ES2064730T3 - Nuevos esteres arilicos de acidos fosfonosos, un procedimiento para su preparacion y su utilizacion para la estabilizacion de materiales sinteticos, especialmente masas de moldeo de poliolefinas. - Google Patents
Nuevos esteres arilicos de acidos fosfonosos, un procedimiento para su preparacion y su utilizacion para la estabilizacion de materiales sinteticos, especialmente masas de moldeo de poliolefinas.Info
- Publication number
- ES2064730T3 ES2064730T3 ES90907020T ES90907020T ES2064730T3 ES 2064730 T3 ES2064730 T3 ES 2064730T3 ES 90907020 T ES90907020 T ES 90907020T ES 90907020 T ES90907020 T ES 90907020T ES 2064730 T3 ES2064730 T3 ES 2064730T3
- Authority
- ES
- Spain
- Prior art keywords
- carbon atoms
- aryl
- residue
- aromatic
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title abstract 5
- 238000000465 moulding Methods 0.000 title abstract 4
- 229920000098 polyolefin Polymers 0.000 title abstract 2
- 239000002253 acid Substances 0.000 title 1
- 150000007513 acids Chemical class 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- 230000006641 stabilisation Effects 0.000 title 1
- 238000011105 stabilization Methods 0.000 title 1
- 125000003118 aryl group Chemical group 0.000 abstract 5
- 125000004432 carbon atom Chemical group C* 0.000 abstract 5
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 abstract 2
- -1 phosphonous acid arylester Chemical class 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- 238000010420 art technique Methods 0.000 abstract 1
- 150000007860 aryl ester derivatives Chemical class 0.000 abstract 1
- 125000005002 aryl methyl group Chemical group 0.000 abstract 1
- 125000004104 aryloxy group Chemical group 0.000 abstract 1
- 125000004663 dialkyl amino group Chemical group 0.000 abstract 1
- 150000008282 halocarbons Chemical class 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 150000002901 organomagnesium compounds Chemical class 0.000 abstract 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5393—Phosphonous compounds, e.g. R—P(OR')2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
- C07F9/4808—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof the acid moiety containing a substituent or structure which is considered as characteristic
- C07F9/4841—Aromatic acids or derivatives (P-C aromatic linkage)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
- C07F9/4808—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof the acid moiety containing a substituent or structure which is considered as characteristic
- C07F9/485—Polyphosphonous acids or derivatives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/657163—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom
- C07F9/65719—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom the ring phosphorus atom and, at least, one ring oxygen atom being part of a (thio)phosphonous acid derivative
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
PROCESO PARA LA PREPARACION DE ARILESTERES DE ACIDO FOSFONICO QUE TIENEN LA FORMULA (V), DONDE A ES UN ENLACE DIRECTO O NO EXISTENTE O UN PUENTE DE HIDROCARBURO DIVALENTE CON 1 A 6 ATOMOS DE CARBONO, QUE PUEDE SER SUSTITUIDO POR LOS GRUPOS ABAJO MENCIONADOS, O UN HETEROATOMO, CLICLOALQUILIDENO CON 4 A 8 ATOMOS DE CARBONO O FENILALQUILIDENO CON 7 A 12 ATOMOS DE CARBONO, N ES IGUAL A 1 O 2, R'' ES UN RESIDUO MONOVALENTE QUE DENOTA CIERTOS RESIDUOS DE HIDROCARBUROS NO AROMATICOS O AROMATICOS , DENOTANDO LOS RESIDUOS AROMATICOS SUSTITUYENTES COMO POR EJEMPLO ALQUILO , ALCOXI, ALQUILTIO, DIALQUILAMINO, ARILO, ARILOXI O HALOGENO Y COMO RESIDUO DIVALENTE DENOTA UN RESIDUO DE FENILENO O DE NAFTILENO, QUE PUEDE LLEVAR RESIDUOS DE HIDROCARBUROS NO AROMATICOS COMO SUSTITUYENTES, R (AL CUADRADO) ES UN RESIDUO DE HIDROCARBURO NO AROMATICO CON 1 A 18 ATOMOS DE CARBONO, ARILO, ARILMETILO, ARILETILO O ARILOSOPROPILO, CONTENIENDO CADA ARILO DE 6 A 10 ATOMOS DE CARBONO Y R ELEVADO 3 DENOTA HIDROGENO O UNO DELOS GRUPOS MENCIONADOS BAJO R (AL CUADRADO) . EN UNA PRIMERA FASE SE CONVIERTE UN R ELEVADO 1 (-HAL) SUB N DE HIDROCARBURO HALOGENADO, EN QUE R ELEVADO 1 TIENE EL SIGNIFICADO ARRIBA MENCIONADO, N=1 O 2, Y EL HALOGENO TIENE UN PESO ATOMICO DE 35 POR LO MENOS, BAJO CONDICIONES DE GRIGNARD CON AL MENOS CANTIDADES MOLARES DE MAGNESIO A LOS COMPUESTOS DE ORGANOMAGNESIO CORRESPONDIENTES DE R ELEVADO 1 (MGHAL) SUB N. A ESTOS SE LOS HACE REACCIONAR EN UNA SEGUNDA FASE CON HALOGENUROS DE BIS-ARILESTER DE ACIDO FOSFORICO QUE TIENEN LA FORMULA (VI), DONDE R (AL CUADRADO) , R ELEVADO 3 Y HAL TIENEN LOS SIGNIFICADOS ARRIBA MENCIONADOS, PARA FORMAR EL ARILESTER DE ACIDO FOSFONICO (V). LA INVENCION SE REFIERE TAMBIEN A UN MATERIAL DE MOLDEO DE PLASTICO, EN PARTICULAR A UN MATERIAL DE MOLDEO DE POLIOLEFINA, QUE CONTIENE EL ARILESTER DE ACIDO FOSFONICO DE LA FORMULA (V). LAS PROPIEDADES DEL MATERIAL DE MOLDEO SON SUPERIORES A LAS DE LOS MATERIALES DE MOLDEO QUE CONTIENEN FOSFONITAS PRODUCIDAS SEGUN METODOSANTERIORES.