE QUE CONTENGA UN POLIOL TAPADO CON OXIDO DE ETILENO, EN DONDE AL MENOS UNA PORCION DE LOS GRUPOS HIDROXILO SECUNDARIOS QUE SE ENCUENTRAN EN DICHO POLIOL SE CONVIERTEN EN GRUPOS HIDROXILO PRIMARIOS Y (E) SEPARAR DICHA BASE DE DICHO POLIOL TAPADO CON OXIDO DE ETILENO PARA OBTENER UN POLIOL TAPADO CON OXIDO DE ETILENO PURIFICADO.
ES92907044T 1991-04-29 1992-03-02 Proceso para la purificacion y tapado final de polioles hechos mediante la utilizacion de catalizadores de cianuro bimetalicos. Expired - Lifetime ES2096753T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/692,753 US5144093A (en) 1991-04-29 1991-04-29 Process for purifying and end-capping polyols made using double metal cyanide catalysts

Publications (1)

Publication Number Publication Date
ES2096753T3 true ES2096753T3 (es) 1997-03-16

Family

ID=24781871

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92907044T Expired - Lifetime ES2096753T3 (es) 1991-04-29 1992-03-02 Proceso para la purificacion y tapado final de polioles hechos mediante la utilizacion de catalizadores de cianuro bimetalicos.

Country Status (7)

Country Link
US (1) US5144093A (es)
EP (1) EP0583251B1 (es)
JP (1) JP3131445B2 (es)
AU (1) AU1442992A (es)
DE (1) DE69216398T2 (es)
ES (1) ES2096753T3 (es)
WO (1) WO1992019578A1 (es)

Families Citing this family (32)

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US4681606A (en) * 1986-02-26 1987-07-21 Cobe Laboratories, Inc. Drip chamber
US5235114A (en) * 1991-04-29 1993-08-10 Olin Corporation Process for purifying and end-capping polyols made using double metal cyanide catalysts
US5266681A (en) * 1992-08-03 1993-11-30 Olin Corporation Process and composition for providing double metal cyanide catalyzed polyols having enhanced reactivity
US5357038A (en) * 1992-08-03 1994-10-18 Olin Corporation Process and composition for providing double metal cyanide catalyzed polyols having enhanced reactivity
US5248833A (en) * 1992-09-22 1993-09-28 Arco Chemical Technology, L.P. Process for purifying polyols made with double metal cyanide catalysts
US5712216A (en) * 1995-05-15 1998-01-27 Arco Chemical Technology, L.P. Highly active double metal cyanide complex catalysts
US5470813A (en) * 1993-11-23 1995-11-28 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts
US5591251A (en) * 1993-11-29 1997-01-07 Cobe Laboratories, Inc. Side flow bubble trap apparatus and method
GB9325468D0 (en) * 1993-12-13 1994-02-16 Ici Plc Process for purifying polyols
US5426081A (en) * 1993-12-23 1995-06-20 Arco Chemical Technology, L.P. Polyurethane foam-supported double metal cyanide catalysts for polyol synthesis
CA2138063C (en) * 1993-12-23 2007-02-20 Bi Le-Khac Polyurethane foam-supported double metal cyanide catalysts for polyol synthesis
US5416241A (en) * 1994-01-27 1995-05-16 Arco Chemical Technology, L.P. Method for purifying polyether polyols made with double metal cyanide catalysts
US5563221A (en) * 1995-06-21 1996-10-08 Arco Chemical Technology, L.P. Process for making ethylene oxide-capped polyols from double metal cyanide-catalyzed polyols
US5605939A (en) * 1996-01-26 1997-02-25 Arco Chemical Technology, L.P. Poly(oxypropylene/oxyethylene) random polyols useful in preparing flexible high resilience foam with reduced tendencies toward shrinkage and foam prepared therewith
US6077978A (en) * 1997-09-17 2000-06-20 Arco Chemical Technology L.P. Direct polyoxyalkylation of glycerine with double metal cyanide catalysis
US6429342B1 (en) 1999-07-09 2002-08-06 Dow Global Technologies Inc. Polymerization of ethylene oxide using metal cyanide catalysts
US6642423B2 (en) 1999-07-09 2003-11-04 Dow Global Technologies, Inc. Polymerization of ethylene oxide using metal cyanide catalysts
ES2199666B1 (es) * 2002-02-25 2005-06-01 Repsol Quimica, S.A. Procedimiento de produccion de polioleteres.
KR20050084970A (ko) * 2002-11-07 2005-08-29 다우 글로벌 테크놀로지스 인크. 중합가능한 착화제를 사용해 금속 시안화물 촉매를제조하는 방법
US6806348B2 (en) * 2003-02-11 2004-10-19 Basf Corporation Process for removing and regenerating a double metal cyanide (DMC) catalyst from a polymer polyol
EP1493769B1 (en) * 2003-06-30 2007-11-21 Repsol Quimica S.A. Process to purify polyether polyols
US7005552B2 (en) 2003-11-03 2006-02-28 Bayer Materialscience Llc Single reactor synthesis of KOH-capped polyols based on DMC-synthesized intermediates
DE102004047524A1 (de) * 2004-09-28 2006-03-30 Basf Ag Verfahren zur Herstellung von Polyurethan-Weichschaumstoffen
DE102005041142A1 (de) * 2005-08-30 2007-03-01 Basf Ag Verfahren zur Herstellung von Polyetheralkoholen
KR20140025350A (ko) * 2011-03-30 2014-03-04 아사히 가라스 가부시키가이샤 폴리에테르폴리올 및 연질 폴리우레탄 폼의 제조 방법, 그리고 시트
US9527958B2 (en) 2014-05-02 2016-12-27 Covestro Llc Process for purification of polyether carbonate polyols
CN104109234B (zh) * 2014-08-06 2016-06-15 山东蓝星东大化工有限责任公司 高分子量低不饱和度高伯羟基含量聚醚多元醇的制备方法
WO2018005055A1 (en) * 2016-06-30 2018-01-04 Dow Global Technologies Llc Process for making polyethers with reduced amounts of unsaturated monols
KR102387647B1 (ko) * 2016-06-30 2022-04-19 다우 글로벌 테크놀로지스 엘엘씨 폴리에테르 디올 제조 공정
US20190119444A1 (en) 2017-10-25 2019-04-25 Covestro Llc Process to remove dmc catalysts from polyether carbonate polyols
CN113302224B (zh) 2019-01-31 2023-09-19 陶氏环球技术有限责任公司 聚醚-碳酸酯多元醇的纯化方法
WO2022015638A1 (en) 2020-07-17 2022-01-20 Dow Global Technologies Llc Polyurethanes with reduced cobalt extractables