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3916502A DE3916502A1 (de) | 1989-05-20 | 1989-05-20 | Neue phosphonigsaeure-arylester, ein verfahren zu ihrer herstellung und deren verwendung zur stabilisierung von kunststoffen |
| DE3923492A DE3923492A1 (de) | 1989-05-20 | 1989-07-15 | Kunststoff-formmasse |
| DE4014428A DE4014428A1 (de) | 1989-05-20 | 1990-05-05 | Neue phosphonigsaeure-arylester, ein verfahren zu ihrer herstellung und deren verwendung zur stabilisierung von kunststoffen, insbesondere polyolefinformmassen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2064730T3 true ES2064730T3 (es) | 1995-02-01 |
Family
ID=27199597
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES90907020T Expired - Lifetime ES2064730T3 (es) | 1989-05-20 | 1990-05-16 | Nuevos esteres arilicos de acidos fosfonosos, un procedimiento para su preparacion y su utilizacion para la estabilizacion de materiales sinteticos, especialmente masas de moldeo de poliolefinas. |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0472564B1 (es) |
| JP (1) | JP3004713B2 (es) |
| KR (1) | KR0169086B1 (es) |
| AT (1) | ATE111915T1 (es) |
| AU (1) | AU635537B2 (es) |
| CA (1) | CA2058762C (es) |
| DE (1) | DE59007280D1 (es) |
| ES (1) | ES2064730T3 (es) |
| WO (1) | WO1990014349A2 (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2250990A (en) * | 1990-12-21 | 1992-06-24 | Ciba Geigy Ag | Substituted dibenzo[d,g][1,3,2]dioxaphosphocins |
| TW208017B (es) * | 1991-07-26 | 1993-06-21 | Hoechst Ag | |
| ES2938526T3 (es) | 2019-02-21 | 2023-04-12 | Clariant Int Ltd | Compuestos de fosfonito como estabilizadores de proceso |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH633296A5 (de) * | 1977-08-19 | 1982-11-30 | Sandoz Ag | Verfahren zur herstellung von 4-(n,n-dialkylamino-)phenylphosphoniten. |
| SU897797A1 (ru) * | 1980-04-07 | 1982-01-15 | Всесоюзный Научно-Исследовательский И Проектный Институт Полимерных Продуктов | Композици на основе политрихлорбутадиена |
| DE3373658D1 (en) * | 1983-06-08 | 1987-10-22 | Adeka Argus Chemical Co Ltd | Hindered bisphenol diphosphonites and stabilized synthetic resin compositions containing the same |
| FR2562543B1 (fr) * | 1984-04-10 | 1987-09-25 | Elf Aquitaine | Nouveaux phosphonites cycliques, leur preparation et applications |
| JP3479544B2 (ja) * | 1993-10-22 | 2003-12-15 | スター精密株式会社 | 印字装置 |
-
1990
- 1990-05-16 AU AU56539/90A patent/AU635537B2/en not_active Ceased
- 1990-05-16 JP JP2507347A patent/JP3004713B2/ja not_active Expired - Fee Related
- 1990-05-16 EP EP90907020A patent/EP0472564B1/de not_active Expired - Lifetime
- 1990-05-16 WO PCT/EP1990/000787 patent/WO1990014349A2/de active IP Right Grant
- 1990-05-16 CA CA002058762A patent/CA2058762C/en not_active Expired - Fee Related
- 1990-05-16 AT AT90907020T patent/ATE111915T1/de not_active IP Right Cessation
- 1990-05-16 KR KR1019910701632A patent/KR0169086B1/ko not_active IP Right Cessation
- 1990-05-16 DE DE59007280T patent/DE59007280D1/de not_active Expired - Fee Related
- 1990-05-16 ES ES90907020T patent/ES2064730T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE59007280D1 (de) | 1994-10-27 |
| JP3004713B2 (ja) | 2000-01-31 |
| AU635537B2 (en) | 1993-03-25 |
| JPH04507092A (ja) | 1992-12-10 |
| WO1990014349A3 (de) | 1991-02-21 |
| EP0472564B1 (de) | 1994-09-21 |
| AU5653990A (en) | 1990-12-18 |
| WO1990014349A2 (de) | 1990-11-29 |
| ATE111915T1 (de) | 1994-10-15 |
| CA2058762A1 (en) | 1990-11-21 |
| KR920701218A (ko) | 1992-08-11 |
| KR0169086B1 (ko) | 1999-03-20 |
| EP0472564A1 (de) | 1992-03-04 |
| CA2058762C (en) | 2001-05-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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