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3829505A (en) * 1970-02-24 1974-08-13 Gen Tire & Rubber Co Polyethers and method for making the same
US3941849A (en) * 1972-07-07 1976-03-02 The General Tire & Rubber Company Polyethers and method for making the same
DE2352856C3 (de) * 1973-10-22 1978-09-28 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt Verfahren zum Entgiften von Abwässern in denen Cyanide und/oder Cyanhydrine und/oder Nitrile enthalten sind
JPS55164270A (en) * 1979-06-07 1980-12-20 Kuraray Co Ltd Laminate
JPS5698232A (en) * 1980-01-09 1981-08-07 Dai Ichi Kogyo Seiyaku Co Ltd Purification of polyetherpolyol
CA1155871A (en) * 1980-10-16 1983-10-25 Gencorp Inc. Method for treating polypropylene ether and poly-1,2- butylene ether polyols
AU551979B2 (en) * 1982-03-31 1986-05-15 Shell Internationale Research Maatschappij B.V. Epoxy polymerisation catalysts
AU552988B2 (en) * 1982-03-31 1986-06-26 Shell Internationale Research Maatschappij B.V. Polymerizing epoxides and catalyst suspensions for this
US4721818A (en) * 1987-03-20 1988-01-26 Atlantic Richfield Company Purification of polyols prepared using double metal cyanide complex catalysts
US4877906A (en) * 1988-11-25 1989-10-31 Arco Chemical Technology, Inc. Purification of polyols prepared using double metal cyanide complex catalysts
WO1990007537A1 (en) * 1989-01-06 1990-07-12 Asahi Glass Company Ltd. Production of polyether
JP2743454B2 (ja) * 1989-04-07 1998-04-22 旭硝子株式会社 ポリエーテル類の製造方法
JPH02265923A (ja) * 1989-04-07 1990-10-30 Asahi Glass Co Ltd ポリエーテル類の製造方法

Also Published As

Publication number Publication date
WO1992019578A1 (en) 1992-11-12
EP0583251A1 (en) 1994-02-23
AU1442992A (en) 1992-12-21
JPH06506708A (ja) 1994-07-28
JP3131445B2 (ja) 2001-01-31
DE69216398D1 (de) 1997-02-13
EP0583251A4 (en) 1994-10-05
EP0583251B1 (en) 1997-01-02
US5144093A (en) 1992-09-01
DE69216398T2 (de) 1997-06-19

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